New ceramic electrodes allow reaching the target current density in bioelectrochemical systems

Autores
Massazza, Diego; Parra, Rodrigo; Busalmen, Juan Pablo; Romeo, Hernan Esteban
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Whereas most of the studies conducted nowadays to boost electrode performance in bioelectrochemical systems (BES) are focused on carbonaceous scaffolds, in this study we demonstrate that ice-templated titanium-based ceramics (ITTC) can provide a new alternative for this purpose. We combined the chemistry of titanium suboxides (Ti4O7) with an ice-templating technique (ISISA) to produce electrically conducting and highly porous (88% porosity) 3D architectures. The ITTC platforms were characterized by strongly aligned macrochannels that provided a direct path for substrate supply under a flow-through configuration, while supporting the growth of electroactive Geobacter sulfurreducens biofilms. This new electrode material is demonstrated to outperform graphite when used as an anode in bioelectrochemical reactors, providing volumetric current densities of 9500 A.m-3, equating to projected current densities of 128.7 A.m-2 and maximum power densities of 1.9 kW.m-3. The performance of the ITTC scaffolds levels that of any of the available materials on the current state of research. The presented alternative may lead to the start of a branch into the exploration of conducting ITTC materials in the growing area of bioelectrochemical technologies.
Fil: Massazza, Diego. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Parra, Rodrigo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Busalmen, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Romeo, Hernan Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Porous Electrode
Geobacter
Biofilm
Bioelectrochemistry
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/30942
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/30942
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling New ceramic electrodes allow reaching the target current density in bioelectrochemical systemsMassazza, DiegoParra, RodrigoBusalmen, Juan PabloRomeo, Hernan EstebanPorous ElectrodeGeobacterBiofilmBioelectrochemistryhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.6https://purl.org/becyt/ford/1Whereas most of the studies conducted nowadays to boost electrode performance in bioelectrochemical systems (BES) are focused on carbonaceous scaffolds, in this study we demonstrate that ice-templated titanium-based ceramics (ITTC) can provide a new alternative for this purpose. We combined the chemistry of titanium suboxides (Ti4O7) with an ice-templating technique (ISISA) to produce electrically conducting and highly porous (88% porosity) 3D architectures. The ITTC platforms were characterized by strongly aligned macrochannels that provided a direct path for substrate supply under a flow-through configuration, while supporting the growth of electroactive Geobacter sulfurreducens biofilms. This new electrode material is demonstrated to outperform graphite when used as an anode in bioelectrochemical reactors, providing volumetric current densities of 9500 A.m-3, equating to projected current densities of 128.7 A.m-2 and maximum power densities of 1.9 kW.m-3. The performance of the ITTC scaffolds levels that of any of the available materials on the current state of research. The presented alternative may lead to the start of a branch into the exploration of conducting ITTC materials in the growing area of bioelectrochemical technologies.Fil: Massazza, Diego. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Parra, Rodrigo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Busalmen, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Romeo, Hernan Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaRoyal Society of Chemistry2015-07-14info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/30942Massazza, Diego; Parra, Rodrigo; Busalmen, Juan Pablo; Romeo, Hernan Esteban; New ceramic electrodes allow reaching the target current density in bioelectrochemical systems; Royal Society of Chemistry; Energy & Environmental Science; 8; 9; 14-7-2015; 2707-27121754-5692CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/content/articlelanding/2015/ee/c5ee01498k#!divAbstractinfo:eu-repo/semantics/altIdentifier/doi/10.1039/C5EE01498Kinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:12:41Zoai:ri.conicet.gov.ar:11336/30942instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:12:41.345CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv New ceramic electrodes allow reaching the target current density in bioelectrochemical systems
title New ceramic electrodes allow reaching the target current density in bioelectrochemical systems
spellingShingle New ceramic electrodes allow reaching the target current density in bioelectrochemical systems
Massazza, Diego
Porous Electrode
Geobacter
Biofilm
Bioelectrochemistry
title_short New ceramic electrodes allow reaching the target current density in bioelectrochemical systems
title_full New ceramic electrodes allow reaching the target current density in bioelectrochemical systems
title_fullStr New ceramic electrodes allow reaching the target current density in bioelectrochemical systems
title_full_unstemmed New ceramic electrodes allow reaching the target current density in bioelectrochemical systems
title_sort New ceramic electrodes allow reaching the target current density in bioelectrochemical systems
dc.creator.none.fl_str_mv Massazza, Diego
Parra, Rodrigo
Busalmen, Juan Pablo
Romeo, Hernan Esteban
author Massazza, Diego
author_facet Massazza, Diego
Parra, Rodrigo
Busalmen, Juan Pablo
Romeo, Hernan Esteban
author_role author
author2 Parra, Rodrigo
Busalmen, Juan Pablo
Romeo, Hernan Esteban
author2_role author
author
author
dc.subject.none.fl_str_mv Porous Electrode
Geobacter
Biofilm
Bioelectrochemistry
topic Porous Electrode
Geobacter
Biofilm
Bioelectrochemistry
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/1.6
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Whereas most of the studies conducted nowadays to boost electrode performance in bioelectrochemical systems (BES) are focused on carbonaceous scaffolds, in this study we demonstrate that ice-templated titanium-based ceramics (ITTC) can provide a new alternative for this purpose. We combined the chemistry of titanium suboxides (Ti4O7) with an ice-templating technique (ISISA) to produce electrically conducting and highly porous (88% porosity) 3D architectures. The ITTC platforms were characterized by strongly aligned macrochannels that provided a direct path for substrate supply under a flow-through configuration, while supporting the growth of electroactive Geobacter sulfurreducens biofilms. This new electrode material is demonstrated to outperform graphite when used as an anode in bioelectrochemical reactors, providing volumetric current densities of 9500 A.m-3, equating to projected current densities of 128.7 A.m-2 and maximum power densities of 1.9 kW.m-3. The performance of the ITTC scaffolds levels that of any of the available materials on the current state of research. The presented alternative may lead to the start of a branch into the exploration of conducting ITTC materials in the growing area of bioelectrochemical technologies.
Fil: Massazza, Diego. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Parra, Rodrigo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Busalmen, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Romeo, Hernan Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Whereas most of the studies conducted nowadays to boost electrode performance in bioelectrochemical systems (BES) are focused on carbonaceous scaffolds, in this study we demonstrate that ice-templated titanium-based ceramics (ITTC) can provide a new alternative for this purpose. We combined the chemistry of titanium suboxides (Ti4O7) with an ice-templating technique (ISISA) to produce electrically conducting and highly porous (88% porosity) 3D architectures. The ITTC platforms were characterized by strongly aligned macrochannels that provided a direct path for substrate supply under a flow-through configuration, while supporting the growth of electroactive Geobacter sulfurreducens biofilms. This new electrode material is demonstrated to outperform graphite when used as an anode in bioelectrochemical reactors, providing volumetric current densities of 9500 A.m-3, equating to projected current densities of 128.7 A.m-2 and maximum power densities of 1.9 kW.m-3. The performance of the ITTC scaffolds levels that of any of the available materials on the current state of research. The presented alternative may lead to the start of a branch into the exploration of conducting ITTC materials in the growing area of bioelectrochemical technologies.
publishDate 2015
dc.date.none.fl_str_mv 2015-07-14
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/30942
Massazza, Diego; Parra, Rodrigo; Busalmen, Juan Pablo; Romeo, Hernan Esteban; New ceramic electrodes allow reaching the target current density in bioelectrochemical systems; Royal Society of Chemistry; Energy & Environmental Science; 8; 9; 14-7-2015; 2707-2712
1754-5692
CONICET Digital
CONICET
url http://hdl.handle.net/11336/30942
identifier_str_mv Massazza, Diego; Parra, Rodrigo; Busalmen, Juan Pablo; Romeo, Hernan Esteban; New ceramic electrodes allow reaching the target current density in bioelectrochemical systems; Royal Society of Chemistry; Energy & Environmental Science; 8; 9; 14-7-2015; 2707-2712
1754-5692
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/content/articlelanding/2015/ee/c5ee01498k#!divAbstract
info:eu-repo/semantics/altIdentifier/doi/10.1039/C5EE01498K
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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