Biochar as a substitute for graphite in microbial electrochemical technologies

Autores
Antic Gorrazzi, Sofia Julieta; Massazza, Diego Ariel; Pedetta, Andrea; Silva, Leonel Ignacio; Prados, Belén; Fouga, Gastón Galo; Bonanni, P. Sebastian
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Biochar has emerged as an attractive electrode material due to its biocompatibility, low cost andreduced environmental impact. The temperature at which biochar is produced greatly affects itsphysicochemical properties and its environmental performance. Despite that, only biochar obtainedat relatively high temperatures (800 to 1000 °C) has been applied in microbial electrochemicaltechnologies (METs) so far. In this work, the physicochemical and electrical properties of biocharelectrodes obtained at several temperatures (500 °C to 1000 °C) are explored and compared tothose of graphite which is the most commonly used electrode material in METs. Besides, theassociated carbon emissions and energy input of the production process at each temperature areestimated and compared to those of graphite. Results indicate that low-temperature (600 °C)biochar electrodes generate about half of the electric current obtained with high-temperaturebiochar or graphite electrodes. Furthermore, carbon emissions and energetic inputs for theproduction of low-temperature biochar are much lower than those of graphite production, with the600 °C electrodes having a net positive carbon footprint and also a lower production cost.Nevertheless, further research is needed to optimize biochar conductivity and mechanicalperformance in order to allow its integration into large scale METs.
Fil: Antic Gorrazzi, Sofia Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Massazza, Diego Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Pedetta, Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Silva, Leonel Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Prados, Belén. Comisión Nacional de Energía Atómica; Argentina
Fil: Fouga, Gastón Galo. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Bonanni, P. Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
LOW-TEMPERATURE BIOCHAR ELECTRODES
BIOELECTROCHEMISTRY
PAPYRUS BIOCHAR
GEOBACTER SULFURREDUCENS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/229882
Acceder
id CONICETDig_1c76dcfa2d4b5d75751ab88a1fd438de
oai_identifier_str oai:ri.conicet.gov.ar:11336/229882
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Biochar as a substitute for graphite in microbial electrochemical technologiesAntic Gorrazzi, Sofia JulietaMassazza, Diego ArielPedetta, AndreaSilva, Leonel IgnacioPrados, BelénFouga, Gastón GaloBonanni, P. SebastianLOW-TEMPERATURE BIOCHAR ELECTRODESBIOELECTROCHEMISTRYPAPYRUS BIOCHARGEOBACTER SULFURREDUCENShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Biochar has emerged as an attractive electrode material due to its biocompatibility, low cost andreduced environmental impact. The temperature at which biochar is produced greatly affects itsphysicochemical properties and its environmental performance. Despite that, only biochar obtainedat relatively high temperatures (800 to 1000 °C) has been applied in microbial electrochemicaltechnologies (METs) so far. In this work, the physicochemical and electrical properties of biocharelectrodes obtained at several temperatures (500 °C to 1000 °C) are explored and compared tothose of graphite which is the most commonly used electrode material in METs. Besides, theassociated carbon emissions and energy input of the production process at each temperature areestimated and compared to those of graphite. Results indicate that low-temperature (600 °C)biochar electrodes generate about half of the electric current obtained with high-temperaturebiochar or graphite electrodes. Furthermore, carbon emissions and energetic inputs for theproduction of low-temperature biochar are much lower than those of graphite production, with the600 °C electrodes having a net positive carbon footprint and also a lower production cost.Nevertheless, further research is needed to optimize biochar conductivity and mechanicalperformance in order to allow its integration into large scale METs.Fil: Antic Gorrazzi, Sofia Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Massazza, Diego Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Pedetta, Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Silva, Leonel Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Prados, Belén. Comisión Nacional de Energía Atómica; ArgentinaFil: Fouga, Gastón Galo. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Bonanni, P. Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaRoyal Society of Chemistry2023-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/229882Antic Gorrazzi, Sofia Julieta; Massazza, Diego Ariel; Pedetta, Andrea; Silva, Leonel Ignacio; Prados, Belén; et al.; Biochar as a substitute for graphite in microbial electrochemical technologies; Royal Society of Chemistry; RSC Sustainability; 1; 5; 5-2023; 1200-12102753-8125CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=D3SU00041Ainfo:eu-repo/semantics/altIdentifier/doi/10.1039/D3SU00041Ainfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:35:15Zoai:ri.conicet.gov.ar:11336/229882instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:35:15.302CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Biochar as a substitute for graphite in microbial electrochemical technologies
title Biochar as a substitute for graphite in microbial electrochemical technologies
spellingShingle Biochar as a substitute for graphite in microbial electrochemical technologies
Antic Gorrazzi, Sofia Julieta
LOW-TEMPERATURE BIOCHAR ELECTRODES
BIOELECTROCHEMISTRY
PAPYRUS BIOCHAR
GEOBACTER SULFURREDUCENS
title_short Biochar as a substitute for graphite in microbial electrochemical technologies
title_full Biochar as a substitute for graphite in microbial electrochemical technologies
title_fullStr Biochar as a substitute for graphite in microbial electrochemical technologies
title_full_unstemmed Biochar as a substitute for graphite in microbial electrochemical technologies
title_sort Biochar as a substitute for graphite in microbial electrochemical technologies
dc.creator.none.fl_str_mv Antic Gorrazzi, Sofia Julieta
Massazza, Diego Ariel
Pedetta, Andrea
Silva, Leonel Ignacio
Prados, Belén
Fouga, Gastón Galo
Bonanni, P. Sebastian
author Antic Gorrazzi, Sofia Julieta
author_facet Antic Gorrazzi, Sofia Julieta
Massazza, Diego Ariel
Pedetta, Andrea
Silva, Leonel Ignacio
Prados, Belén
Fouga, Gastón Galo
Bonanni, P. Sebastian
author_role author
author2 Massazza, Diego Ariel
Pedetta, Andrea
Silva, Leonel Ignacio
Prados, Belén
Fouga, Gastón Galo
Bonanni, P. Sebastian
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv LOW-TEMPERATURE BIOCHAR ELECTRODES
BIOELECTROCHEMISTRY
PAPYRUS BIOCHAR
GEOBACTER SULFURREDUCENS
topic LOW-TEMPERATURE BIOCHAR ELECTRODES
BIOELECTROCHEMISTRY
PAPYRUS BIOCHAR
GEOBACTER SULFURREDUCENS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Biochar has emerged as an attractive electrode material due to its biocompatibility, low cost andreduced environmental impact. The temperature at which biochar is produced greatly affects itsphysicochemical properties and its environmental performance. Despite that, only biochar obtainedat relatively high temperatures (800 to 1000 °C) has been applied in microbial electrochemicaltechnologies (METs) so far. In this work, the physicochemical and electrical properties of biocharelectrodes obtained at several temperatures (500 °C to 1000 °C) are explored and compared tothose of graphite which is the most commonly used electrode material in METs. Besides, theassociated carbon emissions and energy input of the production process at each temperature areestimated and compared to those of graphite. Results indicate that low-temperature (600 °C)biochar electrodes generate about half of the electric current obtained with high-temperaturebiochar or graphite electrodes. Furthermore, carbon emissions and energetic inputs for theproduction of low-temperature biochar are much lower than those of graphite production, with the600 °C electrodes having a net positive carbon footprint and also a lower production cost.Nevertheless, further research is needed to optimize biochar conductivity and mechanicalperformance in order to allow its integration into large scale METs.
Fil: Antic Gorrazzi, Sofia Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Massazza, Diego Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Pedetta, Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Silva, Leonel Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Prados, Belén. Comisión Nacional de Energía Atómica; Argentina
Fil: Fouga, Gastón Galo. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Bonanni, P. Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Biochar has emerged as an attractive electrode material due to its biocompatibility, low cost andreduced environmental impact. The temperature at which biochar is produced greatly affects itsphysicochemical properties and its environmental performance. Despite that, only biochar obtainedat relatively high temperatures (800 to 1000 °C) has been applied in microbial electrochemicaltechnologies (METs) so far. In this work, the physicochemical and electrical properties of biocharelectrodes obtained at several temperatures (500 °C to 1000 °C) are explored and compared tothose of graphite which is the most commonly used electrode material in METs. Besides, theassociated carbon emissions and energy input of the production process at each temperature areestimated and compared to those of graphite. Results indicate that low-temperature (600 °C)biochar electrodes generate about half of the electric current obtained with high-temperaturebiochar or graphite electrodes. Furthermore, carbon emissions and energetic inputs for theproduction of low-temperature biochar are much lower than those of graphite production, with the600 °C electrodes having a net positive carbon footprint and also a lower production cost.Nevertheless, further research is needed to optimize biochar conductivity and mechanicalperformance in order to allow its integration into large scale METs.
publishDate 2023
dc.date.none.fl_str_mv 2023-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/229882
Antic Gorrazzi, Sofia Julieta; Massazza, Diego Ariel; Pedetta, Andrea; Silva, Leonel Ignacio; Prados, Belén; et al.; Biochar as a substitute for graphite in microbial electrochemical technologies; Royal Society of Chemistry; RSC Sustainability; 1; 5; 5-2023; 1200-1210
2753-8125
CONICET Digital
CONICET
url http://hdl.handle.net/11336/229882
identifier_str_mv Antic Gorrazzi, Sofia Julieta; Massazza, Diego Ariel; Pedetta, Andrea; Silva, Leonel Ignacio; Prados, Belén; et al.; Biochar as a substitute for graphite in microbial electrochemical technologies; Royal Society of Chemistry; RSC Sustainability; 1; 5; 5-2023; 1200-1210
2753-8125
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=D3SU00041A
info:eu-repo/semantics/altIdentifier/doi/10.1039/D3SU00041A
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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