Exploiting the synergistic effect of concurrent data signals: Low-level fusion of liquid chromatographic with dual detection data

Autores
Teglia, Carla Mariela; Azcarate, Silvana Mariela; Alcaraz, Mirta Raquel; Goicoechea, Hector Casimiro; Culzoni, Maria Julia
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A low-level data fusion strategy was developed and implemented for data processing of second-order liquid chromatographic data with dual detection, i.e. absorbance and fluorescence monitoring. The synergistic effect of coupling individual information provided by two different detectors was evaluated by analyzing the results gathered after the application of a series of data preprocessing steps and chemometric resolution. The chemometric modeling involved data analysis by MCR-ALS, PARAFAC and N-PLS. Their ability to handle the new data block was assessed through the estimation of the analytical figures of merits achieved in the prediction of a validation set containing fifteen fluorescent and non-fluorescent veterinary active ingredients that can be found in poultry litter. Eventually, the feasibility of the application of the fusion strategy to real poultry litter samples containing the studied compounds was verified.
Fil: Teglia, Carla Mariela. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Azcarate, Silvana Mariela. Universidad Nacional de La Pampa; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Alcaraz, Mirta Raquel. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Goicoechea, Hector Casimiro. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Culzoni, Maria Julia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina
Materia
CHEMOMETRICS
DUAL DETECTION
LIQUID CHROMATOGRAPHY
LOW-LEVEL DATA FUSION
SECOND-ORDER DATA
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/83083
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Exploiting the synergistic effect of concurrent data signals: Low-level fusion of liquid chromatographic with dual detection dataTeglia, Carla MarielaAzcarate, Silvana MarielaAlcaraz, Mirta RaquelGoicoechea, Hector CasimiroCulzoni, Maria JuliaCHEMOMETRICSDUAL DETECTIONLIQUID CHROMATOGRAPHYLOW-LEVEL DATA FUSIONSECOND-ORDER DATAhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A low-level data fusion strategy was developed and implemented for data processing of second-order liquid chromatographic data with dual detection, i.e. absorbance and fluorescence monitoring. The synergistic effect of coupling individual information provided by two different detectors was evaluated by analyzing the results gathered after the application of a series of data preprocessing steps and chemometric resolution. The chemometric modeling involved data analysis by MCR-ALS, PARAFAC and N-PLS. Their ability to handle the new data block was assessed through the estimation of the analytical figures of merits achieved in the prediction of a validation set containing fifteen fluorescent and non-fluorescent veterinary active ingredients that can be found in poultry litter. Eventually, the feasibility of the application of the fusion strategy to real poultry litter samples containing the studied compounds was verified.Fil: Teglia, Carla Mariela. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Azcarate, Silvana Mariela. Universidad Nacional de La Pampa; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Alcaraz, Mirta Raquel. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Goicoechea, Hector Casimiro. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Culzoni, Maria Julia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; ArgentinaElsevier Science2018-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/83083Teglia, Carla Mariela; Azcarate, Silvana Mariela; Alcaraz, Mirta Raquel; Goicoechea, Hector Casimiro; Culzoni, Maria Julia; Exploiting the synergistic effect of concurrent data signals: Low-level fusion of liquid chromatographic with dual detection data; Elsevier Science; Talanta; 186; 8-2018; 481-4880039-9140CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2018.04.090info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0039914018304478info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:07:51Zoai:ri.conicet.gov.ar:11336/83083instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:07:51.734CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Exploiting the synergistic effect of concurrent data signals: Low-level fusion of liquid chromatographic with dual detection data
title Exploiting the synergistic effect of concurrent data signals: Low-level fusion of liquid chromatographic with dual detection data
spellingShingle Exploiting the synergistic effect of concurrent data signals: Low-level fusion of liquid chromatographic with dual detection data
Teglia, Carla Mariela
CHEMOMETRICS
DUAL DETECTION
LIQUID CHROMATOGRAPHY
LOW-LEVEL DATA FUSION
SECOND-ORDER DATA
title_short Exploiting the synergistic effect of concurrent data signals: Low-level fusion of liquid chromatographic with dual detection data
title_full Exploiting the synergistic effect of concurrent data signals: Low-level fusion of liquid chromatographic with dual detection data
title_fullStr Exploiting the synergistic effect of concurrent data signals: Low-level fusion of liquid chromatographic with dual detection data
title_full_unstemmed Exploiting the synergistic effect of concurrent data signals: Low-level fusion of liquid chromatographic with dual detection data
title_sort Exploiting the synergistic effect of concurrent data signals: Low-level fusion of liquid chromatographic with dual detection data
dc.creator.none.fl_str_mv Teglia, Carla Mariela
Azcarate, Silvana Mariela
Alcaraz, Mirta Raquel
Goicoechea, Hector Casimiro
Culzoni, Maria Julia
author Teglia, Carla Mariela
author_facet Teglia, Carla Mariela
Azcarate, Silvana Mariela
Alcaraz, Mirta Raquel
Goicoechea, Hector Casimiro
Culzoni, Maria Julia
author_role author
author2 Azcarate, Silvana Mariela
Alcaraz, Mirta Raquel
Goicoechea, Hector Casimiro
Culzoni, Maria Julia
author2_role author
author
author
author
dc.subject.none.fl_str_mv CHEMOMETRICS
DUAL DETECTION
LIQUID CHROMATOGRAPHY
LOW-LEVEL DATA FUSION
SECOND-ORDER DATA
topic CHEMOMETRICS
DUAL DETECTION
LIQUID CHROMATOGRAPHY
LOW-LEVEL DATA FUSION
SECOND-ORDER DATA
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A low-level data fusion strategy was developed and implemented for data processing of second-order liquid chromatographic data with dual detection, i.e. absorbance and fluorescence monitoring. The synergistic effect of coupling individual information provided by two different detectors was evaluated by analyzing the results gathered after the application of a series of data preprocessing steps and chemometric resolution. The chemometric modeling involved data analysis by MCR-ALS, PARAFAC and N-PLS. Their ability to handle the new data block was assessed through the estimation of the analytical figures of merits achieved in the prediction of a validation set containing fifteen fluorescent and non-fluorescent veterinary active ingredients that can be found in poultry litter. Eventually, the feasibility of the application of the fusion strategy to real poultry litter samples containing the studied compounds was verified.
Fil: Teglia, Carla Mariela. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Azcarate, Silvana Mariela. Universidad Nacional de La Pampa; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Alcaraz, Mirta Raquel. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Goicoechea, Hector Casimiro. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Culzoni, Maria Julia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina
description A low-level data fusion strategy was developed and implemented for data processing of second-order liquid chromatographic data with dual detection, i.e. absorbance and fluorescence monitoring. The synergistic effect of coupling individual information provided by two different detectors was evaluated by analyzing the results gathered after the application of a series of data preprocessing steps and chemometric resolution. The chemometric modeling involved data analysis by MCR-ALS, PARAFAC and N-PLS. Their ability to handle the new data block was assessed through the estimation of the analytical figures of merits achieved in the prediction of a validation set containing fifteen fluorescent and non-fluorescent veterinary active ingredients that can be found in poultry litter. Eventually, the feasibility of the application of the fusion strategy to real poultry litter samples containing the studied compounds was verified.
publishDate 2018
dc.date.none.fl_str_mv 2018-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/83083
Teglia, Carla Mariela; Azcarate, Silvana Mariela; Alcaraz, Mirta Raquel; Goicoechea, Hector Casimiro; Culzoni, Maria Julia; Exploiting the synergistic effect of concurrent data signals: Low-level fusion of liquid chromatographic with dual detection data; Elsevier Science; Talanta; 186; 8-2018; 481-488
0039-9140
CONICET Digital
CONICET
url http://hdl.handle.net/11336/83083
identifier_str_mv Teglia, Carla Mariela; Azcarate, Silvana Mariela; Alcaraz, Mirta Raquel; Goicoechea, Hector Casimiro; Culzoni, Maria Julia; Exploiting the synergistic effect of concurrent data signals: Low-level fusion of liquid chromatographic with dual detection data; Elsevier Science; Talanta; 186; 8-2018; 481-488
0039-9140
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2018.04.090
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0039914018304478
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.993085

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