Effect of lathanum addition on the properties of patassium-free catalysts for ethylbenzene dehydrogenation
- Autores
- Santana Santos, Manuela de; Marchetti, Sergio Gustavo; Albornoz, Alberto; Rangel, Maria do Carmo
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The ethylbenzene dehydrogenation in the presence of steam is the dominant technology for styrene production, one of the most important high value chemicals. The most widely used industrial catalyst comprises potassium-promoted iron oxide, which deactivates with time, due to potassium loss. In order to find alternative free-potassium catalysts, the effect of lanthanum on hematite-based catalysts was studied in this work. Samples with different amounts of lanthanum and prepared with different precipitants (ammonium hydroxide, sodium carbonate and sodium hydroxide) were obtained. It was found that lanthanum led to the production of solids with small particles when ammonium hydroxide was used, a fact which was assigned to lanthanum species on the surface where they keep the hematite particles apart avoiding sinterization. On the other hand, bigger particles were produced when sodium hydroxide and sodium carbonate are used, which resulted in solids with small specific surface areas. This was related to the sodium species which covered the surface impairing the lanthanum action. The most promising catalyst was that prepared with ammonium hydroxide and with La/Fe = 0.1, which showed the highest specific activity and the highest activity per area. In this solid, lanthanum acts as a structural promoter
Fil: Santana Santos, Manuela de. Universidade Federal de Bahia. Instituto de Química. Grupo de Estudios en Cinética e Catalise; Brasil
Fil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Albornoz, Alberto. Instituto Venezolano de Investigaciones Científicas; Venezuela
Fil: Rangel, Maria do Carmo. Universidade Federal de Bahia. Instituto de Química. Grupo de Estudios en Cinética e Catalise; Brasil - Materia
-
Ethylbenzene
Styrene
Lanthanum
Hematite - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/30406
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Effect of lathanum addition on the properties of patassium-free catalysts for ethylbenzene dehydrogenationSantana Santos, Manuela deMarchetti, Sergio GustavoAlbornoz, AlbertoRangel, Maria do CarmoEthylbenzeneStyreneLanthanumHematitehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The ethylbenzene dehydrogenation in the presence of steam is the dominant technology for styrene production, one of the most important high value chemicals. The most widely used industrial catalyst comprises potassium-promoted iron oxide, which deactivates with time, due to potassium loss. In order to find alternative free-potassium catalysts, the effect of lanthanum on hematite-based catalysts was studied in this work. Samples with different amounts of lanthanum and prepared with different precipitants (ammonium hydroxide, sodium carbonate and sodium hydroxide) were obtained. It was found that lanthanum led to the production of solids with small particles when ammonium hydroxide was used, a fact which was assigned to lanthanum species on the surface where they keep the hematite particles apart avoiding sinterization. On the other hand, bigger particles were produced when sodium hydroxide and sodium carbonate are used, which resulted in solids with small specific surface areas. This was related to the sodium species which covered the surface impairing the lanthanum action. The most promising catalyst was that prepared with ammonium hydroxide and with La/Fe = 0.1, which showed the highest specific activity and the highest activity per area. In this solid, lanthanum acts as a structural promoterFil: Santana Santos, Manuela de. Universidade Federal de Bahia. Instituto de Química. Grupo de Estudios en Cinética e Catalise; BrasilFil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Albornoz, Alberto. Instituto Venezolano de Investigaciones Científicas; VenezuelaFil: Rangel, Maria do Carmo. Universidade Federal de Bahia. Instituto de Química. Grupo de Estudios en Cinética e Catalise; BrasilElsevier Science2008-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/30406Santana Santos, Manuela de; Marchetti, Sergio Gustavo; Albornoz, Alberto; Rangel, Maria do Carmo; Effect of lathanum addition on the properties of patassium-free catalysts for ethylbenzene dehydrogenation; Elsevier Science; Catalysis Today; 133-135; 1-12-2008; 160-1670920-5861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0920586107008954info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:02:50Zoai:ri.conicet.gov.ar:11336/30406instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:02:50.876CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Effect of lathanum addition on the properties of patassium-free catalysts for ethylbenzene dehydrogenation |
title |
Effect of lathanum addition on the properties of patassium-free catalysts for ethylbenzene dehydrogenation |
spellingShingle |
Effect of lathanum addition on the properties of patassium-free catalysts for ethylbenzene dehydrogenation Santana Santos, Manuela de Ethylbenzene Styrene Lanthanum Hematite |
title_short |
Effect of lathanum addition on the properties of patassium-free catalysts for ethylbenzene dehydrogenation |
title_full |
Effect of lathanum addition on the properties of patassium-free catalysts for ethylbenzene dehydrogenation |
title_fullStr |
Effect of lathanum addition on the properties of patassium-free catalysts for ethylbenzene dehydrogenation |
title_full_unstemmed |
Effect of lathanum addition on the properties of patassium-free catalysts for ethylbenzene dehydrogenation |
title_sort |
Effect of lathanum addition on the properties of patassium-free catalysts for ethylbenzene dehydrogenation |
dc.creator.none.fl_str_mv |
Santana Santos, Manuela de Marchetti, Sergio Gustavo Albornoz, Alberto Rangel, Maria do Carmo |
author |
Santana Santos, Manuela de |
author_facet |
Santana Santos, Manuela de Marchetti, Sergio Gustavo Albornoz, Alberto Rangel, Maria do Carmo |
author_role |
author |
author2 |
Marchetti, Sergio Gustavo Albornoz, Alberto Rangel, Maria do Carmo |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Ethylbenzene Styrene Lanthanum Hematite |
topic |
Ethylbenzene Styrene Lanthanum Hematite |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The ethylbenzene dehydrogenation in the presence of steam is the dominant technology for styrene production, one of the most important high value chemicals. The most widely used industrial catalyst comprises potassium-promoted iron oxide, which deactivates with time, due to potassium loss. In order to find alternative free-potassium catalysts, the effect of lanthanum on hematite-based catalysts was studied in this work. Samples with different amounts of lanthanum and prepared with different precipitants (ammonium hydroxide, sodium carbonate and sodium hydroxide) were obtained. It was found that lanthanum led to the production of solids with small particles when ammonium hydroxide was used, a fact which was assigned to lanthanum species on the surface where they keep the hematite particles apart avoiding sinterization. On the other hand, bigger particles were produced when sodium hydroxide and sodium carbonate are used, which resulted in solids with small specific surface areas. This was related to the sodium species which covered the surface impairing the lanthanum action. The most promising catalyst was that prepared with ammonium hydroxide and with La/Fe = 0.1, which showed the highest specific activity and the highest activity per area. In this solid, lanthanum acts as a structural promoter Fil: Santana Santos, Manuela de. Universidade Federal de Bahia. Instituto de Química. Grupo de Estudios en Cinética e Catalise; Brasil Fil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina Fil: Albornoz, Alberto. Instituto Venezolano de Investigaciones Científicas; Venezuela Fil: Rangel, Maria do Carmo. Universidade Federal de Bahia. Instituto de Química. Grupo de Estudios en Cinética e Catalise; Brasil |
description |
The ethylbenzene dehydrogenation in the presence of steam is the dominant technology for styrene production, one of the most important high value chemicals. The most widely used industrial catalyst comprises potassium-promoted iron oxide, which deactivates with time, due to potassium loss. In order to find alternative free-potassium catalysts, the effect of lanthanum on hematite-based catalysts was studied in this work. Samples with different amounts of lanthanum and prepared with different precipitants (ammonium hydroxide, sodium carbonate and sodium hydroxide) were obtained. It was found that lanthanum led to the production of solids with small particles when ammonium hydroxide was used, a fact which was assigned to lanthanum species on the surface where they keep the hematite particles apart avoiding sinterization. On the other hand, bigger particles were produced when sodium hydroxide and sodium carbonate are used, which resulted in solids with small specific surface areas. This was related to the sodium species which covered the surface impairing the lanthanum action. The most promising catalyst was that prepared with ammonium hydroxide and with La/Fe = 0.1, which showed the highest specific activity and the highest activity per area. In this solid, lanthanum acts as a structural promoter |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-12-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/30406 Santana Santos, Manuela de; Marchetti, Sergio Gustavo; Albornoz, Alberto; Rangel, Maria do Carmo; Effect of lathanum addition on the properties of patassium-free catalysts for ethylbenzene dehydrogenation; Elsevier Science; Catalysis Today; 133-135; 1-12-2008; 160-167 0920-5861 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/30406 |
identifier_str_mv |
Santana Santos, Manuela de; Marchetti, Sergio Gustavo; Albornoz, Alberto; Rangel, Maria do Carmo; Effect of lathanum addition on the properties of patassium-free catalysts for ethylbenzene dehydrogenation; Elsevier Science; Catalysis Today; 133-135; 1-12-2008; 160-167 0920-5861 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/ info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0920586107008954 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613837167263744 |
score |
13.070432 |