Effect of the preparation method on the properties of hematite-based catalysts with lanthanum for styrene production

Autores
Santos, Manuela de S.; Marchetti, Sergio Gustavo; Albornoz, Alberto; Rangela, Maria do Carmo
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The influence of the preparation method on the properties of lanthanum-doped hematite prepared with potassium carbonate was studied aiming to get catalysts for styrene production from ethylbenzene dehydrogenation. The most active catalyst was obtained by adding the reactants on water. This solid has the highest intrinsic activity, the highest resistance against reduction and the lowest conversion drop. These properties were related to the presence of potassium compounds on the surface and to the presence of Fe+3 species (active phase) stabilized in lanthanum oxide lattice.
Fil: Santos, Manuela de S.. Universidade Federal da Bahia. Instituto de Química. GECCAT; Brasil
Fil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Albornoz, Alberto. Instituto Venezolano de Investigaciones Cientificas; Venezuela
Fil: Rangela, Maria do Carmo. Universidade Federal da Bahia. Instituto de Química. GECCAT; Brasil
Materia
Lanthanum
Iron Oxide
Potassium Carbonate
Styrene
Ethylbenzene
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/4622
Acceder
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network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Effect of the preparation method on the properties of hematite-based catalysts with lanthanum for styrene productionSantos, Manuela de S.Marchetti, Sergio Gustavo Albornoz, AlbertoRangela, Maria do CarmoLanthanumIron OxidePotassium CarbonateStyreneEthylbenzenehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The influence of the preparation method on the properties of lanthanum-doped hematite prepared with potassium carbonate was studied aiming to get catalysts for styrene production from ethylbenzene dehydrogenation. The most active catalyst was obtained by adding the reactants on water. This solid has the highest intrinsic activity, the highest resistance against reduction and the lowest conversion drop. These properties were related to the presence of potassium compounds on the surface and to the presence of Fe+3 species (active phase) stabilized in lanthanum oxide lattice.Fil: Santos, Manuela de S.. Universidade Federal da Bahia. Instituto de Química. GECCAT; BrasilFil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Albornoz, Alberto. Instituto Venezolano de Investigaciones Cientificas; VenezuelaFil: Rangela, Maria do Carmo. Universidade Federal da Bahia. Instituto de Química. GECCAT; BrasilElsevier2010-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/4622Santos, Manuela de S.; Marchetti, Sergio Gustavo; Albornoz, Alberto; Rangela, Maria do Carmo; Effect of the preparation method on the properties of hematite-based catalysts with lanthanum for styrene production; Elsevier; Studies In Surface Science And Catalysis; 175; 11-2010; 819-822978-0-444-53601-30167-2991enginfo:eu-repo/semantics/altIdentifier/ark/http://www.sciencedirect.com/science/article/pii/S0167299110751685info:eu-repo/semantics/altIdentifier/doi/10.1016/S0167-2991(10)75168-5info:eu-repo/semantics/altIdentifier/isbn/978-0-444-53601-3info:eu-repo/semantics/altIdentifier/issn/0167-2991info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:32:18Zoai:ri.conicet.gov.ar:11336/4622instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:32:18.765CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effect of the preparation method on the properties of hematite-based catalysts with lanthanum for styrene production
title Effect of the preparation method on the properties of hematite-based catalysts with lanthanum for styrene production
spellingShingle Effect of the preparation method on the properties of hematite-based catalysts with lanthanum for styrene production
Santos, Manuela de S.
Lanthanum
Iron Oxide
Potassium Carbonate
Styrene
Ethylbenzene
title_short Effect of the preparation method on the properties of hematite-based catalysts with lanthanum for styrene production
title_full Effect of the preparation method on the properties of hematite-based catalysts with lanthanum for styrene production
title_fullStr Effect of the preparation method on the properties of hematite-based catalysts with lanthanum for styrene production
title_full_unstemmed Effect of the preparation method on the properties of hematite-based catalysts with lanthanum for styrene production
title_sort Effect of the preparation method on the properties of hematite-based catalysts with lanthanum for styrene production
dc.creator.none.fl_str_mv Santos, Manuela de S.
Marchetti, Sergio Gustavo
Albornoz, Alberto
Rangela, Maria do Carmo
author Santos, Manuela de S.
author_facet Santos, Manuela de S.
Marchetti, Sergio Gustavo
Albornoz, Alberto
Rangela, Maria do Carmo
author_role author
author2 Marchetti, Sergio Gustavo
Albornoz, Alberto
Rangela, Maria do Carmo
author2_role author
author
author
dc.subject.none.fl_str_mv Lanthanum
Iron Oxide
Potassium Carbonate
Styrene
Ethylbenzene
topic Lanthanum
Iron Oxide
Potassium Carbonate
Styrene
Ethylbenzene
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The influence of the preparation method on the properties of lanthanum-doped hematite prepared with potassium carbonate was studied aiming to get catalysts for styrene production from ethylbenzene dehydrogenation. The most active catalyst was obtained by adding the reactants on water. This solid has the highest intrinsic activity, the highest resistance against reduction and the lowest conversion drop. These properties were related to the presence of potassium compounds on the surface and to the presence of Fe+3 species (active phase) stabilized in lanthanum oxide lattice.
Fil: Santos, Manuela de S.. Universidade Federal da Bahia. Instituto de Química. GECCAT; Brasil
Fil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Albornoz, Alberto. Instituto Venezolano de Investigaciones Cientificas; Venezuela
Fil: Rangela, Maria do Carmo. Universidade Federal da Bahia. Instituto de Química. GECCAT; Brasil
description The influence of the preparation method on the properties of lanthanum-doped hematite prepared with potassium carbonate was studied aiming to get catalysts for styrene production from ethylbenzene dehydrogenation. The most active catalyst was obtained by adding the reactants on water. This solid has the highest intrinsic activity, the highest resistance against reduction and the lowest conversion drop. These properties were related to the presence of potassium compounds on the surface and to the presence of Fe+3 species (active phase) stabilized in lanthanum oxide lattice.
publishDate 2010
dc.date.none.fl_str_mv 2010-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/4622
Santos, Manuela de S.; Marchetti, Sergio Gustavo; Albornoz, Alberto; Rangela, Maria do Carmo; Effect of the preparation method on the properties of hematite-based catalysts with lanthanum for styrene production; Elsevier; Studies In Surface Science And Catalysis; 175; 11-2010; 819-822
978-0-444-53601-3
0167-2991
url http://hdl.handle.net/11336/4622
identifier_str_mv Santos, Manuela de S.; Marchetti, Sergio Gustavo; Albornoz, Alberto; Rangela, Maria do Carmo; Effect of the preparation method on the properties of hematite-based catalysts with lanthanum for styrene production; Elsevier; Studies In Surface Science And Catalysis; 175; 11-2010; 819-822
978-0-444-53601-3
0167-2991
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/ark/http://www.sciencedirect.com/science/article/pii/S0167299110751685
info:eu-repo/semantics/altIdentifier/doi/10.1016/S0167-2991(10)75168-5
info:eu-repo/semantics/altIdentifier/isbn/978-0-444-53601-3
info:eu-repo/semantics/altIdentifier/issn/0167-2991
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844612985524322304
score 13.070432

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