Thermal Decomposition of Diethylketone Cyclic Triperoxide in Polar Solvents

Autores
Barreto, Gastón Pablo; Alvarez, Elida Ester; Eyler, Gladys Nora; Cañizo, Adriana Ines; Allegretti, Patricia Ercilia
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The thermolysis of diethylketone cyclic triperoxide (3,3,6,6,9,9-hexaethyl-1,2,4,5,7,8-hexaoxacyclononane, DEKTP) was studied in different polar solvents (ethanol, 2-propanol, 1-butanol, 2-butanol, 2-methyl-2-propanol, and acetonitrile). The rate constant values (kd) are higher for reactions performed in secondary alcohols probably because of the possibility to form a cyclic adduct with the participation of the hydrogen atom bonded to the secondary carbon. The kinetic parameters were correlated with the physicochemical properties of the selected solvents. The products of the DEKTP thermal decomposition in different polar solvents support a radical-based decomposition mechanism.
Fil: Barreto, Gastón Pablo. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingenieria Olavarria. Departamento de Ingenieria Quimica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Alvarez, Elida Ester. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingenieria Olavarria. Departamento de Ingenieria Quimica; Argentina
Fil: Eyler, Gladys Nora. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingenieria Olavarria. Departamento de Ingenieria Quimica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Cañizo, Adriana Ines. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingenieria Olavarria. Departamento de Ingenieria Quimica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Allegretti, Patricia Ercilia. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina
Materia
Thermolysis
Solvent Effect
Diethylketone Triperoxide
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/33685
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Thermal Decomposition of Diethylketone Cyclic Triperoxide in Polar SolventsBarreto, Gastón PabloAlvarez, Elida EsterEyler, Gladys NoraCañizo, Adriana InesAllegretti, Patricia ErciliaThermolysisSolvent EffectDiethylketone Triperoxidehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The thermolysis of diethylketone cyclic triperoxide (3,3,6,6,9,9-hexaethyl-1,2,4,5,7,8-hexaoxacyclononane, DEKTP) was studied in different polar solvents (ethanol, 2-propanol, 1-butanol, 2-butanol, 2-methyl-2-propanol, and acetonitrile). The rate constant values (kd) are higher for reactions performed in secondary alcohols probably because of the possibility to form a cyclic adduct with the participation of the hydrogen atom bonded to the secondary carbon. The kinetic parameters were correlated with the physicochemical properties of the selected solvents. The products of the DEKTP thermal decomposition in different polar solvents support a radical-based decomposition mechanism.Fil: Barreto, Gastón Pablo. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingenieria Olavarria. Departamento de Ingenieria Quimica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Alvarez, Elida Ester. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingenieria Olavarria. Departamento de Ingenieria Quimica; ArgentinaFil: Eyler, Gladys Nora. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingenieria Olavarria. Departamento de Ingenieria Quimica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Cañizo, Adriana Ines. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingenieria Olavarria. Departamento de Ingenieria Quimica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Allegretti, Patricia Ercilia. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; ArgentinaCsiro Publishing2014-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/33685Cañizo, Adriana Ines; Eyler, Gladys Nora; Allegretti, Patricia Ercilia; Barreto, Gastón Pablo; Alvarez, Elida Ester; Thermal Decomposition of Diethylketone Cyclic Triperoxide in Polar Solvents; Csiro Publishing; Australian Journal of Chemistry; 67; 6; 2-2014; 881-8860004-9425CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1071/CH13660info:eu-repo/semantics/altIdentifier/url/http://www.publish.csiro.au/ch/CH13660info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:47:10Zoai:ri.conicet.gov.ar:11336/33685instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:47:11.382CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Thermal Decomposition of Diethylketone Cyclic Triperoxide in Polar Solvents
title Thermal Decomposition of Diethylketone Cyclic Triperoxide in Polar Solvents
spellingShingle Thermal Decomposition of Diethylketone Cyclic Triperoxide in Polar Solvents
Barreto, Gastón Pablo
Thermolysis
Solvent Effect
Diethylketone Triperoxide
title_short Thermal Decomposition of Diethylketone Cyclic Triperoxide in Polar Solvents
title_full Thermal Decomposition of Diethylketone Cyclic Triperoxide in Polar Solvents
title_fullStr Thermal Decomposition of Diethylketone Cyclic Triperoxide in Polar Solvents
title_full_unstemmed Thermal Decomposition of Diethylketone Cyclic Triperoxide in Polar Solvents
title_sort Thermal Decomposition of Diethylketone Cyclic Triperoxide in Polar Solvents
dc.creator.none.fl_str_mv Barreto, Gastón Pablo
Alvarez, Elida Ester
Eyler, Gladys Nora
Cañizo, Adriana Ines
Allegretti, Patricia Ercilia
author Barreto, Gastón Pablo
author_facet Barreto, Gastón Pablo
Alvarez, Elida Ester
Eyler, Gladys Nora
Cañizo, Adriana Ines
Allegretti, Patricia Ercilia
author_role author
author2 Alvarez, Elida Ester
Eyler, Gladys Nora
Cañizo, Adriana Ines
Allegretti, Patricia Ercilia
author2_role author
author
author
author
dc.subject.none.fl_str_mv Thermolysis
Solvent Effect
Diethylketone Triperoxide
topic Thermolysis
Solvent Effect
Diethylketone Triperoxide
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The thermolysis of diethylketone cyclic triperoxide (3,3,6,6,9,9-hexaethyl-1,2,4,5,7,8-hexaoxacyclononane, DEKTP) was studied in different polar solvents (ethanol, 2-propanol, 1-butanol, 2-butanol, 2-methyl-2-propanol, and acetonitrile). The rate constant values (kd) are higher for reactions performed in secondary alcohols probably because of the possibility to form a cyclic adduct with the participation of the hydrogen atom bonded to the secondary carbon. The kinetic parameters were correlated with the physicochemical properties of the selected solvents. The products of the DEKTP thermal decomposition in different polar solvents support a radical-based decomposition mechanism.
Fil: Barreto, Gastón Pablo. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingenieria Olavarria. Departamento de Ingenieria Quimica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Alvarez, Elida Ester. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingenieria Olavarria. Departamento de Ingenieria Quimica; Argentina
Fil: Eyler, Gladys Nora. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingenieria Olavarria. Departamento de Ingenieria Quimica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Cañizo, Adriana Ines. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingenieria Olavarria. Departamento de Ingenieria Quimica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Allegretti, Patricia Ercilia. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina
description The thermolysis of diethylketone cyclic triperoxide (3,3,6,6,9,9-hexaethyl-1,2,4,5,7,8-hexaoxacyclononane, DEKTP) was studied in different polar solvents (ethanol, 2-propanol, 1-butanol, 2-butanol, 2-methyl-2-propanol, and acetonitrile). The rate constant values (kd) are higher for reactions performed in secondary alcohols probably because of the possibility to form a cyclic adduct with the participation of the hydrogen atom bonded to the secondary carbon. The kinetic parameters were correlated with the physicochemical properties of the selected solvents. The products of the DEKTP thermal decomposition in different polar solvents support a radical-based decomposition mechanism.
publishDate 2014
dc.date.none.fl_str_mv 2014-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/33685
Cañizo, Adriana Ines; Eyler, Gladys Nora; Allegretti, Patricia Ercilia; Barreto, Gastón Pablo; Alvarez, Elida Ester; Thermal Decomposition of Diethylketone Cyclic Triperoxide in Polar Solvents; Csiro Publishing; Australian Journal of Chemistry; 67; 6; 2-2014; 881-886
0004-9425
CONICET Digital
CONICET
url http://hdl.handle.net/11336/33685
identifier_str_mv Cañizo, Adriana Ines; Eyler, Gladys Nora; Allegretti, Patricia Ercilia; Barreto, Gastón Pablo; Alvarez, Elida Ester; Thermal Decomposition of Diethylketone Cyclic Triperoxide in Polar Solvents; Csiro Publishing; Australian Journal of Chemistry; 67; 6; 2-2014; 881-886
0004-9425
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1071/CH13660
info:eu-repo/semantics/altIdentifier/url/http://www.publish.csiro.au/ch/CH13660
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Csiro Publishing
publisher.none.fl_str_mv Csiro Publishing
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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