A New Strategy to Improve Alkyd/Acrylic Compatibilization in Waterborne Hybrid Dispersions

Autores
Goikoetxea, Monika; Minari, Roque Javier; Beristain, Itxaso; Paulis, María; Barandiaran, María; Asua, José M.
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Grafting of alkyd resin to the acrylic polymer is needed to fully exploit the possibilities of these hybrids; but in the current technology, grafting is accompanied by an important reduction of the unsaturated groups of the alkyds, which adversely affects the curing of the film and its properties. A novel strategy that overcomes these limitations is presented. The strategy is based on the use of alkyd resin functionalized with methacrylic groups, that substantially improved the incorporation of the resin to the growing acrylic polymer chain, and the polymer particle homogeneity, without decreasing the degree of unsaturation in the alkyd resin.
Fil: Goikoetxea, Monika. Universidad del Pais Vasco; España
Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina. Universidad del Pais Vasco; España
Fil: Beristain, Itxaso. Universidad del Pais Vasco; España
Fil: Paulis, María. Universidad del Pais Vasco; España
Fil: Barandiaran, María. Universidad del Pais Vasco; España
Fil: Asua, José M.. Universidad del Pais Vasco; España
Materia
Coatings
Nanocomposites
Miniemulsion
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/13748
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A New Strategy to Improve Alkyd/Acrylic Compatibilization in Waterborne Hybrid DispersionsGoikoetxea, MonikaMinari, Roque JavierBeristain, ItxasoPaulis, MaríaBarandiaran, MaríaAsua, José M.CoatingsNanocompositesMiniemulsionhttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Grafting of alkyd resin to the acrylic polymer is needed to fully exploit the possibilities of these hybrids; but in the current technology, grafting is accompanied by an important reduction of the unsaturated groups of the alkyds, which adversely affects the curing of the film and its properties. A novel strategy that overcomes these limitations is presented. The strategy is based on the use of alkyd resin functionalized with methacrylic groups, that substantially improved the incorporation of the resin to the growing acrylic polymer chain, and the polymer particle homogeneity, without decreasing the degree of unsaturation in the alkyd resin.Fil: Goikoetxea, Monika. Universidad del Pais Vasco; EspañaFil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina. Universidad del Pais Vasco; EspañaFil: Beristain, Itxaso. Universidad del Pais Vasco; EspañaFil: Paulis, María. Universidad del Pais Vasco; EspañaFil: Barandiaran, María. Universidad del Pais Vasco; EspañaFil: Asua, José M.. Universidad del Pais Vasco; EspañaElsevier2010-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/13748Goikoetxea, Monika; Minari, Roque Javier; Beristain, Itxaso; Paulis, María; Barandiaran, María; et al.; A New Strategy to Improve Alkyd/Acrylic Compatibilization in Waterborne Hybrid Dispersions; Elsevier; Polymer; 51; 23; 9-2010; 5313-53170032-3861enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2010.09.052info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0032386110008359info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:04:23Zoai:ri.conicet.gov.ar:11336/13748instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:04:23.375CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A New Strategy to Improve Alkyd/Acrylic Compatibilization in Waterborne Hybrid Dispersions
title A New Strategy to Improve Alkyd/Acrylic Compatibilization in Waterborne Hybrid Dispersions
spellingShingle A New Strategy to Improve Alkyd/Acrylic Compatibilization in Waterborne Hybrid Dispersions
Goikoetxea, Monika
Coatings
Nanocomposites
Miniemulsion
title_short A New Strategy to Improve Alkyd/Acrylic Compatibilization in Waterborne Hybrid Dispersions
title_full A New Strategy to Improve Alkyd/Acrylic Compatibilization in Waterborne Hybrid Dispersions
title_fullStr A New Strategy to Improve Alkyd/Acrylic Compatibilization in Waterborne Hybrid Dispersions
title_full_unstemmed A New Strategy to Improve Alkyd/Acrylic Compatibilization in Waterborne Hybrid Dispersions
title_sort A New Strategy to Improve Alkyd/Acrylic Compatibilization in Waterborne Hybrid Dispersions
dc.creator.none.fl_str_mv Goikoetxea, Monika
Minari, Roque Javier
Beristain, Itxaso
Paulis, María
Barandiaran, María
Asua, José M.
author Goikoetxea, Monika
author_facet Goikoetxea, Monika
Minari, Roque Javier
Beristain, Itxaso
Paulis, María
Barandiaran, María
Asua, José M.
author_role author
author2 Minari, Roque Javier
Beristain, Itxaso
Paulis, María
Barandiaran, María
Asua, José M.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Coatings
Nanocomposites
Miniemulsion
topic Coatings
Nanocomposites
Miniemulsion
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Grafting of alkyd resin to the acrylic polymer is needed to fully exploit the possibilities of these hybrids; but in the current technology, grafting is accompanied by an important reduction of the unsaturated groups of the alkyds, which adversely affects the curing of the film and its properties. A novel strategy that overcomes these limitations is presented. The strategy is based on the use of alkyd resin functionalized with methacrylic groups, that substantially improved the incorporation of the resin to the growing acrylic polymer chain, and the polymer particle homogeneity, without decreasing the degree of unsaturation in the alkyd resin.
Fil: Goikoetxea, Monika. Universidad del Pais Vasco; España
Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina. Universidad del Pais Vasco; España
Fil: Beristain, Itxaso. Universidad del Pais Vasco; España
Fil: Paulis, María. Universidad del Pais Vasco; España
Fil: Barandiaran, María. Universidad del Pais Vasco; España
Fil: Asua, José M.. Universidad del Pais Vasco; España
description Grafting of alkyd resin to the acrylic polymer is needed to fully exploit the possibilities of these hybrids; but in the current technology, grafting is accompanied by an important reduction of the unsaturated groups of the alkyds, which adversely affects the curing of the film and its properties. A novel strategy that overcomes these limitations is presented. The strategy is based on the use of alkyd resin functionalized with methacrylic groups, that substantially improved the incorporation of the resin to the growing acrylic polymer chain, and the polymer particle homogeneity, without decreasing the degree of unsaturation in the alkyd resin.
publishDate 2010
dc.date.none.fl_str_mv 2010-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/13748
Goikoetxea, Monika; Minari, Roque Javier; Beristain, Itxaso; Paulis, María; Barandiaran, María; et al.; A New Strategy to Improve Alkyd/Acrylic Compatibilization in Waterborne Hybrid Dispersions; Elsevier; Polymer; 51; 23; 9-2010; 5313-5317
0032-3861
url http://hdl.handle.net/11336/13748
identifier_str_mv Goikoetxea, Monika; Minari, Roque Javier; Beristain, Itxaso; Paulis, María; Barandiaran, María; et al.; A New Strategy to Improve Alkyd/Acrylic Compatibilization in Waterborne Hybrid Dispersions; Elsevier; Polymer; 51; 23; 9-2010; 5313-5317
0032-3861
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2010.09.052
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0032386110008359
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.993085

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