Dependence of the broad frequency dielectric spectra of colloidal polystyrene particle suspensions on the difference between the counterion and co-ion diffusion coefficients

Autores
Tirado, Monica Cecilia; Grosse, Constantino
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Dielectric properties of four suspensions of spherical polystyrene particles were measured at 25 ◦ C over a broad frequency range extending from 100 Hz to 10 MHz, using a HP 4192 A Impedance Analyzer. The instrument was coupled to a cell with parallel platinum black electrodes and variable spacing, and the quadrupole calibration method was used. The aqueous electrolyte solutions were prepared using equal concentrations of NaCl, KCl, NaAc, or KAc, so that the calculated Debye screening length and Zeta potential remained constant, while the conductivity changed. The polystyrene particles used (Interfacial Dynamics Corp., surfactant-free white sulfate latex) have a diameter of 1 micron and a surface charge density that is independent of the pH. The dielectric spectra were described using the Nettelblad–Niklasson expression combined with a Debye type high-frequency term and analyzed using the Shilov–Dukhin theory and numerical results. The theoretical prediction that the low-frequency dispersion parameters are determined by the co-ion diffusion coefficient was experimentally confirmed. This also allowed to justify an alternative definition of the characteristic time of the low-frequency dispersion. On the contrary, the prediction that the high-frequency dispersion parameters are determined by the diffusion coefficient of counterions could not be confirmed, possibly due to experimental problems. However, the ζ -potential values deduced from high-frequency data were compatible with values deduced from electrophoretic mobility measurements.
Fil: Tirado, Monica Cecilia. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina
Fil: Grosse, Constantino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; Argentina
Materia
Dielectric Dispersion
Diffusion Coefficients
Colloidal Suspensions Polystyrene Particles;
Polystyrene Particles
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/83974
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Dependence of the broad frequency dielectric spectra of colloidal polystyrene particle suspensions on the difference between the counterion and co-ion diffusion coefficientsTirado, Monica CeciliaGrosse, ConstantinoDielectric DispersionDiffusion CoefficientsColloidal Suspensions Polystyrene Particles;Polystyrene Particleshttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Dielectric properties of four suspensions of spherical polystyrene particles were measured at 25 ◦ C over a broad frequency range extending from 100 Hz to 10 MHz, using a HP 4192 A Impedance Analyzer. The instrument was coupled to a cell with parallel platinum black electrodes and variable spacing, and the quadrupole calibration method was used. The aqueous electrolyte solutions were prepared using equal concentrations of NaCl, KCl, NaAc, or KAc, so that the calculated Debye screening length and Zeta potential remained constant, while the conductivity changed. The polystyrene particles used (Interfacial Dynamics Corp., surfactant-free white sulfate latex) have a diameter of 1 micron and a surface charge density that is independent of the pH. The dielectric spectra were described using the Nettelblad–Niklasson expression combined with a Debye type high-frequency term and analyzed using the Shilov–Dukhin theory and numerical results. The theoretical prediction that the low-frequency dispersion parameters are determined by the co-ion diffusion coefficient was experimentally confirmed. This also allowed to justify an alternative definition of the characteristic time of the low-frequency dispersion. On the contrary, the prediction that the high-frequency dispersion parameters are determined by the diffusion coefficient of counterions could not be confirmed, possibly due to experimental problems. However, the ζ -potential values deduced from high-frequency data were compatible with values deduced from electrophoretic mobility measurements.Fil: Tirado, Monica Cecilia. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; ArgentinaFil: Grosse, Constantino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; ArgentinaAcademic Press Inc Elsevier Science2006-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/83974Tirado, Monica Cecilia; Grosse, Constantino; Dependence of the broad frequency dielectric spectra of colloidal polystyrene particle suspensions on the difference between the counterion and co-ion diffusion coefficients; Academic Press Inc Elsevier Science; Journal of Colloid and Interface Science; 298; 2; 12-2006; 973-9810021-9797CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jcis.2006.01.027info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0021979706000336?via%3Dihubinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:01:00Zoai:ri.conicet.gov.ar:11336/83974instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:01:01.169CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Dependence of the broad frequency dielectric spectra of colloidal polystyrene particle suspensions on the difference between the counterion and co-ion diffusion coefficients
title Dependence of the broad frequency dielectric spectra of colloidal polystyrene particle suspensions on the difference between the counterion and co-ion diffusion coefficients
spellingShingle Dependence of the broad frequency dielectric spectra of colloidal polystyrene particle suspensions on the difference between the counterion and co-ion diffusion coefficients
Tirado, Monica Cecilia
Dielectric Dispersion
Diffusion Coefficients
Colloidal Suspensions Polystyrene Particles;
Polystyrene Particles
title_short Dependence of the broad frequency dielectric spectra of colloidal polystyrene particle suspensions on the difference between the counterion and co-ion diffusion coefficients
title_full Dependence of the broad frequency dielectric spectra of colloidal polystyrene particle suspensions on the difference between the counterion and co-ion diffusion coefficients
title_fullStr Dependence of the broad frequency dielectric spectra of colloidal polystyrene particle suspensions on the difference between the counterion and co-ion diffusion coefficients
title_full_unstemmed Dependence of the broad frequency dielectric spectra of colloidal polystyrene particle suspensions on the difference between the counterion and co-ion diffusion coefficients
title_sort Dependence of the broad frequency dielectric spectra of colloidal polystyrene particle suspensions on the difference between the counterion and co-ion diffusion coefficients
dc.creator.none.fl_str_mv Tirado, Monica Cecilia
Grosse, Constantino
author Tirado, Monica Cecilia
author_facet Tirado, Monica Cecilia
Grosse, Constantino
author_role author
author2 Grosse, Constantino
author2_role author
dc.subject.none.fl_str_mv Dielectric Dispersion
Diffusion Coefficients
Colloidal Suspensions Polystyrene Particles;
Polystyrene Particles
topic Dielectric Dispersion
Diffusion Coefficients
Colloidal Suspensions Polystyrene Particles;
Polystyrene Particles
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Dielectric properties of four suspensions of spherical polystyrene particles were measured at 25 ◦ C over a broad frequency range extending from 100 Hz to 10 MHz, using a HP 4192 A Impedance Analyzer. The instrument was coupled to a cell with parallel platinum black electrodes and variable spacing, and the quadrupole calibration method was used. The aqueous electrolyte solutions were prepared using equal concentrations of NaCl, KCl, NaAc, or KAc, so that the calculated Debye screening length and Zeta potential remained constant, while the conductivity changed. The polystyrene particles used (Interfacial Dynamics Corp., surfactant-free white sulfate latex) have a diameter of 1 micron and a surface charge density that is independent of the pH. The dielectric spectra were described using the Nettelblad–Niklasson expression combined with a Debye type high-frequency term and analyzed using the Shilov–Dukhin theory and numerical results. The theoretical prediction that the low-frequency dispersion parameters are determined by the co-ion diffusion coefficient was experimentally confirmed. This also allowed to justify an alternative definition of the characteristic time of the low-frequency dispersion. On the contrary, the prediction that the high-frequency dispersion parameters are determined by the diffusion coefficient of counterions could not be confirmed, possibly due to experimental problems. However, the ζ -potential values deduced from high-frequency data were compatible with values deduced from electrophoretic mobility measurements.
Fil: Tirado, Monica Cecilia. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina
Fil: Grosse, Constantino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina. Universidad Nacional de Tucumán. Facultad de Ciencias Exactas y Tecnología. Departamento de Física; Argentina
description Dielectric properties of four suspensions of spherical polystyrene particles were measured at 25 ◦ C over a broad frequency range extending from 100 Hz to 10 MHz, using a HP 4192 A Impedance Analyzer. The instrument was coupled to a cell with parallel platinum black electrodes and variable spacing, and the quadrupole calibration method was used. The aqueous electrolyte solutions were prepared using equal concentrations of NaCl, KCl, NaAc, or KAc, so that the calculated Debye screening length and Zeta potential remained constant, while the conductivity changed. The polystyrene particles used (Interfacial Dynamics Corp., surfactant-free white sulfate latex) have a diameter of 1 micron and a surface charge density that is independent of the pH. The dielectric spectra were described using the Nettelblad–Niklasson expression combined with a Debye type high-frequency term and analyzed using the Shilov–Dukhin theory and numerical results. The theoretical prediction that the low-frequency dispersion parameters are determined by the co-ion diffusion coefficient was experimentally confirmed. This also allowed to justify an alternative definition of the characteristic time of the low-frequency dispersion. On the contrary, the prediction that the high-frequency dispersion parameters are determined by the diffusion coefficient of counterions could not be confirmed, possibly due to experimental problems. However, the ζ -potential values deduced from high-frequency data were compatible with values deduced from electrophoretic mobility measurements.
publishDate 2006
dc.date.none.fl_str_mv 2006-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/83974
Tirado, Monica Cecilia; Grosse, Constantino; Dependence of the broad frequency dielectric spectra of colloidal polystyrene particle suspensions on the difference between the counterion and co-ion diffusion coefficients; Academic Press Inc Elsevier Science; Journal of Colloid and Interface Science; 298; 2; 12-2006; 973-981
0021-9797
CONICET Digital
CONICET
url http://hdl.handle.net/11336/83974
identifier_str_mv Tirado, Monica Cecilia; Grosse, Constantino; Dependence of the broad frequency dielectric spectra of colloidal polystyrene particle suspensions on the difference between the counterion and co-ion diffusion coefficients; Academic Press Inc Elsevier Science; Journal of Colloid and Interface Science; 298; 2; 12-2006; 973-981
0021-9797
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jcis.2006.01.027
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0021979706000336?via%3Dihub
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Academic Press Inc Elsevier Science
publisher.none.fl_str_mv Academic Press Inc Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613798336397312
score 13.070432

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