Optimal operation of ethylene polymerization reactors for tailored molecular weight distribution

Autores
Asteasuain, Mariano; Brandolin, Adriana
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work presents a comprehensive steady-state model of the high-pressure ethylene polymerization in a tubular reactor able to calculate the complete molecular weight distribution (MWD). For this purpose, the probability generating function technique is employed. The model is included in an optimization framework, which is used to determine optimal reactor designs and operating conditions for producing a polymer with tailored MWD. Two application examples are presented. The first one involves maximization of conversion to obtain a given MWD, typical of industrial operation. Excellent agreement between the resulting MWD and the target one is achieved with a conversion about 5% higher than the ones commonly reported for this type of reactor. The second example consists in finding the design and operating conditions necessary to produce a polymer with a bimodal MWD. The optimal design for this case involves a split of the initiator, monomer, and modifier feeds between the main stream and two lateral injections. To the best of our knowledge, this is the first work dealing with the optimization of this process in which a tailored shape for the MWD is included.
Fil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Modeling
Molecular Weight Distribution
Optimization
Polyethylene (Pe)
Radical Polymerization
Tubular Reactor
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/79087
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/79087
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Optimal operation of ethylene polymerization reactors for tailored molecular weight distributionAsteasuain, MarianoBrandolin, AdrianaModelingMolecular Weight DistributionOptimizationPolyethylene (Pe)Radical PolymerizationTubular Reactorhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This work presents a comprehensive steady-state model of the high-pressure ethylene polymerization in a tubular reactor able to calculate the complete molecular weight distribution (MWD). For this purpose, the probability generating function technique is employed. The model is included in an optimization framework, which is used to determine optimal reactor designs and operating conditions for producing a polymer with tailored MWD. Two application examples are presented. The first one involves maximization of conversion to obtain a given MWD, typical of industrial operation. Excellent agreement between the resulting MWD and the target one is achieved with a conversion about 5% higher than the ones commonly reported for this type of reactor. The second example consists in finding the design and operating conditions necessary to produce a polymer with a bimodal MWD. The optimal design for this case involves a split of the initiator, monomer, and modifier feeds between the main stream and two lateral injections. To the best of our knowledge, this is the first work dealing with the optimization of this process in which a tailored shape for the MWD is included.Fil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaJohn Wiley & Sons Inc2007-09-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/79087Asteasuain, Mariano; Brandolin, Adriana; Optimal operation of ethylene polymerization reactors for tailored molecular weight distribution; John Wiley & Sons Inc; Journal of Applied Polymer Science; 105; 5; 5-9-2007; 2621-26300021-89951097-4628CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1474667016353289info:eu-repo/semantics/altIdentifier/doi/10.1002/app.26295info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:10:54Zoai:ri.conicet.gov.ar:11336/79087instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:10:55.191CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Optimal operation of ethylene polymerization reactors for tailored molecular weight distribution
title Optimal operation of ethylene polymerization reactors for tailored molecular weight distribution
spellingShingle Optimal operation of ethylene polymerization reactors for tailored molecular weight distribution
Asteasuain, Mariano
Modeling
Molecular Weight Distribution
Optimization
Polyethylene (Pe)
Radical Polymerization
Tubular Reactor
title_short Optimal operation of ethylene polymerization reactors for tailored molecular weight distribution
title_full Optimal operation of ethylene polymerization reactors for tailored molecular weight distribution
title_fullStr Optimal operation of ethylene polymerization reactors for tailored molecular weight distribution
title_full_unstemmed Optimal operation of ethylene polymerization reactors for tailored molecular weight distribution
title_sort Optimal operation of ethylene polymerization reactors for tailored molecular weight distribution
dc.creator.none.fl_str_mv Asteasuain, Mariano
Brandolin, Adriana
author Asteasuain, Mariano
author_facet Asteasuain, Mariano
Brandolin, Adriana
author_role author
author2 Brandolin, Adriana
author2_role author
dc.subject.none.fl_str_mv Modeling
Molecular Weight Distribution
Optimization
Polyethylene (Pe)
Radical Polymerization
Tubular Reactor
topic Modeling
Molecular Weight Distribution
Optimization
Polyethylene (Pe)
Radical Polymerization
Tubular Reactor
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This work presents a comprehensive steady-state model of the high-pressure ethylene polymerization in a tubular reactor able to calculate the complete molecular weight distribution (MWD). For this purpose, the probability generating function technique is employed. The model is included in an optimization framework, which is used to determine optimal reactor designs and operating conditions for producing a polymer with tailored MWD. Two application examples are presented. The first one involves maximization of conversion to obtain a given MWD, typical of industrial operation. Excellent agreement between the resulting MWD and the target one is achieved with a conversion about 5% higher than the ones commonly reported for this type of reactor. The second example consists in finding the design and operating conditions necessary to produce a polymer with a bimodal MWD. The optimal design for this case involves a split of the initiator, monomer, and modifier feeds between the main stream and two lateral injections. To the best of our knowledge, this is the first work dealing with the optimization of this process in which a tailored shape for the MWD is included.
Fil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description This work presents a comprehensive steady-state model of the high-pressure ethylene polymerization in a tubular reactor able to calculate the complete molecular weight distribution (MWD). For this purpose, the probability generating function technique is employed. The model is included in an optimization framework, which is used to determine optimal reactor designs and operating conditions for producing a polymer with tailored MWD. Two application examples are presented. The first one involves maximization of conversion to obtain a given MWD, typical of industrial operation. Excellent agreement between the resulting MWD and the target one is achieved with a conversion about 5% higher than the ones commonly reported for this type of reactor. The second example consists in finding the design and operating conditions necessary to produce a polymer with a bimodal MWD. The optimal design for this case involves a split of the initiator, monomer, and modifier feeds between the main stream and two lateral injections. To the best of our knowledge, this is the first work dealing with the optimization of this process in which a tailored shape for the MWD is included.
publishDate 2007
dc.date.none.fl_str_mv 2007-09-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/79087
Asteasuain, Mariano; Brandolin, Adriana; Optimal operation of ethylene polymerization reactors for tailored molecular weight distribution; John Wiley & Sons Inc; Journal of Applied Polymer Science; 105; 5; 5-9-2007; 2621-2630
0021-8995
1097-4628
CONICET Digital
CONICET
url http://hdl.handle.net/11336/79087
identifier_str_mv Asteasuain, Mariano; Brandolin, Adriana; Optimal operation of ethylene polymerization reactors for tailored molecular weight distribution; John Wiley & Sons Inc; Journal of Applied Polymer Science; 105; 5; 5-9-2007; 2621-2630
0021-8995
1097-4628
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1474667016353289
info:eu-repo/semantics/altIdentifier/doi/10.1002/app.26295
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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