How excitation-emission matrices have revolutionised multi-way data analyses – A tutorial for multi-way EEM-based calibration method developments

Autores
Antonio, Marina; Muñoz de la Peña, Arsenio; Goicoechea, Hector Casimiro; Alcaraz, Mirta Raquel
Año de publicación
2025
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
For many years, excitation-emission matrix (EEM) fluorescence spectroscopy has been a compelling analytical technique, fostering the development of multidimensional data analysis-based methods. Its applications span diverse fields, including analytical chemistry and biological, food, and environmental sciences, which have been extensively documented in the scientific literature. EEM spectroscopy stands out for its versatility, affordability, and exceptional capacity to provide rich analytical insights, making it a preferred choice for investigations requiring higher-order data analysis. While second-order data analysis based on EEM fluorescence spectroscopy has been widely explored, generating third-order data from EEM remains a challenging and spotlighted research area.This tutorial intends to trace the evolution of multi-way data analysis in recent years, focusing on applying multidimensional fluorescence in analytical contexts. It delves into the critical issues, emerging trends, and challenges in analytical calibration method developments. Moreover, our comprehensive assessment encompasses the instrumental, methodological, and practical aspects of multi-way data applications, providing tailored guidance to empower readers in overcoming obstacles and advancing their research endeavours..
Fil: Antonio, Marina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Química. Cátedra de Química Analítica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Muñoz de la Peña, Arsenio. Universidad de Extremadura; España
Fil: Goicoechea, Hector Casimiro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Química. Cátedra de Química Analítica; Argentina
Fil: Alcaraz, Mirta Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Química. Cátedra de Química Analítica; Argentina
Materia
EXCITATION EMISSION MATRICES
MULTIWAY CALIBRATON
SECOND ORDER
THIRD ORDER
EVOLVING SYSTEMS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/278920
Acceder
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spelling How excitation-emission matrices have revolutionised multi-way data analyses – A tutorial for multi-way EEM-based calibration method developmentsAntonio, MarinaMuñoz de la Peña, ArsenioGoicoechea, Hector CasimiroAlcaraz, Mirta RaquelEXCITATION EMISSION MATRICESMULTIWAY CALIBRATONSECOND ORDERTHIRD ORDEREVOLVING SYSTEMShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1For many years, excitation-emission matrix (EEM) fluorescence spectroscopy has been a compelling analytical technique, fostering the development of multidimensional data analysis-based methods. Its applications span diverse fields, including analytical chemistry and biological, food, and environmental sciences, which have been extensively documented in the scientific literature. EEM spectroscopy stands out for its versatility, affordability, and exceptional capacity to provide rich analytical insights, making it a preferred choice for investigations requiring higher-order data analysis. While second-order data analysis based on EEM fluorescence spectroscopy has been widely explored, generating third-order data from EEM remains a challenging and spotlighted research area.This tutorial intends to trace the evolution of multi-way data analysis in recent years, focusing on applying multidimensional fluorescence in analytical contexts. It delves into the critical issues, emerging trends, and challenges in analytical calibration method developments. Moreover, our comprehensive assessment encompasses the instrumental, methodological, and practical aspects of multi-way data applications, providing tailored guidance to empower readers in overcoming obstacles and advancing their research endeavours..Fil: Antonio, Marina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Química. Cátedra de Química Analítica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Muñoz de la Peña, Arsenio. Universidad de Extremadura; EspañaFil: Goicoechea, Hector Casimiro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Química. Cátedra de Química Analítica; ArgentinaFil: Alcaraz, Mirta Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Química. Cátedra de Química Analítica; ArgentinaElsevier Science2025-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/278920Antonio, Marina; Muñoz de la Peña, Arsenio; Goicoechea, Hector Casimiro; Alcaraz, Mirta Raquel; How excitation-emission matrices have revolutionised multi-way data analyses – A tutorial for multi-way EEM-based calibration method developments; Elsevier Science; Analytica Chimica Acta; 1360; 4-2025; 1-740003-2670CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0003267025004830info:eu-repo/semantics/altIdentifier/doi/10.1016/j.aca.2025.344089info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2026-01-14T11:43:59Zoai:ri.conicet.gov.ar:11336/278920instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982026-01-14 11:44:00.258CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv How excitation-emission matrices have revolutionised multi-way data analyses – A tutorial for multi-way EEM-based calibration method developments
title How excitation-emission matrices have revolutionised multi-way data analyses – A tutorial for multi-way EEM-based calibration method developments
spellingShingle How excitation-emission matrices have revolutionised multi-way data analyses – A tutorial for multi-way EEM-based calibration method developments
Antonio, Marina
EXCITATION EMISSION MATRICES
MULTIWAY CALIBRATON
SECOND ORDER
THIRD ORDER
EVOLVING SYSTEMS
title_short How excitation-emission matrices have revolutionised multi-way data analyses – A tutorial for multi-way EEM-based calibration method developments
title_full How excitation-emission matrices have revolutionised multi-way data analyses – A tutorial for multi-way EEM-based calibration method developments
title_fullStr How excitation-emission matrices have revolutionised multi-way data analyses – A tutorial for multi-way EEM-based calibration method developments
title_full_unstemmed How excitation-emission matrices have revolutionised multi-way data analyses – A tutorial for multi-way EEM-based calibration method developments
title_sort How excitation-emission matrices have revolutionised multi-way data analyses – A tutorial for multi-way EEM-based calibration method developments
dc.creator.none.fl_str_mv Antonio, Marina
Muñoz de la Peña, Arsenio
Goicoechea, Hector Casimiro
Alcaraz, Mirta Raquel
author Antonio, Marina
author_facet Antonio, Marina
Muñoz de la Peña, Arsenio
Goicoechea, Hector Casimiro
Alcaraz, Mirta Raquel
author_role author
author2 Muñoz de la Peña, Arsenio
Goicoechea, Hector Casimiro
Alcaraz, Mirta Raquel
author2_role author
author
author
dc.subject.none.fl_str_mv EXCITATION EMISSION MATRICES
MULTIWAY CALIBRATON
SECOND ORDER
THIRD ORDER
EVOLVING SYSTEMS
topic EXCITATION EMISSION MATRICES
MULTIWAY CALIBRATON
SECOND ORDER
THIRD ORDER
EVOLVING SYSTEMS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv For many years, excitation-emission matrix (EEM) fluorescence spectroscopy has been a compelling analytical technique, fostering the development of multidimensional data analysis-based methods. Its applications span diverse fields, including analytical chemistry and biological, food, and environmental sciences, which have been extensively documented in the scientific literature. EEM spectroscopy stands out for its versatility, affordability, and exceptional capacity to provide rich analytical insights, making it a preferred choice for investigations requiring higher-order data analysis. While second-order data analysis based on EEM fluorescence spectroscopy has been widely explored, generating third-order data from EEM remains a challenging and spotlighted research area.This tutorial intends to trace the evolution of multi-way data analysis in recent years, focusing on applying multidimensional fluorescence in analytical contexts. It delves into the critical issues, emerging trends, and challenges in analytical calibration method developments. Moreover, our comprehensive assessment encompasses the instrumental, methodological, and practical aspects of multi-way data applications, providing tailored guidance to empower readers in overcoming obstacles and advancing their research endeavours..
Fil: Antonio, Marina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Química. Cátedra de Química Analítica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Muñoz de la Peña, Arsenio. Universidad de Extremadura; España
Fil: Goicoechea, Hector Casimiro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Química. Cátedra de Química Analítica; Argentina
Fil: Alcaraz, Mirta Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Química. Cátedra de Química Analítica; Argentina
description For many years, excitation-emission matrix (EEM) fluorescence spectroscopy has been a compelling analytical technique, fostering the development of multidimensional data analysis-based methods. Its applications span diverse fields, including analytical chemistry and biological, food, and environmental sciences, which have been extensively documented in the scientific literature. EEM spectroscopy stands out for its versatility, affordability, and exceptional capacity to provide rich analytical insights, making it a preferred choice for investigations requiring higher-order data analysis. While second-order data analysis based on EEM fluorescence spectroscopy has been widely explored, generating third-order data from EEM remains a challenging and spotlighted research area.This tutorial intends to trace the evolution of multi-way data analysis in recent years, focusing on applying multidimensional fluorescence in analytical contexts. It delves into the critical issues, emerging trends, and challenges in analytical calibration method developments. Moreover, our comprehensive assessment encompasses the instrumental, methodological, and practical aspects of multi-way data applications, providing tailored guidance to empower readers in overcoming obstacles and advancing their research endeavours..
publishDate 2025
dc.date.none.fl_str_mv 2025-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/278920
Antonio, Marina; Muñoz de la Peña, Arsenio; Goicoechea, Hector Casimiro; Alcaraz, Mirta Raquel; How excitation-emission matrices have revolutionised multi-way data analyses – A tutorial for multi-way EEM-based calibration method developments; Elsevier Science; Analytica Chimica Acta; 1360; 4-2025; 1-74
0003-2670
CONICET Digital
CONICET
url http://hdl.handle.net/11336/278920
identifier_str_mv Antonio, Marina; Muñoz de la Peña, Arsenio; Goicoechea, Hector Casimiro; Alcaraz, Mirta Raquel; How excitation-emission matrices have revolutionised multi-way data analyses – A tutorial for multi-way EEM-based calibration method developments; Elsevier Science; Analytica Chimica Acta; 1360; 4-2025; 1-74
0003-2670
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0003267025004830
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.aca.2025.344089
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.113929

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