Native Fluorescent Natural Deep Eutectic Solvents for Green Sensing Applications: Curcuminoids in Curcuma longa Powder

Autores
Lorenzetti, Anabela Silvana; Vidal, Ezequiel Martin; Silva, María Fernanda; Domini, Claudia Elizabeth; Gomez, Federico Jose Vicente
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Natural deep eutectic solvents are a trending topic in Green Chemistry. These solvents present high solubilization capacity, reusability, tunable properties, simple preparation, biodegradability, safety, high availability, and low cost, making them excellent candidates for analytical applications. In this work, a new family of fluorescent eutectic systems is described, with the fluorescence property being unknown and unused so far. For this purpose, a novel preparation method using an ultrasound probe was employed, by means of an innovative single-step procedure, that included the preparation of FCH (fructose, citric acid, and water, 1:1:5 molar ratio) and the extraction/determination of curcuminoids from Curcuma longa powder. This methodology was successfully carried out by employing a portable and inexpensive 3D-printed fluorometer and a smartphone. In this way, extraction efficiencies between 90 and 106%, relative to the NIST reference method, were obtained in just 3.40 min. Besides, the greenness of the new methodology was evaluated by employing the AGREE metric, showing that the developed approach is >2.5 times greener than previously published works for curcuminoid determination. This groundbreaking procedure is robust, versatile, and simple to implement, does not require sophisticated apparatus or instruments in the detection step, and, mainly, agrees with Green Analytical Chemistry (GAC) principles.
Fil: Lorenzetti, Anabela Silvana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; Argentina
Fil: Vidal, Ezequiel Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Silva, María Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; Argentina
Fil: Domini, Claudia Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Gomez, Federico Jose Vicente. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; Argentina
Materia
3D-PRINTED DEVICE
AGREE METRIC
CURCUMINOIDS
FLUORESCENCE
GREEN ANALYTICAL CHEMISTRY
NADES
ULTRASOUND PROBE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/168979
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Native Fluorescent Natural Deep Eutectic Solvents for Green Sensing Applications: Curcuminoids in Curcuma longa PowderLorenzetti, Anabela SilvanaVidal, Ezequiel MartinSilva, María FernandaDomini, Claudia ElizabethGomez, Federico Jose Vicente3D-PRINTED DEVICEAGREE METRICCURCUMINOIDSFLUORESCENCEGREEN ANALYTICAL CHEMISTRYNADESULTRASOUND PROBEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Natural deep eutectic solvents are a trending topic in Green Chemistry. These solvents present high solubilization capacity, reusability, tunable properties, simple preparation, biodegradability, safety, high availability, and low cost, making them excellent candidates for analytical applications. In this work, a new family of fluorescent eutectic systems is described, with the fluorescence property being unknown and unused so far. For this purpose, a novel preparation method using an ultrasound probe was employed, by means of an innovative single-step procedure, that included the preparation of FCH (fructose, citric acid, and water, 1:1:5 molar ratio) and the extraction/determination of curcuminoids from Curcuma longa powder. This methodology was successfully carried out by employing a portable and inexpensive 3D-printed fluorometer and a smartphone. In this way, extraction efficiencies between 90 and 106%, relative to the NIST reference method, were obtained in just 3.40 min. Besides, the greenness of the new methodology was evaluated by employing the AGREE metric, showing that the developed approach is >2.5 times greener than previously published works for curcuminoid determination. This groundbreaking procedure is robust, versatile, and simple to implement, does not require sophisticated apparatus or instruments in the detection step, and, mainly, agrees with Green Analytical Chemistry (GAC) principles.Fil: Lorenzetti, Anabela Silvana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; ArgentinaFil: Vidal, Ezequiel Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Silva, María Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; ArgentinaFil: Domini, Claudia Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Gomez, Federico Jose Vicente. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; ArgentinaAmerican Chemical Society Inc2021-04-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/168979Lorenzetti, Anabela Silvana; Vidal, Ezequiel Martin; Silva, María Fernanda; Domini, Claudia Elizabeth; Gomez, Federico Jose Vicente; Native Fluorescent Natural Deep Eutectic Solvents for Green Sensing Applications: Curcuminoids in Curcuma longa Powder; American Chemical Society Inc; ACS Sustainable Chemistry and Engeneering; 9; 15; 7-4-2021; 5405-54112168-0485CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acssuschemeng.1c00406info:eu-repo/semantics/altIdentifier/doi/10.1021/acssuschemeng.1c00406info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:00:47Zoai:ri.conicet.gov.ar:11336/168979instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:00:47.717CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Native Fluorescent Natural Deep Eutectic Solvents for Green Sensing Applications: Curcuminoids in Curcuma longa Powder
title Native Fluorescent Natural Deep Eutectic Solvents for Green Sensing Applications: Curcuminoids in Curcuma longa Powder
spellingShingle Native Fluorescent Natural Deep Eutectic Solvents for Green Sensing Applications: Curcuminoids in Curcuma longa Powder
Lorenzetti, Anabela Silvana
3D-PRINTED DEVICE
AGREE METRIC
CURCUMINOIDS
FLUORESCENCE
GREEN ANALYTICAL CHEMISTRY
NADES
ULTRASOUND PROBE
title_short Native Fluorescent Natural Deep Eutectic Solvents for Green Sensing Applications: Curcuminoids in Curcuma longa Powder
title_full Native Fluorescent Natural Deep Eutectic Solvents for Green Sensing Applications: Curcuminoids in Curcuma longa Powder
title_fullStr Native Fluorescent Natural Deep Eutectic Solvents for Green Sensing Applications: Curcuminoids in Curcuma longa Powder
title_full_unstemmed Native Fluorescent Natural Deep Eutectic Solvents for Green Sensing Applications: Curcuminoids in Curcuma longa Powder
title_sort Native Fluorescent Natural Deep Eutectic Solvents for Green Sensing Applications: Curcuminoids in Curcuma longa Powder
dc.creator.none.fl_str_mv Lorenzetti, Anabela Silvana
Vidal, Ezequiel Martin
Silva, María Fernanda
Domini, Claudia Elizabeth
Gomez, Federico Jose Vicente
author Lorenzetti, Anabela Silvana
author_facet Lorenzetti, Anabela Silvana
Vidal, Ezequiel Martin
Silva, María Fernanda
Domini, Claudia Elizabeth
Gomez, Federico Jose Vicente
author_role author
author2 Vidal, Ezequiel Martin
Silva, María Fernanda
Domini, Claudia Elizabeth
Gomez, Federico Jose Vicente
author2_role author
author
author
author
dc.subject.none.fl_str_mv 3D-PRINTED DEVICE
AGREE METRIC
CURCUMINOIDS
FLUORESCENCE
GREEN ANALYTICAL CHEMISTRY
NADES
ULTRASOUND PROBE
topic 3D-PRINTED DEVICE
AGREE METRIC
CURCUMINOIDS
FLUORESCENCE
GREEN ANALYTICAL CHEMISTRY
NADES
ULTRASOUND PROBE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Natural deep eutectic solvents are a trending topic in Green Chemistry. These solvents present high solubilization capacity, reusability, tunable properties, simple preparation, biodegradability, safety, high availability, and low cost, making them excellent candidates for analytical applications. In this work, a new family of fluorescent eutectic systems is described, with the fluorescence property being unknown and unused so far. For this purpose, a novel preparation method using an ultrasound probe was employed, by means of an innovative single-step procedure, that included the preparation of FCH (fructose, citric acid, and water, 1:1:5 molar ratio) and the extraction/determination of curcuminoids from Curcuma longa powder. This methodology was successfully carried out by employing a portable and inexpensive 3D-printed fluorometer and a smartphone. In this way, extraction efficiencies between 90 and 106%, relative to the NIST reference method, were obtained in just 3.40 min. Besides, the greenness of the new methodology was evaluated by employing the AGREE metric, showing that the developed approach is >2.5 times greener than previously published works for curcuminoid determination. This groundbreaking procedure is robust, versatile, and simple to implement, does not require sophisticated apparatus or instruments in the detection step, and, mainly, agrees with Green Analytical Chemistry (GAC) principles.
Fil: Lorenzetti, Anabela Silvana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; Argentina
Fil: Vidal, Ezequiel Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Silva, María Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; Argentina
Fil: Domini, Claudia Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Gomez, Federico Jose Vicente. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; Argentina
description Natural deep eutectic solvents are a trending topic in Green Chemistry. These solvents present high solubilization capacity, reusability, tunable properties, simple preparation, biodegradability, safety, high availability, and low cost, making them excellent candidates for analytical applications. In this work, a new family of fluorescent eutectic systems is described, with the fluorescence property being unknown and unused so far. For this purpose, a novel preparation method using an ultrasound probe was employed, by means of an innovative single-step procedure, that included the preparation of FCH (fructose, citric acid, and water, 1:1:5 molar ratio) and the extraction/determination of curcuminoids from Curcuma longa powder. This methodology was successfully carried out by employing a portable and inexpensive 3D-printed fluorometer and a smartphone. In this way, extraction efficiencies between 90 and 106%, relative to the NIST reference method, were obtained in just 3.40 min. Besides, the greenness of the new methodology was evaluated by employing the AGREE metric, showing that the developed approach is >2.5 times greener than previously published works for curcuminoid determination. This groundbreaking procedure is robust, versatile, and simple to implement, does not require sophisticated apparatus or instruments in the detection step, and, mainly, agrees with Green Analytical Chemistry (GAC) principles.
publishDate 2021
dc.date.none.fl_str_mv 2021-04-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/168979
Lorenzetti, Anabela Silvana; Vidal, Ezequiel Martin; Silva, María Fernanda; Domini, Claudia Elizabeth; Gomez, Federico Jose Vicente; Native Fluorescent Natural Deep Eutectic Solvents for Green Sensing Applications: Curcuminoids in Curcuma longa Powder; American Chemical Society Inc; ACS Sustainable Chemistry and Engeneering; 9; 15; 7-4-2021; 5405-5411
2168-0485
CONICET Digital
CONICET
url http://hdl.handle.net/11336/168979
identifier_str_mv Lorenzetti, Anabela Silvana; Vidal, Ezequiel Martin; Silva, María Fernanda; Domini, Claudia Elizabeth; Gomez, Federico Jose Vicente; Native Fluorescent Natural Deep Eutectic Solvents for Green Sensing Applications: Curcuminoids in Curcuma longa Powder; American Chemical Society Inc; ACS Sustainable Chemistry and Engeneering; 9; 15; 7-4-2021; 5405-5411
2168-0485
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acssuschemeng.1c00406
info:eu-repo/semantics/altIdentifier/doi/10.1021/acssuschemeng.1c00406
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society Inc
publisher.none.fl_str_mv American Chemical Society Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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