Applying response surface design to the optimization of methane activation with ethane over Zn-H-ZSM-11 zeolite

Autores
Anunziata, Oscar Alfredo; Cussa, Jorgelina
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Experiment design—response surface methodology (RSM) is used to model and to optimize the activation of methane (C1) using ethane (C2) as co-reactant into higher hydrocarbons, over Zn-containing zeolite catalyst. The application of this methodology allows a better understanding of the influence of the different factors: time on stream (TOS), space velocity of C2 (GHSV-C2), molar fraction of C1/(C1 + C2) (XC1) and reaction temperature, on the C1 conversion, reducing the operation costs, achieving efficiency and effectiveness of this process. Box–Behnken design was development with different levels of the factors, determining its influence on the C1 conversion in order to obtain responses surfaces. In this way, we found the best combination in the reaction parameters that allowed us to optimize the process. The results indicated that the reaction time, the XC1 and the interactions of the TOS–temperature factors, have the main influence on C1 conversion, in agreement with the experimental results reported previously.
Fil: Anunziata, Oscar Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Inv. y Tecnología Química. Grupo Fisicoquímica de Nuevos Materiales; Argentina
Fil: Cussa, Jorgelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Inv. y Tecnología Química. Grupo Fisicoquímica de Nuevos Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
Materia
Experiment design
Response surface Optimization
Methane activation, Ethane co-reactant
Aromatic Yields
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/244164
Acceder
id CONICETDig_6ecf4c0391340fe147760ef990bb79f4
oai_identifier_str oai:ri.conicet.gov.ar:11336/244164
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Applying response surface design to the optimization of methane activation with ethane over Zn-H-ZSM-11 zeoliteAnunziata, Oscar AlfredoCussa, JorgelinaExperiment designResponse surface OptimizationMethane activation, Ethane co-reactantAromatic Yieldshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Experiment design—response surface methodology (RSM) is used to model and to optimize the activation of methane (C1) using ethane (C2) as co-reactant into higher hydrocarbons, over Zn-containing zeolite catalyst. The application of this methodology allows a better understanding of the influence of the different factors: time on stream (TOS), space velocity of C2 (GHSV-C2), molar fraction of C1/(C1 + C2) (XC1) and reaction temperature, on the C1 conversion, reducing the operation costs, achieving efficiency and effectiveness of this process. Box–Behnken design was development with different levels of the factors, determining its influence on the C1 conversion in order to obtain responses surfaces. In this way, we found the best combination in the reaction parameters that allowed us to optimize the process. The results indicated that the reaction time, the XC1 and the interactions of the TOS–temperature factors, have the main influence on C1 conversion, in agreement with the experimental results reported previously.Fil: Anunziata, Oscar Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Inv. y Tecnología Química. Grupo Fisicoquímica de Nuevos Materiales; ArgentinaFil: Cussa, Jorgelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Inv. y Tecnología Química. Grupo Fisicoquímica de Nuevos Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; ArgentinaElsevier Science SA2008-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/244164Anunziata, Oscar Alfredo; Cussa, Jorgelina; Applying response surface design to the optimization of methane activation with ethane over Zn-H-ZSM-11 zeolite; Elsevier Science SA; Chemical Engineering Journal; 138; 1-3; 5-2008; 510-5161385-8947CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1385894707005116info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2007.07.033info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:43:52Zoai:ri.conicet.gov.ar:11336/244164instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:43:53.156CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Applying response surface design to the optimization of methane activation with ethane over Zn-H-ZSM-11 zeolite
title Applying response surface design to the optimization of methane activation with ethane over Zn-H-ZSM-11 zeolite
spellingShingle Applying response surface design to the optimization of methane activation with ethane over Zn-H-ZSM-11 zeolite
Anunziata, Oscar Alfredo
Experiment design
Response surface Optimization
Methane activation, Ethane co-reactant
Aromatic Yields
title_short Applying response surface design to the optimization of methane activation with ethane over Zn-H-ZSM-11 zeolite
title_full Applying response surface design to the optimization of methane activation with ethane over Zn-H-ZSM-11 zeolite
title_fullStr Applying response surface design to the optimization of methane activation with ethane over Zn-H-ZSM-11 zeolite
title_full_unstemmed Applying response surface design to the optimization of methane activation with ethane over Zn-H-ZSM-11 zeolite
title_sort Applying response surface design to the optimization of methane activation with ethane over Zn-H-ZSM-11 zeolite
dc.creator.none.fl_str_mv Anunziata, Oscar Alfredo
Cussa, Jorgelina
author Anunziata, Oscar Alfredo
author_facet Anunziata, Oscar Alfredo
Cussa, Jorgelina
author_role author
author2 Cussa, Jorgelina
author2_role author
dc.subject.none.fl_str_mv Experiment design
Response surface Optimization
Methane activation, Ethane co-reactant
Aromatic Yields
topic Experiment design
Response surface Optimization
Methane activation, Ethane co-reactant
Aromatic Yields
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Experiment design—response surface methodology (RSM) is used to model and to optimize the activation of methane (C1) using ethane (C2) as co-reactant into higher hydrocarbons, over Zn-containing zeolite catalyst. The application of this methodology allows a better understanding of the influence of the different factors: time on stream (TOS), space velocity of C2 (GHSV-C2), molar fraction of C1/(C1 + C2) (XC1) and reaction temperature, on the C1 conversion, reducing the operation costs, achieving efficiency and effectiveness of this process. Box–Behnken design was development with different levels of the factors, determining its influence on the C1 conversion in order to obtain responses surfaces. In this way, we found the best combination in the reaction parameters that allowed us to optimize the process. The results indicated that the reaction time, the XC1 and the interactions of the TOS–temperature factors, have the main influence on C1 conversion, in agreement with the experimental results reported previously.
Fil: Anunziata, Oscar Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Inv. y Tecnología Química. Grupo Fisicoquímica de Nuevos Materiales; Argentina
Fil: Cussa, Jorgelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Inv. y Tecnología Química. Grupo Fisicoquímica de Nuevos Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
description Experiment design—response surface methodology (RSM) is used to model and to optimize the activation of methane (C1) using ethane (C2) as co-reactant into higher hydrocarbons, over Zn-containing zeolite catalyst. The application of this methodology allows a better understanding of the influence of the different factors: time on stream (TOS), space velocity of C2 (GHSV-C2), molar fraction of C1/(C1 + C2) (XC1) and reaction temperature, on the C1 conversion, reducing the operation costs, achieving efficiency and effectiveness of this process. Box–Behnken design was development with different levels of the factors, determining its influence on the C1 conversion in order to obtain responses surfaces. In this way, we found the best combination in the reaction parameters that allowed us to optimize the process. The results indicated that the reaction time, the XC1 and the interactions of the TOS–temperature factors, have the main influence on C1 conversion, in agreement with the experimental results reported previously.
publishDate 2008
dc.date.none.fl_str_mv 2008-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/244164
Anunziata, Oscar Alfredo; Cussa, Jorgelina; Applying response surface design to the optimization of methane activation with ethane over Zn-H-ZSM-11 zeolite; Elsevier Science SA; Chemical Engineering Journal; 138; 1-3; 5-2008; 510-516
1385-8947
CONICET Digital
CONICET
url http://hdl.handle.net/11336/244164
identifier_str_mv Anunziata, Oscar Alfredo; Cussa, Jorgelina; Applying response surface design to the optimization of methane activation with ethane over Zn-H-ZSM-11 zeolite; Elsevier Science SA; Chemical Engineering Journal; 138; 1-3; 5-2008; 510-516
1385-8947
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1385894707005116
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2007.07.033
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science SA
publisher.none.fl_str_mv Elsevier Science SA
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613380875223040
score 13.070432

Publicaciones similares