Methane Activation Process: Simultaneous Optimization of Methane Conversion and Aromatic Yields using Zn-ZSM-11 Zeolite

Autores
Anunziata, Oscar Alfred; Cussa, Jorgelina
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Experiment Design – Response Surface Methodology (RSM) is used to model and to optimize the activation of Methane (C1) using Ethane (C2) as co-reactant into higher hydrocarbons, over Zn-containing zeolite catalyst. The application of this methodology in this work, allows a better understanding of the influence of the different factors; on two responses simultaneously: C1 Conversion and Aromatic Hydrocarbons Yields. Box-Behnken Design was developmentand the Responses Surfaces were defined, finding the best combination in the reaction parameters in order to optimize the process. Applying the statistic methodology, the best operation conditions obtained are: high C1 conversion (48.6 mol% C) and Aromatic Hydrocarbons Yields (47.2 mol%) were achieved working at these conditions, advancing to the results recently reported by us, where only one objective function (C1 conversion) was optimized.
Fil: Anunziata, Oscar Alfred. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Cussa, Jorgelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Materia
Experiment Design,
Response Surface
Two Responses Optimization
Methane activation, ethane co-reactant
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/110659
Acceder
id CONICETDig_4b73c71d119128efc916f2e5a60bcb48
oai_identifier_str oai:ri.conicet.gov.ar:11336/110659
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Methane Activation Process: Simultaneous Optimization of Methane Conversion and Aromatic Yields using Zn-ZSM-11 ZeoliteAnunziata, Oscar AlfredCussa, JorgelinaExperiment Design,Response SurfaceTwo Responses OptimizationMethane activation, ethane co-reactanthttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Experiment Design – Response Surface Methodology (RSM) is used to model and to optimize the activation of Methane (C1) using Ethane (C2) as co-reactant into higher hydrocarbons, over Zn-containing zeolite catalyst. The application of this methodology in this work, allows a better understanding of the influence of the different factors; on two responses simultaneously: C1 Conversion and Aromatic Hydrocarbons Yields. Box-Behnken Design was developmentand the Responses Surfaces were defined, finding the best combination in the reaction parameters in order to optimize the process. Applying the statistic methodology, the best operation conditions obtained are: high C1 conversion (48.6 mol% C) and Aromatic Hydrocarbons Yields (47.2 mol%) were achieved working at these conditions, advancing to the results recently reported by us, where only one objective function (C1 conversion) was optimized.Fil: Anunziata, Oscar Alfred. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Cussa, Jorgelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaBentham Science2010-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/110659Anunziata, Oscar Alfred; Cussa, Jorgelina; Methane Activation Process: Simultaneous Optimization of Methane Conversion and Aromatic Yields using Zn-ZSM-11 Zeolite; Bentham Science; The Open Process Chemistry Journal; 3; 1; 5-2010; 7-161875-1806CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://benthamopen.com/ABSTRACT/TOCPCJ-3-7info:eu-repo/semantics/altIdentifier/doi/10.2174/1875180601003010007info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:41:50Zoai:ri.conicet.gov.ar:11336/110659instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:41:50.548CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Methane Activation Process: Simultaneous Optimization of Methane Conversion and Aromatic Yields using Zn-ZSM-11 Zeolite
title Methane Activation Process: Simultaneous Optimization of Methane Conversion and Aromatic Yields using Zn-ZSM-11 Zeolite
spellingShingle Methane Activation Process: Simultaneous Optimization of Methane Conversion and Aromatic Yields using Zn-ZSM-11 Zeolite
Anunziata, Oscar Alfred
Experiment Design,
Response Surface
Two Responses Optimization
Methane activation, ethane co-reactant
title_short Methane Activation Process: Simultaneous Optimization of Methane Conversion and Aromatic Yields using Zn-ZSM-11 Zeolite
title_full Methane Activation Process: Simultaneous Optimization of Methane Conversion and Aromatic Yields using Zn-ZSM-11 Zeolite
title_fullStr Methane Activation Process: Simultaneous Optimization of Methane Conversion and Aromatic Yields using Zn-ZSM-11 Zeolite
title_full_unstemmed Methane Activation Process: Simultaneous Optimization of Methane Conversion and Aromatic Yields using Zn-ZSM-11 Zeolite
title_sort Methane Activation Process: Simultaneous Optimization of Methane Conversion and Aromatic Yields using Zn-ZSM-11 Zeolite
dc.creator.none.fl_str_mv Anunziata, Oscar Alfred
Cussa, Jorgelina
author Anunziata, Oscar Alfred
author_facet Anunziata, Oscar Alfred
Cussa, Jorgelina
author_role author
author2 Cussa, Jorgelina
author2_role author
dc.subject.none.fl_str_mv Experiment Design,
Response Surface
Two Responses Optimization
Methane activation, ethane co-reactant
topic Experiment Design,
Response Surface
Two Responses Optimization
Methane activation, ethane co-reactant
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Experiment Design – Response Surface Methodology (RSM) is used to model and to optimize the activation of Methane (C1) using Ethane (C2) as co-reactant into higher hydrocarbons, over Zn-containing zeolite catalyst. The application of this methodology in this work, allows a better understanding of the influence of the different factors; on two responses simultaneously: C1 Conversion and Aromatic Hydrocarbons Yields. Box-Behnken Design was developmentand the Responses Surfaces were defined, finding the best combination in the reaction parameters in order to optimize the process. Applying the statistic methodology, the best operation conditions obtained are: high C1 conversion (48.6 mol% C) and Aromatic Hydrocarbons Yields (47.2 mol%) were achieved working at these conditions, advancing to the results recently reported by us, where only one objective function (C1 conversion) was optimized.
Fil: Anunziata, Oscar Alfred. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Cussa, Jorgelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
description Experiment Design – Response Surface Methodology (RSM) is used to model and to optimize the activation of Methane (C1) using Ethane (C2) as co-reactant into higher hydrocarbons, over Zn-containing zeolite catalyst. The application of this methodology in this work, allows a better understanding of the influence of the different factors; on two responses simultaneously: C1 Conversion and Aromatic Hydrocarbons Yields. Box-Behnken Design was developmentand the Responses Surfaces were defined, finding the best combination in the reaction parameters in order to optimize the process. Applying the statistic methodology, the best operation conditions obtained are: high C1 conversion (48.6 mol% C) and Aromatic Hydrocarbons Yields (47.2 mol%) were achieved working at these conditions, advancing to the results recently reported by us, where only one objective function (C1 conversion) was optimized.
publishDate 2010
dc.date.none.fl_str_mv 2010-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/110659
Anunziata, Oscar Alfred; Cussa, Jorgelina; Methane Activation Process: Simultaneous Optimization of Methane Conversion and Aromatic Yields using Zn-ZSM-11 Zeolite; Bentham Science; The Open Process Chemistry Journal; 3; 1; 5-2010; 7-16
1875-1806
CONICET Digital
CONICET
url http://hdl.handle.net/11336/110659
identifier_str_mv Anunziata, Oscar Alfred; Cussa, Jorgelina; Methane Activation Process: Simultaneous Optimization of Methane Conversion and Aromatic Yields using Zn-ZSM-11 Zeolite; Bentham Science; The Open Process Chemistry Journal; 3; 1; 5-2010; 7-16
1875-1806
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://benthamopen.com/ABSTRACT/TOCPCJ-3-7
info:eu-repo/semantics/altIdentifier/doi/10.2174/1875180601003010007
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Bentham Science
publisher.none.fl_str_mv Bentham Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613319358414848
score 13.070432

Publicaciones similares