NO reduction with CO on alumina-modified silica-supported palladium and molybdenum-palladium catalysts
- Autores
- Díaz Cónsul, Julia María; Costilla, Ignacio Oscar; Gigola, Carlos Eugenio; Baibich, Ione Maluf
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In this work, Pd and Mo-Pd catalysts supported on Al2O3 modified SiO2 and Si-MCM-41 materials were prepared, characterized by H2 chemisorption and FTIR spectroscopy of adsorbed CO and NO and tested for the reduction of NO with CO. The characterization results indicated that in the bimetallic catalysts, Mo that is loaded first, migrates over the Pd atoms and reduced the fraction of exposed metal atoms. The reduction of NO with CO at 523 K showed that the specific activity for NO conversion increased as a result of the Pd-Mo interaction. In the 523–573 K temperature range NH3 was produced in addition to CO2, N2 and N2O. This result suggests the reaction of NCO species formed on the Pd surface with OH groups of the support materials to produce isocyanic acid (HNCO) that is hydrolyzed to NH3. The catalysts exhibited a decreasing selectivity to N2O and a parallel increase in the production of N2 and NH3 as the conversion increases. The effect of Mo on the reaction selectivity was clear for Pd/Al2O3/SiO2; at similar NO conversion level the selectivity to N2O and N2 decreased with increasing NH3 formation. FTIR spectra of adsorbed species under reaction conditions demonstrated the absence of isocyanate species and the presence of NH4 + ions in accordance with the high Brønsted acidity of the support materials.
Fil: Díaz Cónsul, Julia María. Universidade Federal do Rio Grande do Sul; Brasil
Fil: Costilla, Ignacio Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Gigola, Carlos Eugenio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Baibich, Ione Maluf. Universidade Federal do Rio Grande do Sul; Brasil - Materia
-
Mcm-41
Mo-Pd Catalyst
Pd Catalyst
No Reduction with Co - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/41976
Ver los metadatos del registro completo
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NO reduction with CO on alumina-modified silica-supported palladium and molybdenum-palladium catalystsDíaz Cónsul, Julia MaríaCostilla, Ignacio OscarGigola, Carlos EugenioBaibich, Ione MalufMcm-41Mo-Pd CatalystPd CatalystNo Reduction with Cohttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In this work, Pd and Mo-Pd catalysts supported on Al2O3 modified SiO2 and Si-MCM-41 materials were prepared, characterized by H2 chemisorption and FTIR spectroscopy of adsorbed CO and NO and tested for the reduction of NO with CO. The characterization results indicated that in the bimetallic catalysts, Mo that is loaded first, migrates over the Pd atoms and reduced the fraction of exposed metal atoms. The reduction of NO with CO at 523 K showed that the specific activity for NO conversion increased as a result of the Pd-Mo interaction. In the 523–573 K temperature range NH3 was produced in addition to CO2, N2 and N2O. This result suggests the reaction of NCO species formed on the Pd surface with OH groups of the support materials to produce isocyanic acid (HNCO) that is hydrolyzed to NH3. The catalysts exhibited a decreasing selectivity to N2O and a parallel increase in the production of N2 and NH3 as the conversion increases. The effect of Mo on the reaction selectivity was clear for Pd/Al2O3/SiO2; at similar NO conversion level the selectivity to N2O and N2 decreased with increasing NH3 formation. FTIR spectra of adsorbed species under reaction conditions demonstrated the absence of isocyanate species and the presence of NH4 + ions in accordance with the high Brønsted acidity of the support materials.Fil: Díaz Cónsul, Julia María. Universidade Federal do Rio Grande do Sul; BrasilFil: Costilla, Ignacio Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Gigola, Carlos Eugenio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Baibich, Ione Maluf. Universidade Federal do Rio Grande do Sul; BrasilElsevier Science2008-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/41976Díaz Cónsul, Julia María; Costilla, Ignacio Oscar; Gigola, Carlos Eugenio; Baibich, Ione Maluf; NO reduction with CO on alumina-modified silica-supported palladium and molybdenum-palladium catalysts; Elsevier Science; Applied Catalysis A: General; 339; 2; 5-2008; 151-1580926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2008.01.022info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X08000422info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:47:43Zoai:ri.conicet.gov.ar:11336/41976instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:47:43.722CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
NO reduction with CO on alumina-modified silica-supported palladium and molybdenum-palladium catalysts |
title |
NO reduction with CO on alumina-modified silica-supported palladium and molybdenum-palladium catalysts |
spellingShingle |
NO reduction with CO on alumina-modified silica-supported palladium and molybdenum-palladium catalysts Díaz Cónsul, Julia María Mcm-41 Mo-Pd Catalyst Pd Catalyst No Reduction with Co |
title_short |
NO reduction with CO on alumina-modified silica-supported palladium and molybdenum-palladium catalysts |
title_full |
NO reduction with CO on alumina-modified silica-supported palladium and molybdenum-palladium catalysts |
title_fullStr |
NO reduction with CO on alumina-modified silica-supported palladium and molybdenum-palladium catalysts |
title_full_unstemmed |
NO reduction with CO on alumina-modified silica-supported palladium and molybdenum-palladium catalysts |
title_sort |
NO reduction with CO on alumina-modified silica-supported palladium and molybdenum-palladium catalysts |
dc.creator.none.fl_str_mv |
Díaz Cónsul, Julia María Costilla, Ignacio Oscar Gigola, Carlos Eugenio Baibich, Ione Maluf |
author |
Díaz Cónsul, Julia María |
author_facet |
Díaz Cónsul, Julia María Costilla, Ignacio Oscar Gigola, Carlos Eugenio Baibich, Ione Maluf |
author_role |
author |
author2 |
Costilla, Ignacio Oscar Gigola, Carlos Eugenio Baibich, Ione Maluf |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Mcm-41 Mo-Pd Catalyst Pd Catalyst No Reduction with Co |
topic |
Mcm-41 Mo-Pd Catalyst Pd Catalyst No Reduction with Co |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
In this work, Pd and Mo-Pd catalysts supported on Al2O3 modified SiO2 and Si-MCM-41 materials were prepared, characterized by H2 chemisorption and FTIR spectroscopy of adsorbed CO and NO and tested for the reduction of NO with CO. The characterization results indicated that in the bimetallic catalysts, Mo that is loaded first, migrates over the Pd atoms and reduced the fraction of exposed metal atoms. The reduction of NO with CO at 523 K showed that the specific activity for NO conversion increased as a result of the Pd-Mo interaction. In the 523–573 K temperature range NH3 was produced in addition to CO2, N2 and N2O. This result suggests the reaction of NCO species formed on the Pd surface with OH groups of the support materials to produce isocyanic acid (HNCO) that is hydrolyzed to NH3. The catalysts exhibited a decreasing selectivity to N2O and a parallel increase in the production of N2 and NH3 as the conversion increases. The effect of Mo on the reaction selectivity was clear for Pd/Al2O3/SiO2; at similar NO conversion level the selectivity to N2O and N2 decreased with increasing NH3 formation. FTIR spectra of adsorbed species under reaction conditions demonstrated the absence of isocyanate species and the presence of NH4 + ions in accordance with the high Brønsted acidity of the support materials. Fil: Díaz Cónsul, Julia María. Universidade Federal do Rio Grande do Sul; Brasil Fil: Costilla, Ignacio Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Gigola, Carlos Eugenio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Baibich, Ione Maluf. Universidade Federal do Rio Grande do Sul; Brasil |
description |
In this work, Pd and Mo-Pd catalysts supported on Al2O3 modified SiO2 and Si-MCM-41 materials were prepared, characterized by H2 chemisorption and FTIR spectroscopy of adsorbed CO and NO and tested for the reduction of NO with CO. The characterization results indicated that in the bimetallic catalysts, Mo that is loaded first, migrates over the Pd atoms and reduced the fraction of exposed metal atoms. The reduction of NO with CO at 523 K showed that the specific activity for NO conversion increased as a result of the Pd-Mo interaction. In the 523–573 K temperature range NH3 was produced in addition to CO2, N2 and N2O. This result suggests the reaction of NCO species formed on the Pd surface with OH groups of the support materials to produce isocyanic acid (HNCO) that is hydrolyzed to NH3. The catalysts exhibited a decreasing selectivity to N2O and a parallel increase in the production of N2 and NH3 as the conversion increases. The effect of Mo on the reaction selectivity was clear for Pd/Al2O3/SiO2; at similar NO conversion level the selectivity to N2O and N2 decreased with increasing NH3 formation. FTIR spectra of adsorbed species under reaction conditions demonstrated the absence of isocyanate species and the presence of NH4 + ions in accordance with the high Brønsted acidity of the support materials. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-05 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/41976 Díaz Cónsul, Julia María; Costilla, Ignacio Oscar; Gigola, Carlos Eugenio; Baibich, Ione Maluf; NO reduction with CO on alumina-modified silica-supported palladium and molybdenum-palladium catalysts; Elsevier Science; Applied Catalysis A: General; 339; 2; 5-2008; 151-158 0926-860X CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/41976 |
identifier_str_mv |
Díaz Cónsul, Julia María; Costilla, Ignacio Oscar; Gigola, Carlos Eugenio; Baibich, Ione Maluf; NO reduction with CO on alumina-modified silica-supported palladium and molybdenum-palladium catalysts; Elsevier Science; Applied Catalysis A: General; 339; 2; 5-2008; 151-158 0926-860X CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2008.01.022 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X08000422 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842268876752027648 |
score |
13.13397 |