Graphite oxide as a support for palladium and rhodium complexes, assessed as catalysts for the partial hydrogenation of 1-heptyne
- Autores
- Liprandi, Domingo Antonio; Cagnola, Edgardo Alberto; Mastalir, A.; Szabó, A.; Paredes, J.; Martínez Bovier, Luciana; Betti, Carolina Paola; Badano, Juan Manuel; Lederhos, Cecilia Rosa; Quiroga, Monica Esther
- Año de publicación
- 2020
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Graphite oxide (GO) was used to anchor [PdCl2(TDA)2] and [RhCl(TDA)3] (TDA = NH2(CH2)12CH3) with 2wt % of metal load. Elemental analysis (EA), FTIR, XPS, XRD and atomic absorption spectroscopy (AA) were the techniques employed for characterization. FTIR and XRD revealed that both complexes were mainly immobilized on the GO surface. The partial hydrogenation of 1-heptyne was the test reaction to evaluate the catalytic behavior of these heterogenized complexes under mild conditions of temperature and pressure in a semi continuous process. The results were compared with those obtained with the Wilkinson catalyst under the same operational conditions. AA analysis revealed that there is no leaching of the complexes during the heterogeneous catalytic evaluations. [RhCl(TDA)3]/GO was the best catalyst due to electronic and steric effects as well as the influence of the support.
Fil: Liprandi, Domingo Antonio. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina
Fil: Cagnola, Edgardo Alberto. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina
Fil: Mastalir, A.. University Of Szeged; Hungría
Fil: Szabó, A.. University Of Szeged; Hungría
Fil: Paredes, J.. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina
Fil: Martínez Bovier, Luciana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Betti, Carolina Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Badano, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Lederhos, Cecilia Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina - Materia
-
GRAPHITE OXIDE
PD(II) AND RH(I) COMPLEXES
WILKINSON CATALYST
1-HEPTYNE
HETEROGENEOUS SELECTIVE HYDROGENATION - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/145711
Ver los metadatos del registro completo
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CONICET Digital (CONICET) |
spelling |
Graphite oxide as a support for palladium and rhodium complexes, assessed as catalysts for the partial hydrogenation of 1-heptyneLiprandi, Domingo AntonioCagnola, Edgardo AlbertoMastalir, A.Szabó, A.Paredes, J.Martínez Bovier, LucianaBetti, Carolina PaolaBadano, Juan ManuelLederhos, Cecilia RosaQuiroga, Monica EstherGRAPHITE OXIDEPD(II) AND RH(I) COMPLEXESWILKINSON CATALYST1-HEPTYNEHETEROGENEOUS SELECTIVE HYDROGENATIONhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Graphite oxide (GO) was used to anchor [PdCl2(TDA)2] and [RhCl(TDA)3] (TDA = NH2(CH2)12CH3) with 2wt % of metal load. Elemental analysis (EA), FTIR, XPS, XRD and atomic absorption spectroscopy (AA) were the techniques employed for characterization. FTIR and XRD revealed that both complexes were mainly immobilized on the GO surface. The partial hydrogenation of 1-heptyne was the test reaction to evaluate the catalytic behavior of these heterogenized complexes under mild conditions of temperature and pressure in a semi continuous process. The results were compared with those obtained with the Wilkinson catalyst under the same operational conditions. AA analysis revealed that there is no leaching of the complexes during the heterogeneous catalytic evaluations. [RhCl(TDA)3]/GO was the best catalyst due to electronic and steric effects as well as the influence of the support.Fil: Liprandi, Domingo Antonio. Universidad Nacional del Litoral. Facultad de Ingeniería Química; ArgentinaFil: Cagnola, Edgardo Alberto. Universidad Nacional del Litoral. Facultad de Ingeniería Química; ArgentinaFil: Mastalir, A.. University Of Szeged; HungríaFil: Szabó, A.. University Of Szeged; HungríaFil: Paredes, J.. Universidad Nacional del Litoral. Facultad de Ingeniería Química; ArgentinaFil: Martínez Bovier, Luciana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Betti, Carolina Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Badano, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Lederhos, Cecilia Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaMedCrave2020-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/145711Liprandi, Domingo Antonio; Cagnola, Edgardo Alberto; Mastalir, A.; Szabó, A.; Paredes, J.; et al.; Graphite oxide as a support for palladium and rhodium complexes, assessed as catalysts for the partial hydrogenation of 1-heptyne; MedCrave; Material Science & Engineering International Journal; 4; 8-2020; 110-1152574-9927CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.15406/mseij.2020.04.00136info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:46:36Zoai:ri.conicet.gov.ar:11336/145711instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:46:36.71CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Graphite oxide as a support for palladium and rhodium complexes, assessed as catalysts for the partial hydrogenation of 1-heptyne |
title |
Graphite oxide as a support for palladium and rhodium complexes, assessed as catalysts for the partial hydrogenation of 1-heptyne |
spellingShingle |
Graphite oxide as a support for palladium and rhodium complexes, assessed as catalysts for the partial hydrogenation of 1-heptyne Liprandi, Domingo Antonio GRAPHITE OXIDE PD(II) AND RH(I) COMPLEXES WILKINSON CATALYST 1-HEPTYNE HETEROGENEOUS SELECTIVE HYDROGENATION |
title_short |
Graphite oxide as a support for palladium and rhodium complexes, assessed as catalysts for the partial hydrogenation of 1-heptyne |
title_full |
Graphite oxide as a support for palladium and rhodium complexes, assessed as catalysts for the partial hydrogenation of 1-heptyne |
title_fullStr |
Graphite oxide as a support for palladium and rhodium complexes, assessed as catalysts for the partial hydrogenation of 1-heptyne |
title_full_unstemmed |
Graphite oxide as a support for palladium and rhodium complexes, assessed as catalysts for the partial hydrogenation of 1-heptyne |
title_sort |
Graphite oxide as a support for palladium and rhodium complexes, assessed as catalysts for the partial hydrogenation of 1-heptyne |
dc.creator.none.fl_str_mv |
Liprandi, Domingo Antonio Cagnola, Edgardo Alberto Mastalir, A. Szabó, A. Paredes, J. Martínez Bovier, Luciana Betti, Carolina Paola Badano, Juan Manuel Lederhos, Cecilia Rosa Quiroga, Monica Esther |
author |
Liprandi, Domingo Antonio |
author_facet |
Liprandi, Domingo Antonio Cagnola, Edgardo Alberto Mastalir, A. Szabó, A. Paredes, J. Martínez Bovier, Luciana Betti, Carolina Paola Badano, Juan Manuel Lederhos, Cecilia Rosa Quiroga, Monica Esther |
author_role |
author |
author2 |
Cagnola, Edgardo Alberto Mastalir, A. Szabó, A. Paredes, J. Martínez Bovier, Luciana Betti, Carolina Paola Badano, Juan Manuel Lederhos, Cecilia Rosa Quiroga, Monica Esther |
author2_role |
author author author author author author author author author |
dc.subject.none.fl_str_mv |
GRAPHITE OXIDE PD(II) AND RH(I) COMPLEXES WILKINSON CATALYST 1-HEPTYNE HETEROGENEOUS SELECTIVE HYDROGENATION |
topic |
GRAPHITE OXIDE PD(II) AND RH(I) COMPLEXES WILKINSON CATALYST 1-HEPTYNE HETEROGENEOUS SELECTIVE HYDROGENATION |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Graphite oxide (GO) was used to anchor [PdCl2(TDA)2] and [RhCl(TDA)3] (TDA = NH2(CH2)12CH3) with 2wt % of metal load. Elemental analysis (EA), FTIR, XPS, XRD and atomic absorption spectroscopy (AA) were the techniques employed for characterization. FTIR and XRD revealed that both complexes were mainly immobilized on the GO surface. The partial hydrogenation of 1-heptyne was the test reaction to evaluate the catalytic behavior of these heterogenized complexes under mild conditions of temperature and pressure in a semi continuous process. The results were compared with those obtained with the Wilkinson catalyst under the same operational conditions. AA analysis revealed that there is no leaching of the complexes during the heterogeneous catalytic evaluations. [RhCl(TDA)3]/GO was the best catalyst due to electronic and steric effects as well as the influence of the support. Fil: Liprandi, Domingo Antonio. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina Fil: Cagnola, Edgardo Alberto. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina Fil: Mastalir, A.. University Of Szeged; Hungría Fil: Szabó, A.. University Of Szeged; Hungría Fil: Paredes, J.. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina Fil: Martínez Bovier, Luciana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Betti, Carolina Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Badano, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Lederhos, Cecilia Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina |
description |
Graphite oxide (GO) was used to anchor [PdCl2(TDA)2] and [RhCl(TDA)3] (TDA = NH2(CH2)12CH3) with 2wt % of metal load. Elemental analysis (EA), FTIR, XPS, XRD and atomic absorption spectroscopy (AA) were the techniques employed for characterization. FTIR and XRD revealed that both complexes were mainly immobilized on the GO surface. The partial hydrogenation of 1-heptyne was the test reaction to evaluate the catalytic behavior of these heterogenized complexes under mild conditions of temperature and pressure in a semi continuous process. The results were compared with those obtained with the Wilkinson catalyst under the same operational conditions. AA analysis revealed that there is no leaching of the complexes during the heterogeneous catalytic evaluations. [RhCl(TDA)3]/GO was the best catalyst due to electronic and steric effects as well as the influence of the support. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-08 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/145711 Liprandi, Domingo Antonio; Cagnola, Edgardo Alberto; Mastalir, A.; Szabó, A.; Paredes, J.; et al.; Graphite oxide as a support for palladium and rhodium complexes, assessed as catalysts for the partial hydrogenation of 1-heptyne; MedCrave; Material Science & Engineering International Journal; 4; 8-2020; 110-115 2574-9927 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/145711 |
identifier_str_mv |
Liprandi, Domingo Antonio; Cagnola, Edgardo Alberto; Mastalir, A.; Szabó, A.; Paredes, J.; et al.; Graphite oxide as a support for palladium and rhodium complexes, assessed as catalysts for the partial hydrogenation of 1-heptyne; MedCrave; Material Science & Engineering International Journal; 4; 8-2020; 110-115 2574-9927 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.15406/mseij.2020.04.00136 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
MedCrave |
publisher.none.fl_str_mv |
MedCrave |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842268806390480896 |
score |
13.13397 |