MCM-41-supported vanadium catalysts structurally modified with Al or Zr for thiophene hydrodesulfurization

Autores
Escalante Contreras, Yelisbeth Carolina; Méndez, Franklin J.; Díaz, Yraida; Inojosa, Marcel; Morgado, Myloa; Delgado, Miguel; Bastardo González, Ernesto; Brito, Joaquín L.
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Vanadium catalysts supported on Al(Zr)-MCM-41-type materials were prepared by impregnation. Textural and structural properties, elemental composition and electronic structure were determined by N2 physisorption, small-angle XRD, SEM?EDX and UV?vis DRS, respectively. Al-containing materials showed mostly of Al framework and a small fraction of Al extra-framework species. Zr-containing materials presented almost exclusively small clusters of ZrxOy covering the MCM-41 matrix. Vanadium catalysts, showed the presence of isolated V5+ species and to a lesser extent polymeric chains likely as small crystallites of V2O5. The catalytic results revealed that VAlM30 catalyst, characterized by a Si/Al atomic ratio of 30, was the most active in thiophene hydrodesulfurization, which could be associated to better textural properties and high dispersion of the vanadium species.
Fil: Escalante Contreras, Yelisbeth Carolina. Instituto Venezolano de Investigaciones Científicas; Venezuela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Méndez, Franklin J.. Instituto Venezolano de Investigaciones Científicas; Venezuela. Universidad Nacional Autónoma de México; México
Fil: Díaz, Yraida. Instituto Venezolano de Investigaciones Científicas; Venezuela
Fil: Inojosa, Marcel. Instituto Venezolano de Investigaciones Científicas; Venezuela
Fil: Morgado, Myloa. Instituto Venezolano de Investigaciones Científicas; Venezuela
Fil: Delgado, Miguel. Universidad de los Andes; Colombia
Fil: Bastardo González, Ernesto. Universidad de Oriente; Venezuela
Fil: Brito, Joaquín L.. Instituto Venezolano de Investigaciones Científicas; Venezuela
Materia
ALUMINOSILICATES
HYDRODESULFURIZATION
MODIFIED-MCM-41
VANADIUM CATALYSTS
ZIRCONIOSILICATES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/124912
Acceder
id CONICETDig_6b38a44120bc55c0b2c07edc46126691
oai_identifier_str oai:ri.conicet.gov.ar:11336/124912
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling MCM-41-supported vanadium catalysts structurally modified with Al or Zr for thiophene hydrodesulfurizationEscalante Contreras, Yelisbeth CarolinaMéndez, Franklin J.Díaz, YraidaInojosa, MarcelMorgado, MyloaDelgado, MiguelBastardo González, ErnestoBrito, Joaquín L.ALUMINOSILICATESHYDRODESULFURIZATIONMODIFIED-MCM-41VANADIUM CATALYSTSZIRCONIOSILICATEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Vanadium catalysts supported on Al(Zr)-MCM-41-type materials were prepared by impregnation. Textural and structural properties, elemental composition and electronic structure were determined by N2 physisorption, small-angle XRD, SEM?EDX and UV?vis DRS, respectively. Al-containing materials showed mostly of Al framework and a small fraction of Al extra-framework species. Zr-containing materials presented almost exclusively small clusters of ZrxOy covering the MCM-41 matrix. Vanadium catalysts, showed the presence of isolated V5+ species and to a lesser extent polymeric chains likely as small crystallites of V2O5. The catalytic results revealed that VAlM30 catalyst, characterized by a Si/Al atomic ratio of 30, was the most active in thiophene hydrodesulfurization, which could be associated to better textural properties and high dispersion of the vanadium species.Fil: Escalante Contreras, Yelisbeth Carolina. Instituto Venezolano de Investigaciones Científicas; Venezuela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Méndez, Franklin J.. Instituto Venezolano de Investigaciones Científicas; Venezuela. Universidad Nacional Autónoma de México; MéxicoFil: Díaz, Yraida. Instituto Venezolano de Investigaciones Científicas; VenezuelaFil: Inojosa, Marcel. Instituto Venezolano de Investigaciones Científicas; VenezuelaFil: Morgado, Myloa. Instituto Venezolano de Investigaciones Científicas; VenezuelaFil: Delgado, Miguel. Universidad de los Andes; ColombiaFil: Bastardo González, Ernesto. Universidad de Oriente; VenezuelaFil: Brito, Joaquín L.. Instituto Venezolano de Investigaciones Científicas; VenezuelaSpringer2019-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/124912Escalante Contreras, Yelisbeth Carolina; Méndez, Franklin J.; Díaz, Yraida; Inojosa, Marcel; Morgado, Myloa; et al.; MCM-41-supported vanadium catalysts structurally modified with Al or Zr for thiophene hydrodesulfurization; Springer; Applied Petrochemical Research; 9; 1; 4-2019; 47-552190-55252190-5533CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://link.springer.com/10.1007/s13203-019-0227-zinfo:eu-repo/semantics/altIdentifier/doi/10.1007/s13203-019-0227-zinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:10:52Zoai:ri.conicet.gov.ar:11336/124912instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:10:52.629CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv MCM-41-supported vanadium catalysts structurally modified with Al or Zr for thiophene hydrodesulfurization
title MCM-41-supported vanadium catalysts structurally modified with Al or Zr for thiophene hydrodesulfurization
spellingShingle MCM-41-supported vanadium catalysts structurally modified with Al or Zr for thiophene hydrodesulfurization
Escalante Contreras, Yelisbeth Carolina
ALUMINOSILICATES
HYDRODESULFURIZATION
MODIFIED-MCM-41
VANADIUM CATALYSTS
ZIRCONIOSILICATES
title_short MCM-41-supported vanadium catalysts structurally modified with Al or Zr for thiophene hydrodesulfurization
title_full MCM-41-supported vanadium catalysts structurally modified with Al or Zr for thiophene hydrodesulfurization
title_fullStr MCM-41-supported vanadium catalysts structurally modified with Al or Zr for thiophene hydrodesulfurization
title_full_unstemmed MCM-41-supported vanadium catalysts structurally modified with Al or Zr for thiophene hydrodesulfurization
title_sort MCM-41-supported vanadium catalysts structurally modified with Al or Zr for thiophene hydrodesulfurization
dc.creator.none.fl_str_mv Escalante Contreras, Yelisbeth Carolina
Méndez, Franklin J.
Díaz, Yraida
Inojosa, Marcel
Morgado, Myloa
Delgado, Miguel
Bastardo González, Ernesto
Brito, Joaquín L.
author Escalante Contreras, Yelisbeth Carolina
author_facet Escalante Contreras, Yelisbeth Carolina
Méndez, Franklin J.
Díaz, Yraida
Inojosa, Marcel
Morgado, Myloa
Delgado, Miguel
Bastardo González, Ernesto
Brito, Joaquín L.
author_role author
author2 Méndez, Franklin J.
Díaz, Yraida
Inojosa, Marcel
Morgado, Myloa
Delgado, Miguel
Bastardo González, Ernesto
Brito, Joaquín L.
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv ALUMINOSILICATES
HYDRODESULFURIZATION
MODIFIED-MCM-41
VANADIUM CATALYSTS
ZIRCONIOSILICATES
topic ALUMINOSILICATES
HYDRODESULFURIZATION
MODIFIED-MCM-41
VANADIUM CATALYSTS
ZIRCONIOSILICATES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Vanadium catalysts supported on Al(Zr)-MCM-41-type materials were prepared by impregnation. Textural and structural properties, elemental composition and electronic structure were determined by N2 physisorption, small-angle XRD, SEM?EDX and UV?vis DRS, respectively. Al-containing materials showed mostly of Al framework and a small fraction of Al extra-framework species. Zr-containing materials presented almost exclusively small clusters of ZrxOy covering the MCM-41 matrix. Vanadium catalysts, showed the presence of isolated V5+ species and to a lesser extent polymeric chains likely as small crystallites of V2O5. The catalytic results revealed that VAlM30 catalyst, characterized by a Si/Al atomic ratio of 30, was the most active in thiophene hydrodesulfurization, which could be associated to better textural properties and high dispersion of the vanadium species.
Fil: Escalante Contreras, Yelisbeth Carolina. Instituto Venezolano de Investigaciones Científicas; Venezuela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Méndez, Franklin J.. Instituto Venezolano de Investigaciones Científicas; Venezuela. Universidad Nacional Autónoma de México; México
Fil: Díaz, Yraida. Instituto Venezolano de Investigaciones Científicas; Venezuela
Fil: Inojosa, Marcel. Instituto Venezolano de Investigaciones Científicas; Venezuela
Fil: Morgado, Myloa. Instituto Venezolano de Investigaciones Científicas; Venezuela
Fil: Delgado, Miguel. Universidad de los Andes; Colombia
Fil: Bastardo González, Ernesto. Universidad de Oriente; Venezuela
Fil: Brito, Joaquín L.. Instituto Venezolano de Investigaciones Científicas; Venezuela
description Vanadium catalysts supported on Al(Zr)-MCM-41-type materials were prepared by impregnation. Textural and structural properties, elemental composition and electronic structure were determined by N2 physisorption, small-angle XRD, SEM?EDX and UV?vis DRS, respectively. Al-containing materials showed mostly of Al framework and a small fraction of Al extra-framework species. Zr-containing materials presented almost exclusively small clusters of ZrxOy covering the MCM-41 matrix. Vanadium catalysts, showed the presence of isolated V5+ species and to a lesser extent polymeric chains likely as small crystallites of V2O5. The catalytic results revealed that VAlM30 catalyst, characterized by a Si/Al atomic ratio of 30, was the most active in thiophene hydrodesulfurization, which could be associated to better textural properties and high dispersion of the vanadium species.
publishDate 2019
dc.date.none.fl_str_mv 2019-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/124912
Escalante Contreras, Yelisbeth Carolina; Méndez, Franklin J.; Díaz, Yraida; Inojosa, Marcel; Morgado, Myloa; et al.; MCM-41-supported vanadium catalysts structurally modified with Al or Zr for thiophene hydrodesulfurization; Springer; Applied Petrochemical Research; 9; 1; 4-2019; 47-55
2190-5525
2190-5533
CONICET Digital
CONICET
url http://hdl.handle.net/11336/124912
identifier_str_mv Escalante Contreras, Yelisbeth Carolina; Méndez, Franklin J.; Díaz, Yraida; Inojosa, Marcel; Morgado, Myloa; et al.; MCM-41-supported vanadium catalysts structurally modified with Al or Zr for thiophene hydrodesulfurization; Springer; Applied Petrochemical Research; 9; 1; 4-2019; 47-55
2190-5525
2190-5533
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://link.springer.com/10.1007/s13203-019-0227-z
info:eu-repo/semantics/altIdentifier/doi/10.1007/s13203-019-0227-z
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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