Selective oxidation of benzyl alcohol through eco-friendly processes using mesoporous V-MCM-41, Fe-MCM-41 and Co-MCM-41 materials

Autores
Cánepa, Analía Laura; Elías, Verónica Rita; Vaschetti, Virginia María; Sabre, Ema Virginia; Eimer, Griselda Alejandra; Casuscelli, Sandra Graciela
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
MCM-41 nanostructured materials modified with Vanadium, Iron and Cobalt were synthesized by a hydrothermal method. The catalysts were characterized by XRD, UV–Vis-DR, ICP-OES and N2 adsorption. All the catalysts showed good structural order and high specific areas; however the lowest value in these parameters, corresponding to the Co-M(60) sample, could be due to the higher presence of oxide species determined by UV–Vis-DR. These mesoporous metalosilicates were evaluated in the liquid phase oxidation of benzyl alcohol (BzOH) to benzaldehyde (BzH) using H2O2 as oxidant. Results showed that V-M(60) had better catalytic performance than Fe-M(60) and Co-M(60) exhibiting high TON (1100 mol/mol V), selectivity to BzH (95%) and 31.7% yield at 7 h under optimized reaction conditions. The main reason for the enhanced catalytic performance was attributed to the well dispersion of vanadium species in the framework which could be considered as the active sites for the benzyl alcohol oxidation reaction. At the same time, the catalyst could be recovered and effectively reused during three cycles without a significant loss in its activity and selectivity.
Fil: Cánepa, Analía Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Elías, Verónica Rita. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Vaschetti, Virginia María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Sabre, Ema Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Casuscelli, Sandra Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Materia
BENZALDEHYDE
MCM-41
SELECTIVE OXIDATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/64179
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Selective oxidation of benzyl alcohol through eco-friendly processes using mesoporous V-MCM-41, Fe-MCM-41 and Co-MCM-41 materialsCánepa, Analía LauraElías, Verónica RitaVaschetti, Virginia MaríaSabre, Ema VirginiaEimer, Griselda AlejandraCasuscelli, Sandra GracielaBENZALDEHYDEMCM-41SELECTIVE OXIDATIONhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2MCM-41 nanostructured materials modified with Vanadium, Iron and Cobalt were synthesized by a hydrothermal method. The catalysts were characterized by XRD, UV–Vis-DR, ICP-OES and N2 adsorption. All the catalysts showed good structural order and high specific areas; however the lowest value in these parameters, corresponding to the Co-M(60) sample, could be due to the higher presence of oxide species determined by UV–Vis-DR. These mesoporous metalosilicates were evaluated in the liquid phase oxidation of benzyl alcohol (BzOH) to benzaldehyde (BzH) using H2O2 as oxidant. Results showed that V-M(60) had better catalytic performance than Fe-M(60) and Co-M(60) exhibiting high TON (1100 mol/mol V), selectivity to BzH (95%) and 31.7% yield at 7 h under optimized reaction conditions. The main reason for the enhanced catalytic performance was attributed to the well dispersion of vanadium species in the framework which could be considered as the active sites for the benzyl alcohol oxidation reaction. At the same time, the catalyst could be recovered and effectively reused during three cycles without a significant loss in its activity and selectivity.Fil: Cánepa, Analía Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Elías, Verónica Rita. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Vaschetti, Virginia María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Sabre, Ema Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Casuscelli, Sandra Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaElsevier Science2017-07-25info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/64179Cánepa, Analía Laura; Elías, Verónica Rita; Vaschetti, Virginia María; Sabre, Ema Virginia; Eimer, Griselda Alejandra; et al.; Selective oxidation of benzyl alcohol through eco-friendly processes using mesoporous V-MCM-41, Fe-MCM-41 and Co-MCM-41 materials; Elsevier Science; Applied Catalysis A: General; 545; 25-7-2017; 72-780926-860X0926-860CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X17303496info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2017.07.039info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:46:59Zoai:ri.conicet.gov.ar:11336/64179instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:47:00.03CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Selective oxidation of benzyl alcohol through eco-friendly processes using mesoporous V-MCM-41, Fe-MCM-41 and Co-MCM-41 materials
title Selective oxidation of benzyl alcohol through eco-friendly processes using mesoporous V-MCM-41, Fe-MCM-41 and Co-MCM-41 materials
spellingShingle Selective oxidation of benzyl alcohol through eco-friendly processes using mesoporous V-MCM-41, Fe-MCM-41 and Co-MCM-41 materials
Cánepa, Analía Laura
BENZALDEHYDE
MCM-41
SELECTIVE OXIDATION
title_short Selective oxidation of benzyl alcohol through eco-friendly processes using mesoporous V-MCM-41, Fe-MCM-41 and Co-MCM-41 materials
title_full Selective oxidation of benzyl alcohol through eco-friendly processes using mesoporous V-MCM-41, Fe-MCM-41 and Co-MCM-41 materials
title_fullStr Selective oxidation of benzyl alcohol through eco-friendly processes using mesoporous V-MCM-41, Fe-MCM-41 and Co-MCM-41 materials
title_full_unstemmed Selective oxidation of benzyl alcohol through eco-friendly processes using mesoporous V-MCM-41, Fe-MCM-41 and Co-MCM-41 materials
title_sort Selective oxidation of benzyl alcohol through eco-friendly processes using mesoporous V-MCM-41, Fe-MCM-41 and Co-MCM-41 materials
dc.creator.none.fl_str_mv Cánepa, Analía Laura
Elías, Verónica Rita
Vaschetti, Virginia María
Sabre, Ema Virginia
Eimer, Griselda Alejandra
Casuscelli, Sandra Graciela
author Cánepa, Analía Laura
author_facet Cánepa, Analía Laura
Elías, Verónica Rita
Vaschetti, Virginia María
Sabre, Ema Virginia
Eimer, Griselda Alejandra
Casuscelli, Sandra Graciela
author_role author
author2 Elías, Verónica Rita
Vaschetti, Virginia María
Sabre, Ema Virginia
Eimer, Griselda Alejandra
Casuscelli, Sandra Graciela
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv BENZALDEHYDE
MCM-41
SELECTIVE OXIDATION
topic BENZALDEHYDE
MCM-41
SELECTIVE OXIDATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv MCM-41 nanostructured materials modified with Vanadium, Iron and Cobalt were synthesized by a hydrothermal method. The catalysts were characterized by XRD, UV–Vis-DR, ICP-OES and N2 adsorption. All the catalysts showed good structural order and high specific areas; however the lowest value in these parameters, corresponding to the Co-M(60) sample, could be due to the higher presence of oxide species determined by UV–Vis-DR. These mesoporous metalosilicates were evaluated in the liquid phase oxidation of benzyl alcohol (BzOH) to benzaldehyde (BzH) using H2O2 as oxidant. Results showed that V-M(60) had better catalytic performance than Fe-M(60) and Co-M(60) exhibiting high TON (1100 mol/mol V), selectivity to BzH (95%) and 31.7% yield at 7 h under optimized reaction conditions. The main reason for the enhanced catalytic performance was attributed to the well dispersion of vanadium species in the framework which could be considered as the active sites for the benzyl alcohol oxidation reaction. At the same time, the catalyst could be recovered and effectively reused during three cycles without a significant loss in its activity and selectivity.
Fil: Cánepa, Analía Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Elías, Verónica Rita. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Vaschetti, Virginia María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Sabre, Ema Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Casuscelli, Sandra Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
description MCM-41 nanostructured materials modified with Vanadium, Iron and Cobalt were synthesized by a hydrothermal method. The catalysts were characterized by XRD, UV–Vis-DR, ICP-OES and N2 adsorption. All the catalysts showed good structural order and high specific areas; however the lowest value in these parameters, corresponding to the Co-M(60) sample, could be due to the higher presence of oxide species determined by UV–Vis-DR. These mesoporous metalosilicates were evaluated in the liquid phase oxidation of benzyl alcohol (BzOH) to benzaldehyde (BzH) using H2O2 as oxidant. Results showed that V-M(60) had better catalytic performance than Fe-M(60) and Co-M(60) exhibiting high TON (1100 mol/mol V), selectivity to BzH (95%) and 31.7% yield at 7 h under optimized reaction conditions. The main reason for the enhanced catalytic performance was attributed to the well dispersion of vanadium species in the framework which could be considered as the active sites for the benzyl alcohol oxidation reaction. At the same time, the catalyst could be recovered and effectively reused during three cycles without a significant loss in its activity and selectivity.
publishDate 2017
dc.date.none.fl_str_mv 2017-07-25
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/64179
Cánepa, Analía Laura; Elías, Verónica Rita; Vaschetti, Virginia María; Sabre, Ema Virginia; Eimer, Griselda Alejandra; et al.; Selective oxidation of benzyl alcohol through eco-friendly processes using mesoporous V-MCM-41, Fe-MCM-41 and Co-MCM-41 materials; Elsevier Science; Applied Catalysis A: General; 545; 25-7-2017; 72-78
0926-860X
0926-860
CONICET Digital
CONICET
url http://hdl.handle.net/11336/64179
identifier_str_mv Cánepa, Analía Laura; Elías, Verónica Rita; Vaschetti, Virginia María; Sabre, Ema Virginia; Eimer, Griselda Alejandra; et al.; Selective oxidation of benzyl alcohol through eco-friendly processes using mesoporous V-MCM-41, Fe-MCM-41 and Co-MCM-41 materials; Elsevier Science; Applied Catalysis A: General; 545; 25-7-2017; 72-78
0926-860X
0926-860
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X17303496
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2017.07.039
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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