Real‐Time Non‐Faradaic Potentiodynamic Impedance Sensing Using Screen‐Printed Carbon Electrodes
- Autores
- Fuhry, Emil; Guglielmotti, Victoria; Wachta, Isabell; Pallarola, Diego Andres; Balasubramanian, Kannan
- Año de publicación
- 2024
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Electrochemical impedance spectroscopy (EIS) is a suitable analytical technique to detectinterfacial phenomena and analyte binding at electrode surfaces. In contrast to metallicelectrodes, carbon-based electrodes are more suited due to the low cost and the availability ofmore versatile methods for chemical functionalization. For (bio) sensing, often the Faradaicversion of EIS in a three-electrode configuration is used, where a redox-active species is usedas a marker. In order to avoid interference due to the redox-active marker with the interfacialinteraction, we focus here on the use of non-Faradaic EIS in the absence of any added markers.First, we utilize the sedimentation of silica beads as a model system, which reduces thecomplexity of the interaction simplifying the interpretation of the measured signals. Moreover,we introduce two improvements. First, impedance measurements are performed in a threeelectrodeconfiguration with applied potential as an additional variable, which serves as ahandle to optimize the sensitivity. Secondly, we present a time-differential strategy to detectsubtle changes and demonstrate that we can consistently follow the sedimentation of beadsusing the non-Faradaic impedance as a function of the applied potential. Finally, we show aproof-of-principle demonstration for the biosensing of cell attachment on the electrodes in realtimeusing the proposed technique.
Fil: Fuhry, Emil. Humboldt-Universität zu Berlin; Alemania
Fil: Guglielmotti, Victoria. Humboldt-Universität zu Berlin; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina
Fil: Wachta, Isabell. Humboldt-Universität zu Berlin; Alemania
Fil: Pallarola, Diego Andres. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Balasubramanian, Kannan. Humboldt-Universität zu Berlin; Alemania - Materia
-
POINT OF ZERO CHARGE
CAPACITIVE SENSORS
ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY
CELL SENSING
ELECTRIC CELL-SUBSTRATE IMPEDANCE SENSING
POTENTIODYNAMIC
SCREENPRINTED ELECTRODES - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/241317
Ver los metadatos del registro completo
id |
CONICETDig_675d4a8118db8918663284be06b16168 |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/241317 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Real‐Time Non‐Faradaic Potentiodynamic Impedance Sensing Using Screen‐Printed Carbon ElectrodesFuhry, EmilGuglielmotti, VictoriaWachta, IsabellPallarola, Diego AndresBalasubramanian, KannanPOINT OF ZERO CHARGECAPACITIVE SENSORSELECTROCHEMICAL IMPEDANCE SPECTROSCOPYCELL SENSINGELECTRIC CELL-SUBSTRATE IMPEDANCE SENSINGPOTENTIODYNAMICSCREENPRINTED ELECTRODEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.6https://purl.org/becyt/ford/1Electrochemical impedance spectroscopy (EIS) is a suitable analytical technique to detectinterfacial phenomena and analyte binding at electrode surfaces. In contrast to metallicelectrodes, carbon-based electrodes are more suited due to the low cost and the availability ofmore versatile methods for chemical functionalization. For (bio) sensing, often the Faradaicversion of EIS in a three-electrode configuration is used, where a redox-active species is usedas a marker. In order to avoid interference due to the redox-active marker with the interfacialinteraction, we focus here on the use of non-Faradaic EIS in the absence of any added markers.First, we utilize the sedimentation of silica beads as a model system, which reduces thecomplexity of the interaction simplifying the interpretation of the measured signals. Moreover,we introduce two improvements. First, impedance measurements are performed in a threeelectrodeconfiguration with applied potential as an additional variable, which serves as ahandle to optimize the sensitivity. Secondly, we present a time-differential strategy to detectsubtle changes and demonstrate that we can consistently follow the sedimentation of beadsusing the non-Faradaic impedance as a function of the applied potential. Finally, we show aproof-of-principle demonstration for the biosensing of cell attachment on the electrodes in realtimeusing the proposed technique.Fil: Fuhry, Emil. Humboldt-Universität zu Berlin; AlemaniaFil: Guglielmotti, Victoria. Humboldt-Universität zu Berlin; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; ArgentinaFil: Wachta, Isabell. Humboldt-Universität zu Berlin; AlemaniaFil: Pallarola, Diego Andres. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Balasubramanian, Kannan. Humboldt-Universität zu Berlin; AlemaniaWiley2024-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/241317Fuhry, Emil; Guglielmotti, Victoria; Wachta, Isabell; Pallarola, Diego Andres; Balasubramanian, Kannan; Real‐Time Non‐Faradaic Potentiodynamic Impedance Sensing Using Screen‐Printed Carbon Electrodes; Wiley; Analysis & Sensing; 6-2024; 1-222629-2742CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/anse.202400037info:eu-repo/semantics/altIdentifier/doi/10.1002/anse.202400037info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:44:46Zoai:ri.conicet.gov.ar:11336/241317instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:44:46.784CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Real‐Time Non‐Faradaic Potentiodynamic Impedance Sensing Using Screen‐Printed Carbon Electrodes |
title |
Real‐Time Non‐Faradaic Potentiodynamic Impedance Sensing Using Screen‐Printed Carbon Electrodes |
spellingShingle |
Real‐Time Non‐Faradaic Potentiodynamic Impedance Sensing Using Screen‐Printed Carbon Electrodes Fuhry, Emil POINT OF ZERO CHARGE CAPACITIVE SENSORS ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY CELL SENSING ELECTRIC CELL-SUBSTRATE IMPEDANCE SENSING POTENTIODYNAMIC SCREENPRINTED ELECTRODES |
title_short |
Real‐Time Non‐Faradaic Potentiodynamic Impedance Sensing Using Screen‐Printed Carbon Electrodes |
title_full |
Real‐Time Non‐Faradaic Potentiodynamic Impedance Sensing Using Screen‐Printed Carbon Electrodes |
title_fullStr |
Real‐Time Non‐Faradaic Potentiodynamic Impedance Sensing Using Screen‐Printed Carbon Electrodes |
title_full_unstemmed |
Real‐Time Non‐Faradaic Potentiodynamic Impedance Sensing Using Screen‐Printed Carbon Electrodes |
title_sort |
Real‐Time Non‐Faradaic Potentiodynamic Impedance Sensing Using Screen‐Printed Carbon Electrodes |
dc.creator.none.fl_str_mv |
Fuhry, Emil Guglielmotti, Victoria Wachta, Isabell Pallarola, Diego Andres Balasubramanian, Kannan |
author |
Fuhry, Emil |
author_facet |
Fuhry, Emil Guglielmotti, Victoria Wachta, Isabell Pallarola, Diego Andres Balasubramanian, Kannan |
author_role |
author |
author2 |
Guglielmotti, Victoria Wachta, Isabell Pallarola, Diego Andres Balasubramanian, Kannan |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
POINT OF ZERO CHARGE CAPACITIVE SENSORS ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY CELL SENSING ELECTRIC CELL-SUBSTRATE IMPEDANCE SENSING POTENTIODYNAMIC SCREENPRINTED ELECTRODES |
topic |
POINT OF ZERO CHARGE CAPACITIVE SENSORS ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY CELL SENSING ELECTRIC CELL-SUBSTRATE IMPEDANCE SENSING POTENTIODYNAMIC SCREENPRINTED ELECTRODES |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 https://purl.org/becyt/ford/1.6 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Electrochemical impedance spectroscopy (EIS) is a suitable analytical technique to detectinterfacial phenomena and analyte binding at electrode surfaces. In contrast to metallicelectrodes, carbon-based electrodes are more suited due to the low cost and the availability ofmore versatile methods for chemical functionalization. For (bio) sensing, often the Faradaicversion of EIS in a three-electrode configuration is used, where a redox-active species is usedas a marker. In order to avoid interference due to the redox-active marker with the interfacialinteraction, we focus here on the use of non-Faradaic EIS in the absence of any added markers.First, we utilize the sedimentation of silica beads as a model system, which reduces thecomplexity of the interaction simplifying the interpretation of the measured signals. Moreover,we introduce two improvements. First, impedance measurements are performed in a threeelectrodeconfiguration with applied potential as an additional variable, which serves as ahandle to optimize the sensitivity. Secondly, we present a time-differential strategy to detectsubtle changes and demonstrate that we can consistently follow the sedimentation of beadsusing the non-Faradaic impedance as a function of the applied potential. Finally, we show aproof-of-principle demonstration for the biosensing of cell attachment on the electrodes in realtimeusing the proposed technique. Fil: Fuhry, Emil. Humboldt-Universität zu Berlin; Alemania Fil: Guglielmotti, Victoria. Humboldt-Universität zu Berlin; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina Fil: Wachta, Isabell. Humboldt-Universität zu Berlin; Alemania Fil: Pallarola, Diego Andres. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Balasubramanian, Kannan. Humboldt-Universität zu Berlin; Alemania |
description |
Electrochemical impedance spectroscopy (EIS) is a suitable analytical technique to detectinterfacial phenomena and analyte binding at electrode surfaces. In contrast to metallicelectrodes, carbon-based electrodes are more suited due to the low cost and the availability ofmore versatile methods for chemical functionalization. For (bio) sensing, often the Faradaicversion of EIS in a three-electrode configuration is used, where a redox-active species is usedas a marker. In order to avoid interference due to the redox-active marker with the interfacialinteraction, we focus here on the use of non-Faradaic EIS in the absence of any added markers.First, we utilize the sedimentation of silica beads as a model system, which reduces thecomplexity of the interaction simplifying the interpretation of the measured signals. Moreover,we introduce two improvements. First, impedance measurements are performed in a threeelectrodeconfiguration with applied potential as an additional variable, which serves as ahandle to optimize the sensitivity. Secondly, we present a time-differential strategy to detectsubtle changes and demonstrate that we can consistently follow the sedimentation of beadsusing the non-Faradaic impedance as a function of the applied potential. Finally, we show aproof-of-principle demonstration for the biosensing of cell attachment on the electrodes in realtimeusing the proposed technique. |
publishDate |
2024 |
dc.date.none.fl_str_mv |
2024-06 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/241317 Fuhry, Emil; Guglielmotti, Victoria; Wachta, Isabell; Pallarola, Diego Andres; Balasubramanian, Kannan; Real‐Time Non‐Faradaic Potentiodynamic Impedance Sensing Using Screen‐Printed Carbon Electrodes; Wiley; Analysis & Sensing; 6-2024; 1-22 2629-2742 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/241317 |
identifier_str_mv |
Fuhry, Emil; Guglielmotti, Victoria; Wachta, Isabell; Pallarola, Diego Andres; Balasubramanian, Kannan; Real‐Time Non‐Faradaic Potentiodynamic Impedance Sensing Using Screen‐Printed Carbon Electrodes; Wiley; Analysis & Sensing; 6-2024; 1-22 2629-2742 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/anse.202400037 info:eu-repo/semantics/altIdentifier/doi/10.1002/anse.202400037 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley |
publisher.none.fl_str_mv |
Wiley |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613408910999552 |
score |
13.070432 |