Spontaneous Enantiomorphism in Poly-phased Alkaline Salts of tris(oxalato)ferrate(III): Crystal Structure of Cubic NaRb5[Fe(C2O4)3]2
- Autores
- Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Baran, Enrique José
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- We show here that the phenomenon of spontaneous resolution of enantiomers occurs during the crystallization of the sodium and rubidium double salts of the transition metal complex tris(oxalato)ferrate(III), namely sodium penta-rubidium bis[tris(oxalate) ferrate (III)], NaRb5[Fe(C2O4)3]2. One enantiomer of the salt crystallizes in the cubic space group P4332 with Z = 4 and a Flack absolute structure parameter x = -0.01(1) and its chiral counterpart in the space group P4132 with x = -0.00(1). All metal ions are at crystallographic special positions: the Fe(III) ion is on a threefold axis, coordinated by three oxalate dianions in a propeller-like conformation. One of the two independent Rb(I) ions is on a twofold axis in an eightfold coordination with neighboring oxalate oxygen atoms, and the other one on a threefold axis in a sixfold RbO6 coordination. The sodium ion is at a site of D3 point group symmetry in a trigonal-antiprismatic NaO6 coordination.
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina - Materia
-
Absolute crystal structures
Spontaneous resolution of enantiomorphs
Sodium and rubidium salt of tris(oxalato)ferrate(III) - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/101756
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spelling |
Spontaneous Enantiomorphism in Poly-phased Alkaline Salts of tris(oxalato)ferrate(III): Crystal Structure of Cubic NaRb5[Fe(C2O4)3]2Piro, Oscar EnriqueEcheverría, Gustavo AlbertoBaran, Enrique JoséAbsolute crystal structuresSpontaneous resolution of enantiomorphsSodium and rubidium salt of tris(oxalato)ferrate(III)https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1We show here that the phenomenon of spontaneous resolution of enantiomers occurs during the crystallization of the sodium and rubidium double salts of the transition metal complex tris(oxalato)ferrate(III), namely sodium penta-rubidium bis[tris(oxalate) ferrate (III)], NaRb5[Fe(C2O4)3]2. One enantiomer of the salt crystallizes in the cubic space group P4332 with Z = 4 and a Flack absolute structure parameter x = -0.01(1) and its chiral counterpart in the space group P4132 with x = -0.00(1). All metal ions are at crystallographic special positions: the Fe(III) ion is on a threefold axis, coordinated by three oxalate dianions in a propeller-like conformation. One of the two independent Rb(I) ions is on a twofold axis in an eightfold coordination with neighboring oxalate oxygen atoms, and the other one on a threefold axis in a sixfold RbO6 coordination. The sodium ion is at a site of D3 point group symmetry in a trigonal-antiprismatic NaO6 coordination.Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaInternational Union of Crystallography2018-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/101756Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Baran, Enrique José; Spontaneous Enantiomorphism in Poly-phased Alkaline Salts of tris(oxalato)ferrate(III): Crystal Structure of Cubic NaRb5[Fe(C2O4)3]2; International Union of Crystallography; Acta Crystallographica Section E; 74; 7; 6-2018; 905-9092056-9890CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1107/S2056989018008022info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S2056989018008022info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:41:05Zoai:ri.conicet.gov.ar:11336/101756instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:41:05.914CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Spontaneous Enantiomorphism in Poly-phased Alkaline Salts of tris(oxalato)ferrate(III): Crystal Structure of Cubic NaRb5[Fe(C2O4)3]2 |
title |
Spontaneous Enantiomorphism in Poly-phased Alkaline Salts of tris(oxalato)ferrate(III): Crystal Structure of Cubic NaRb5[Fe(C2O4)3]2 |
spellingShingle |
Spontaneous Enantiomorphism in Poly-phased Alkaline Salts of tris(oxalato)ferrate(III): Crystal Structure of Cubic NaRb5[Fe(C2O4)3]2 Piro, Oscar Enrique Absolute crystal structures Spontaneous resolution of enantiomorphs Sodium and rubidium salt of tris(oxalato)ferrate(III) |
title_short |
Spontaneous Enantiomorphism in Poly-phased Alkaline Salts of tris(oxalato)ferrate(III): Crystal Structure of Cubic NaRb5[Fe(C2O4)3]2 |
title_full |
Spontaneous Enantiomorphism in Poly-phased Alkaline Salts of tris(oxalato)ferrate(III): Crystal Structure of Cubic NaRb5[Fe(C2O4)3]2 |
title_fullStr |
Spontaneous Enantiomorphism in Poly-phased Alkaline Salts of tris(oxalato)ferrate(III): Crystal Structure of Cubic NaRb5[Fe(C2O4)3]2 |
title_full_unstemmed |
Spontaneous Enantiomorphism in Poly-phased Alkaline Salts of tris(oxalato)ferrate(III): Crystal Structure of Cubic NaRb5[Fe(C2O4)3]2 |
title_sort |
Spontaneous Enantiomorphism in Poly-phased Alkaline Salts of tris(oxalato)ferrate(III): Crystal Structure of Cubic NaRb5[Fe(C2O4)3]2 |
dc.creator.none.fl_str_mv |
Piro, Oscar Enrique Echeverría, Gustavo Alberto Baran, Enrique José |
author |
Piro, Oscar Enrique |
author_facet |
Piro, Oscar Enrique Echeverría, Gustavo Alberto Baran, Enrique José |
author_role |
author |
author2 |
Echeverría, Gustavo Alberto Baran, Enrique José |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Absolute crystal structures Spontaneous resolution of enantiomorphs Sodium and rubidium salt of tris(oxalato)ferrate(III) |
topic |
Absolute crystal structures Spontaneous resolution of enantiomorphs Sodium and rubidium salt of tris(oxalato)ferrate(III) |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
We show here that the phenomenon of spontaneous resolution of enantiomers occurs during the crystallization of the sodium and rubidium double salts of the transition metal complex tris(oxalato)ferrate(III), namely sodium penta-rubidium bis[tris(oxalate) ferrate (III)], NaRb5[Fe(C2O4)3]2. One enantiomer of the salt crystallizes in the cubic space group P4332 with Z = 4 and a Flack absolute structure parameter x = -0.01(1) and its chiral counterpart in the space group P4132 with x = -0.00(1). All metal ions are at crystallographic special positions: the Fe(III) ion is on a threefold axis, coordinated by three oxalate dianions in a propeller-like conformation. One of the two independent Rb(I) ions is on a twofold axis in an eightfold coordination with neighboring oxalate oxygen atoms, and the other one on a threefold axis in a sixfold RbO6 coordination. The sodium ion is at a site of D3 point group symmetry in a trigonal-antiprismatic NaO6 coordination. Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina Fil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina |
description |
We show here that the phenomenon of spontaneous resolution of enantiomers occurs during the crystallization of the sodium and rubidium double salts of the transition metal complex tris(oxalato)ferrate(III), namely sodium penta-rubidium bis[tris(oxalate) ferrate (III)], NaRb5[Fe(C2O4)3]2. One enantiomer of the salt crystallizes in the cubic space group P4332 with Z = 4 and a Flack absolute structure parameter x = -0.01(1) and its chiral counterpart in the space group P4132 with x = -0.00(1). All metal ions are at crystallographic special positions: the Fe(III) ion is on a threefold axis, coordinated by three oxalate dianions in a propeller-like conformation. One of the two independent Rb(I) ions is on a twofold axis in an eightfold coordination with neighboring oxalate oxygen atoms, and the other one on a threefold axis in a sixfold RbO6 coordination. The sodium ion is at a site of D3 point group symmetry in a trigonal-antiprismatic NaO6 coordination. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-06 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/101756 Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Baran, Enrique José; Spontaneous Enantiomorphism in Poly-phased Alkaline Salts of tris(oxalato)ferrate(III): Crystal Structure of Cubic NaRb5[Fe(C2O4)3]2; International Union of Crystallography; Acta Crystallographica Section E; 74; 7; 6-2018; 905-909 2056-9890 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/101756 |
identifier_str_mv |
Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Baran, Enrique José; Spontaneous Enantiomorphism in Poly-phased Alkaline Salts of tris(oxalato)ferrate(III): Crystal Structure of Cubic NaRb5[Fe(C2O4)3]2; International Union of Crystallography; Acta Crystallographica Section E; 74; 7; 6-2018; 905-909 2056-9890 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1107/S2056989018008022 info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S2056989018008022 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
International Union of Crystallography |
publisher.none.fl_str_mv |
International Union of Crystallography |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613299398770688 |
score |
13.070432 |