Crystallographic new light on an old complex: NaMg[Cr(oxalato) 3]·9H 2O and structure redetermination of the isomorphous aluminum(III) compound

Autores
Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Gonzalez Baro, Ana Cecilia; Baran, Enrique José
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The crystal structure of sodium and magnesium tris(oxalato)chromato(III) nona hydrate, NaMg[Cr(C2O4)3]·9H2O, has been determined by X-ray diffraction methods. It crystallizes in the trigonal P3c1 space group with (in the hexagonal setting) a = b = 16.9635(4), c = 12.5247(3) Å, and Z = 6 molecules per unit cell. The Cr(III) and sodium ions are in octahedral environments coordinated to three oxalate molecules and arranged in a honeycomb-like layered structure perpendicular to the crystal c-axis. There are three different octahedral [Mg(H2O)6]2+ hydrated ions that fill the honeycomb holes giving rise to electrically neutral Na[Mg(H2O)6][Cr(oxalato)3] crystal slabs. Neighboring slabs are bridged by the remaining three water molecules through H-bonds and therefore the whole crystal can be more properly described as Na[Mg(H2O)6][Cr(oxalato)3]·3H2O. Also, the structure of isomorphous NaMg[Al(C2O4)3]·9H2O compound has been re-examined and compared with the chromium(III) complex. Infrared and Raman spectra of both complexes were also recorded and briefly discussed.
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Gonzalez Baro, Ana Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Materia
Crystal Structures
Na/Mg Salts
Tris(Oxalato)Aluminato(Iii)
Tris(Oxalato)Chromato(Iii)
Vibrational Spectra
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/53996
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/53996
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Crystallographic new light on an old complex: NaMg[Cr(oxalato) 3]·9H 2O and structure redetermination of the isomorphous aluminum(III) compoundPiro, Oscar EnriqueEcheverría, Gustavo AlbertoGonzalez Baro, Ana CeciliaBaran, Enrique JoséCrystal StructuresNa/Mg SaltsTris(Oxalato)Aluminato(Iii)Tris(Oxalato)Chromato(Iii)Vibrational Spectrahttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The crystal structure of sodium and magnesium tris(oxalato)chromato(III) nona hydrate, NaMg[Cr(C2O4)3]·9H2O, has been determined by X-ray diffraction methods. It crystallizes in the trigonal P3c1 space group with (in the hexagonal setting) a = b = 16.9635(4), c = 12.5247(3) Å, and Z = 6 molecules per unit cell. The Cr(III) and sodium ions are in octahedral environments coordinated to three oxalate molecules and arranged in a honeycomb-like layered structure perpendicular to the crystal c-axis. There are three different octahedral [Mg(H2O)6]2+ hydrated ions that fill the honeycomb holes giving rise to electrically neutral Na[Mg(H2O)6][Cr(oxalato)3] crystal slabs. Neighboring slabs are bridged by the remaining three water molecules through H-bonds and therefore the whole crystal can be more properly described as Na[Mg(H2O)6][Cr(oxalato)3]·3H2O. Also, the structure of isomorphous NaMg[Al(C2O4)3]·9H2O compound has been re-examined and compared with the chromium(III) complex. Infrared and Raman spectra of both complexes were also recorded and briefly discussed.Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Gonzalez Baro, Ana Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; ArgentinaFil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; ArgentinaTaylor & Francis2015-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/53996Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Gonzalez Baro, Ana Cecilia; Baran, Enrique José; Crystallographic new light on an old complex: NaMg[Cr(oxalato) 3]·9H 2O and structure redetermination of the isomorphous aluminum(III) compound; Taylor & Francis; Journal of Coordination Chemistry; 68; 21; 11-2015; 3776-37870095-89721029-0389CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1080/00958972.2015.1078460info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/00958972.2015.1078460info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:51:47Zoai:ri.conicet.gov.ar:11336/53996instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:51:48.067CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Crystallographic new light on an old complex: NaMg[Cr(oxalato) 3]·9H 2O and structure redetermination of the isomorphous aluminum(III) compound
title Crystallographic new light on an old complex: NaMg[Cr(oxalato) 3]·9H 2O and structure redetermination of the isomorphous aluminum(III) compound
spellingShingle Crystallographic new light on an old complex: NaMg[Cr(oxalato) 3]·9H 2O and structure redetermination of the isomorphous aluminum(III) compound
Piro, Oscar Enrique
Crystal Structures
Na/Mg Salts
Tris(Oxalato)Aluminato(Iii)
Tris(Oxalato)Chromato(Iii)
Vibrational Spectra
title_short Crystallographic new light on an old complex: NaMg[Cr(oxalato) 3]·9H 2O and structure redetermination of the isomorphous aluminum(III) compound
title_full Crystallographic new light on an old complex: NaMg[Cr(oxalato) 3]·9H 2O and structure redetermination of the isomorphous aluminum(III) compound
title_fullStr Crystallographic new light on an old complex: NaMg[Cr(oxalato) 3]·9H 2O and structure redetermination of the isomorphous aluminum(III) compound
title_full_unstemmed Crystallographic new light on an old complex: NaMg[Cr(oxalato) 3]·9H 2O and structure redetermination of the isomorphous aluminum(III) compound
title_sort Crystallographic new light on an old complex: NaMg[Cr(oxalato) 3]·9H 2O and structure redetermination of the isomorphous aluminum(III) compound
dc.creator.none.fl_str_mv Piro, Oscar Enrique
Echeverría, Gustavo Alberto
Gonzalez Baro, Ana Cecilia
Baran, Enrique José
author Piro, Oscar Enrique
author_facet Piro, Oscar Enrique
Echeverría, Gustavo Alberto
Gonzalez Baro, Ana Cecilia
Baran, Enrique José
author_role author
author2 Echeverría, Gustavo Alberto
Gonzalez Baro, Ana Cecilia
Baran, Enrique José
author2_role author
author
author
dc.subject.none.fl_str_mv Crystal Structures
Na/Mg Salts
Tris(Oxalato)Aluminato(Iii)
Tris(Oxalato)Chromato(Iii)
Vibrational Spectra
topic Crystal Structures
Na/Mg Salts
Tris(Oxalato)Aluminato(Iii)
Tris(Oxalato)Chromato(Iii)
Vibrational Spectra
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The crystal structure of sodium and magnesium tris(oxalato)chromato(III) nona hydrate, NaMg[Cr(C2O4)3]·9H2O, has been determined by X-ray diffraction methods. It crystallizes in the trigonal P3c1 space group with (in the hexagonal setting) a = b = 16.9635(4), c = 12.5247(3) Å, and Z = 6 molecules per unit cell. The Cr(III) and sodium ions are in octahedral environments coordinated to three oxalate molecules and arranged in a honeycomb-like layered structure perpendicular to the crystal c-axis. There are three different octahedral [Mg(H2O)6]2+ hydrated ions that fill the honeycomb holes giving rise to electrically neutral Na[Mg(H2O)6][Cr(oxalato)3] crystal slabs. Neighboring slabs are bridged by the remaining three water molecules through H-bonds and therefore the whole crystal can be more properly described as Na[Mg(H2O)6][Cr(oxalato)3]·3H2O. Also, the structure of isomorphous NaMg[Al(C2O4)3]·9H2O compound has been re-examined and compared with the chromium(III) complex. Infrared and Raman spectra of both complexes were also recorded and briefly discussed.
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Gonzalez Baro, Ana Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
description The crystal structure of sodium and magnesium tris(oxalato)chromato(III) nona hydrate, NaMg[Cr(C2O4)3]·9H2O, has been determined by X-ray diffraction methods. It crystallizes in the trigonal P3c1 space group with (in the hexagonal setting) a = b = 16.9635(4), c = 12.5247(3) Å, and Z = 6 molecules per unit cell. The Cr(III) and sodium ions are in octahedral environments coordinated to three oxalate molecules and arranged in a honeycomb-like layered structure perpendicular to the crystal c-axis. There are three different octahedral [Mg(H2O)6]2+ hydrated ions that fill the honeycomb holes giving rise to electrically neutral Na[Mg(H2O)6][Cr(oxalato)3] crystal slabs. Neighboring slabs are bridged by the remaining three water molecules through H-bonds and therefore the whole crystal can be more properly described as Na[Mg(H2O)6][Cr(oxalato)3]·3H2O. Also, the structure of isomorphous NaMg[Al(C2O4)3]·9H2O compound has been re-examined and compared with the chromium(III) complex. Infrared and Raman spectra of both complexes were also recorded and briefly discussed.
publishDate 2015
dc.date.none.fl_str_mv 2015-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/53996
Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Gonzalez Baro, Ana Cecilia; Baran, Enrique José; Crystallographic new light on an old complex: NaMg[Cr(oxalato) 3]·9H 2O and structure redetermination of the isomorphous aluminum(III) compound; Taylor & Francis; Journal of Coordination Chemistry; 68; 21; 11-2015; 3776-3787
0095-8972
1029-0389
CONICET Digital
CONICET
url http://hdl.handle.net/11336/53996
identifier_str_mv Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Gonzalez Baro, Ana Cecilia; Baran, Enrique José; Crystallographic new light on an old complex: NaMg[Cr(oxalato) 3]·9H 2O and structure redetermination of the isomorphous aluminum(III) compound; Taylor & Francis; Journal of Coordination Chemistry; 68; 21; 11-2015; 3776-3787
0095-8972
1029-0389
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1080/00958972.2015.1078460
info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/00958972.2015.1078460
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis
publisher.none.fl_str_mv Taylor & Francis
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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