Obtention and Products Distribution of Bioliquid from Catalytic Pyrolysis of Tomato Plant Waste

Autores
Buitrago Buitrago, Jose Luis; Mendez, Leticia Jesica; Musci, Juan José; Cecilia, Juan Antonio; Ballesteros Plata, Daniel; Rodríguez Castellón, Enrique; Casella, Mónica Laura; Pizzio, Luis Rene; Lick, Ileana Daniela
Año de publicación
2025
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The use of tomato plant residues (i.e., stems, leaves, etc.) as a substrate forcatalytic pyrolysis of biomass was investigated. A comprehensive study was conductedto investigate the impact of catalysts on the performance of different pyrolysis fractions(i.e., gas, biosolid, waxes, and bioliquid) as well as the distribution of products withinthe bioliquid. The catalysts employed in this study were derived from two distinct typesof zirconia. The first type was synthesized by a conventional sol-gel method, while thesecond type was prepared with a modified method aimed at improving the presence ofmesopores. This modification involved the incorporation of Pluronic 123. These materialswere designated ZrO2 and ZrO2P25, respectively. Both types of zirconia were used assupports for tungstophosphoric acid (H3PW12O40, TPA), a heteropolyacid with a Kegginstructure, in the preparation of catalysts with strong acid sites. The results demonstratedthat the bioliquid yield of the non-catalytic fast pyrolysis of tomato plant waste wasapproximately 23% and that the obtained bioliquid contained a wide variety of molecules,which were detected and quantified by GC-MS. In the presence of the catalysts, both thebioliquid yield and the distribution of bioliquid products were substantially modified.Furthermore, the possible sugar degradation pathways leading to the formation of themolecules present in the pyrolytic bioliquids were thoroughly examined. The resultsobtained from this study indicate that the physicochemical characteristics of the catalysts,specifically their pore size and acidity, have a significant impact on the selectivity of thecatalytic processes towards valuable molecules, including anhydro-sugars and furanicderivatives such as furfural and furfuryl alcohol.
Fil: Buitrago Buitrago, Jose Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Mendez, Leticia Jesica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Musci, Juan José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro de Investigaciones y Transferencia del Noroeste de la Provincia de Buenos Aires. Universidad Nacional del Noroeste de la Provincia de Buenos Aires. Centro de Investigaciones y Transferencia del Noroeste de la Provincia de Buenos Aires; Argentina
Fil: Cecilia, Juan Antonio. Universidad de Málaga; España
Fil: Ballesteros Plata, Daniel. Universidad de Málaga; España
Fil: Rodríguez Castellón, Enrique. Universidad de Málaga; España
Fil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Lick, Ileana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Materia
TUNGSTOPHOSPHORIC ACID
HETEROPOLYACIDS
ZIRCONIA
CATALYTIC PYROLYSIS
FURANS
ACID CATALYSTS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/266576
Acceder
id CONICETDig_5d22590a13ca611596e4a99a1ee3888c
oai_identifier_str oai:ri.conicet.gov.ar:11336/266576
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Obtention and Products Distribution of Bioliquid from Catalytic Pyrolysis of Tomato Plant WasteBuitrago Buitrago, Jose LuisMendez, Leticia JesicaMusci, Juan JoséCecilia, Juan AntonioBallesteros Plata, DanielRodríguez Castellón, EnriqueCasella, Mónica LauraPizzio, Luis ReneLick, Ileana DanielaTUNGSTOPHOSPHORIC ACIDHETEROPOLYACIDSZIRCONIACATALYTIC PYROLYSISFURANSACID CATALYSTShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The use of tomato plant residues (i.e., stems, leaves, etc.) as a substrate forcatalytic pyrolysis of biomass was investigated. A comprehensive study was conductedto investigate the impact of catalysts on the performance of different pyrolysis fractions(i.e., gas, biosolid, waxes, and bioliquid) as well as the distribution of products withinthe bioliquid. The catalysts employed in this study were derived from two distinct typesof zirconia. The first type was synthesized by a conventional sol-gel method, while thesecond type was prepared with a modified method aimed at improving the presence ofmesopores. This modification involved the incorporation of Pluronic 123. These materialswere designated ZrO2 and ZrO2P25, respectively. Both types of zirconia were used assupports for tungstophosphoric acid (H3PW12O40, TPA), a heteropolyacid with a Kegginstructure, in the preparation of catalysts with strong acid sites. The results demonstratedthat the bioliquid yield of the non-catalytic fast pyrolysis of tomato plant waste wasapproximately 23% and that the obtained bioliquid contained a wide variety of molecules,which were detected and quantified by GC-MS. In the presence of the catalysts, both thebioliquid yield and the distribution of bioliquid products were substantially modified.Furthermore, the possible sugar degradation pathways leading to the formation of themolecules present in the pyrolytic bioliquids were thoroughly examined. The resultsobtained from this study indicate that the physicochemical characteristics of the catalysts,specifically their pore size and acidity, have a significant impact on the selectivity of thecatalytic processes towards valuable molecules, including anhydro-sugars and furanicderivatives such as furfural and furfuryl alcohol.Fil: Buitrago Buitrago, Jose Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Mendez, Leticia Jesica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Musci, Juan José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro de Investigaciones y Transferencia del Noroeste de la Provincia de Buenos Aires. Universidad Nacional del Noroeste de la Provincia de Buenos Aires. Centro de Investigaciones y Transferencia del Noroeste de la Provincia de Buenos Aires; ArgentinaFil: Cecilia, Juan Antonio. Universidad de Málaga; EspañaFil: Ballesteros Plata, Daniel. Universidad de Málaga; EspañaFil: Rodríguez Castellón, Enrique. Universidad de Málaga; EspañaFil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Lick, Ileana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaMDPI2025-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/266576Buitrago Buitrago, Jose Luis; Mendez, Leticia Jesica; Musci, Juan José; Cecilia, Juan Antonio; Ballesteros Plata, Daniel; et al.; Obtention and Products Distribution of Bioliquid from Catalytic Pyrolysis of Tomato Plant Waste; MDPI; Catalysts; 15; 4; 4-2025; 1-302073-4344CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4344/15/4/388info:eu-repo/semantics/altIdentifier/doi/10.3390/catal15040388info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:02:27Zoai:ri.conicet.gov.ar:11336/266576instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:02:27.968CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Obtention and Products Distribution of Bioliquid from Catalytic Pyrolysis of Tomato Plant Waste
title Obtention and Products Distribution of Bioliquid from Catalytic Pyrolysis of Tomato Plant Waste
spellingShingle Obtention and Products Distribution of Bioliquid from Catalytic Pyrolysis of Tomato Plant Waste
Buitrago Buitrago, Jose Luis
TUNGSTOPHOSPHORIC ACID
HETEROPOLYACIDS
ZIRCONIA
CATALYTIC PYROLYSIS
FURANS
ACID CATALYSTS
title_short Obtention and Products Distribution of Bioliquid from Catalytic Pyrolysis of Tomato Plant Waste
title_full Obtention and Products Distribution of Bioliquid from Catalytic Pyrolysis of Tomato Plant Waste
title_fullStr Obtention and Products Distribution of Bioliquid from Catalytic Pyrolysis of Tomato Plant Waste
title_full_unstemmed Obtention and Products Distribution of Bioliquid from Catalytic Pyrolysis of Tomato Plant Waste
title_sort Obtention and Products Distribution of Bioliquid from Catalytic Pyrolysis of Tomato Plant Waste
dc.creator.none.fl_str_mv Buitrago Buitrago, Jose Luis
Mendez, Leticia Jesica
Musci, Juan José
Cecilia, Juan Antonio
Ballesteros Plata, Daniel
Rodríguez Castellón, Enrique
Casella, Mónica Laura
Pizzio, Luis Rene
Lick, Ileana Daniela
author Buitrago Buitrago, Jose Luis
author_facet Buitrago Buitrago, Jose Luis
Mendez, Leticia Jesica
Musci, Juan José
Cecilia, Juan Antonio
Ballesteros Plata, Daniel
Rodríguez Castellón, Enrique
Casella, Mónica Laura
Pizzio, Luis Rene
Lick, Ileana Daniela
author_role author
author2 Mendez, Leticia Jesica
Musci, Juan José
Cecilia, Juan Antonio
Ballesteros Plata, Daniel
Rodríguez Castellón, Enrique
Casella, Mónica Laura
Pizzio, Luis Rene
Lick, Ileana Daniela
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv TUNGSTOPHOSPHORIC ACID
HETEROPOLYACIDS
ZIRCONIA
CATALYTIC PYROLYSIS
FURANS
ACID CATALYSTS
topic TUNGSTOPHOSPHORIC ACID
HETEROPOLYACIDS
ZIRCONIA
CATALYTIC PYROLYSIS
FURANS
ACID CATALYSTS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The use of tomato plant residues (i.e., stems, leaves, etc.) as a substrate forcatalytic pyrolysis of biomass was investigated. A comprehensive study was conductedto investigate the impact of catalysts on the performance of different pyrolysis fractions(i.e., gas, biosolid, waxes, and bioliquid) as well as the distribution of products withinthe bioliquid. The catalysts employed in this study were derived from two distinct typesof zirconia. The first type was synthesized by a conventional sol-gel method, while thesecond type was prepared with a modified method aimed at improving the presence ofmesopores. This modification involved the incorporation of Pluronic 123. These materialswere designated ZrO2 and ZrO2P25, respectively. Both types of zirconia were used assupports for tungstophosphoric acid (H3PW12O40, TPA), a heteropolyacid with a Kegginstructure, in the preparation of catalysts with strong acid sites. The results demonstratedthat the bioliquid yield of the non-catalytic fast pyrolysis of tomato plant waste wasapproximately 23% and that the obtained bioliquid contained a wide variety of molecules,which were detected and quantified by GC-MS. In the presence of the catalysts, both thebioliquid yield and the distribution of bioliquid products were substantially modified.Furthermore, the possible sugar degradation pathways leading to the formation of themolecules present in the pyrolytic bioliquids were thoroughly examined. The resultsobtained from this study indicate that the physicochemical characteristics of the catalysts,specifically their pore size and acidity, have a significant impact on the selectivity of thecatalytic processes towards valuable molecules, including anhydro-sugars and furanicderivatives such as furfural and furfuryl alcohol.
Fil: Buitrago Buitrago, Jose Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Mendez, Leticia Jesica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Musci, Juan José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro de Investigaciones y Transferencia del Noroeste de la Provincia de Buenos Aires. Universidad Nacional del Noroeste de la Provincia de Buenos Aires. Centro de Investigaciones y Transferencia del Noroeste de la Provincia de Buenos Aires; Argentina
Fil: Cecilia, Juan Antonio. Universidad de Málaga; España
Fil: Ballesteros Plata, Daniel. Universidad de Málaga; España
Fil: Rodríguez Castellón, Enrique. Universidad de Málaga; España
Fil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Lick, Ileana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
description The use of tomato plant residues (i.e., stems, leaves, etc.) as a substrate forcatalytic pyrolysis of biomass was investigated. A comprehensive study was conductedto investigate the impact of catalysts on the performance of different pyrolysis fractions(i.e., gas, biosolid, waxes, and bioliquid) as well as the distribution of products withinthe bioliquid. The catalysts employed in this study were derived from two distinct typesof zirconia. The first type was synthesized by a conventional sol-gel method, while thesecond type was prepared with a modified method aimed at improving the presence ofmesopores. This modification involved the incorporation of Pluronic 123. These materialswere designated ZrO2 and ZrO2P25, respectively. Both types of zirconia were used assupports for tungstophosphoric acid (H3PW12O40, TPA), a heteropolyacid with a Kegginstructure, in the preparation of catalysts with strong acid sites. The results demonstratedthat the bioliquid yield of the non-catalytic fast pyrolysis of tomato plant waste wasapproximately 23% and that the obtained bioliquid contained a wide variety of molecules,which were detected and quantified by GC-MS. In the presence of the catalysts, both thebioliquid yield and the distribution of bioliquid products were substantially modified.Furthermore, the possible sugar degradation pathways leading to the formation of themolecules present in the pyrolytic bioliquids were thoroughly examined. The resultsobtained from this study indicate that the physicochemical characteristics of the catalysts,specifically their pore size and acidity, have a significant impact on the selectivity of thecatalytic processes towards valuable molecules, including anhydro-sugars and furanicderivatives such as furfural and furfuryl alcohol.
publishDate 2025
dc.date.none.fl_str_mv 2025-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/266576
Buitrago Buitrago, Jose Luis; Mendez, Leticia Jesica; Musci, Juan José; Cecilia, Juan Antonio; Ballesteros Plata, Daniel; et al.; Obtention and Products Distribution of Bioliquid from Catalytic Pyrolysis of Tomato Plant Waste; MDPI; Catalysts; 15; 4; 4-2025; 1-30
2073-4344
CONICET Digital
CONICET
url http://hdl.handle.net/11336/266576
identifier_str_mv Buitrago Buitrago, Jose Luis; Mendez, Leticia Jesica; Musci, Juan José; Cecilia, Juan Antonio; Ballesteros Plata, Daniel; et al.; Obtention and Products Distribution of Bioliquid from Catalytic Pyrolysis of Tomato Plant Waste; MDPI; Catalysts; 15; 4; 4-2025; 1-30
2073-4344
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4344/15/4/388
info:eu-repo/semantics/altIdentifier/doi/10.3390/catal15040388
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269756937207808
score 13.13397

Publicaciones similares