Indigo Carmine Degradation in Water Induced by a Pulsed Positive Corona Discharge in Air: Discharge and Postdischarge Effects

Autores
Ferreyra, Matías Germán; Fina, Brenda Lorena; Milardovich, Natalio Jorge; Chamorro Garcés, Juan Camilo; Santamaria, Brenda; Balestrasse, Karina Beatriz; Prevosto, Leandro
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In recent years, one of the fastest growing technological applications in the field of nonthermal plasmas is the degradation of organic contaminants of water. In this work, the degradation of indigo carmine (IC) in water induced by a pulsed positive corona discharge operating in ambient air is reported. Degradation levels in different volumes of IC in solution with distilled water treated with different plasma exposure times immediately after discharge (0 h), and in the postdischarge up to 24 h were examined. To explain the IC discoloration in the postdischarge phase, a chemical model was developed. The stability of the reactive species in solution nitrate (NO3−), nitrite (NO2−) and hydrogen peroxide (H2O2), as well as the properties of the solution (electrical conductivity, pH) were also measured. The results suggest that the hydroxyl radical (OH˙) as well as ozone (O3) are the main oxidizing species during the discharge phase, being primarily formed in the gas phase through plasma-mediated reactions and then transferred to the liquid by diffusion, while the OH˙ production in the bulk liquid through the decomposition of peroxinitrous acid (O=NOOH) plays a major role in the IC degradation during the postdischarge. These results are associated with a noticeably increase in the energy-yield values observed at 24 h post-treatment.
Fil: Ferreyra, Matías Germán. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; Argentina
Fil: Fina, Brenda Lorena. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Milardovich, Natalio Jorge. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; Argentina
Fil: Chamorro Garcés, Juan Camilo. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Santamaria, Brenda. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; Argentina
Fil: Balestrasse, Karina Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Instituto de Investigaciones en Biociencias Agrícolas y Ambientales. Universidad de Buenos Aires. Facultad de Agronomía. Instituto de Investigaciones en Biociencias Agrícolas y Ambientales; Argentina
Fil: Prevosto, Leandro. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
INDIGO CARMINE DEGRADATION
NONTHERMAL PLASMA
POSTDISCHARGE EFFECTS
PULSED CORONA DISCHARGE
REACTIVE SPECIES IN WATER
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/212706
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/212706
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Indigo Carmine Degradation in Water Induced by a Pulsed Positive Corona Discharge in Air: Discharge and Postdischarge EffectsFerreyra, Matías GermánFina, Brenda LorenaMilardovich, Natalio JorgeChamorro Garcés, Juan CamiloSantamaria, BrendaBalestrasse, Karina BeatrizPrevosto, LeandroINDIGO CARMINE DEGRADATIONNONTHERMAL PLASMAPOSTDISCHARGE EFFECTSPULSED CORONA DISCHARGEREACTIVE SPECIES IN WATERhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1In recent years, one of the fastest growing technological applications in the field of nonthermal plasmas is the degradation of organic contaminants of water. In this work, the degradation of indigo carmine (IC) in water induced by a pulsed positive corona discharge operating in ambient air is reported. Degradation levels in different volumes of IC in solution with distilled water treated with different plasma exposure times immediately after discharge (0 h), and in the postdischarge up to 24 h were examined. To explain the IC discoloration in the postdischarge phase, a chemical model was developed. The stability of the reactive species in solution nitrate (NO3−), nitrite (NO2−) and hydrogen peroxide (H2O2), as well as the properties of the solution (electrical conductivity, pH) were also measured. The results suggest that the hydroxyl radical (OH˙) as well as ozone (O3) are the main oxidizing species during the discharge phase, being primarily formed in the gas phase through plasma-mediated reactions and then transferred to the liquid by diffusion, while the OH˙ production in the bulk liquid through the decomposition of peroxinitrous acid (O=NOOH) plays a major role in the IC degradation during the postdischarge. These results are associated with a noticeably increase in the energy-yield values observed at 24 h post-treatment.Fil: Ferreyra, Matías Germán. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; ArgentinaFil: Fina, Brenda Lorena. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Milardovich, Natalio Jorge. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; ArgentinaFil: Chamorro Garcés, Juan Camilo. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Santamaria, Brenda. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; ArgentinaFil: Balestrasse, Karina Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Instituto de Investigaciones en Biociencias Agrícolas y Ambientales. Universidad de Buenos Aires. Facultad de Agronomía. Instituto de Investigaciones en Biociencias Agrícolas y Ambientales; ArgentinaFil: Prevosto, Leandro. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaMDPI2022-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/212706Ferreyra, Matías Germán; Fina, Brenda Lorena; Milardovich, Natalio Jorge; Chamorro Garcés, Juan Camilo; Santamaria, Brenda; et al.; Indigo Carmine Degradation in Water Induced by a Pulsed Positive Corona Discharge in Air: Discharge and Postdischarge Effects; MDPI; Plasma; 5; 2; 5-2022; 265-2792571-6182CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2571-6182/5/2/21info:eu-repo/semantics/altIdentifier/doi/10.3390/plasma5020021info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:17:46Zoai:ri.conicet.gov.ar:11336/212706instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:17:47.189CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Indigo Carmine Degradation in Water Induced by a Pulsed Positive Corona Discharge in Air: Discharge and Postdischarge Effects
title Indigo Carmine Degradation in Water Induced by a Pulsed Positive Corona Discharge in Air: Discharge and Postdischarge Effects
spellingShingle Indigo Carmine Degradation in Water Induced by a Pulsed Positive Corona Discharge in Air: Discharge and Postdischarge Effects
Ferreyra, Matías Germán
INDIGO CARMINE DEGRADATION
NONTHERMAL PLASMA
POSTDISCHARGE EFFECTS
PULSED CORONA DISCHARGE
REACTIVE SPECIES IN WATER
title_short Indigo Carmine Degradation in Water Induced by a Pulsed Positive Corona Discharge in Air: Discharge and Postdischarge Effects
title_full Indigo Carmine Degradation in Water Induced by a Pulsed Positive Corona Discharge in Air: Discharge and Postdischarge Effects
title_fullStr Indigo Carmine Degradation in Water Induced by a Pulsed Positive Corona Discharge in Air: Discharge and Postdischarge Effects
title_full_unstemmed Indigo Carmine Degradation in Water Induced by a Pulsed Positive Corona Discharge in Air: Discharge and Postdischarge Effects
title_sort Indigo Carmine Degradation in Water Induced by a Pulsed Positive Corona Discharge in Air: Discharge and Postdischarge Effects
dc.creator.none.fl_str_mv Ferreyra, Matías Germán
Fina, Brenda Lorena
Milardovich, Natalio Jorge
Chamorro Garcés, Juan Camilo
Santamaria, Brenda
Balestrasse, Karina Beatriz
Prevosto, Leandro
author Ferreyra, Matías Germán
author_facet Ferreyra, Matías Germán
Fina, Brenda Lorena
Milardovich, Natalio Jorge
Chamorro Garcés, Juan Camilo
Santamaria, Brenda
Balestrasse, Karina Beatriz
Prevosto, Leandro
author_role author
author2 Fina, Brenda Lorena
Milardovich, Natalio Jorge
Chamorro Garcés, Juan Camilo
Santamaria, Brenda
Balestrasse, Karina Beatriz
Prevosto, Leandro
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv INDIGO CARMINE DEGRADATION
NONTHERMAL PLASMA
POSTDISCHARGE EFFECTS
PULSED CORONA DISCHARGE
REACTIVE SPECIES IN WATER
topic INDIGO CARMINE DEGRADATION
NONTHERMAL PLASMA
POSTDISCHARGE EFFECTS
PULSED CORONA DISCHARGE
REACTIVE SPECIES IN WATER
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In recent years, one of the fastest growing technological applications in the field of nonthermal plasmas is the degradation of organic contaminants of water. In this work, the degradation of indigo carmine (IC) in water induced by a pulsed positive corona discharge operating in ambient air is reported. Degradation levels in different volumes of IC in solution with distilled water treated with different plasma exposure times immediately after discharge (0 h), and in the postdischarge up to 24 h were examined. To explain the IC discoloration in the postdischarge phase, a chemical model was developed. The stability of the reactive species in solution nitrate (NO3−), nitrite (NO2−) and hydrogen peroxide (H2O2), as well as the properties of the solution (electrical conductivity, pH) were also measured. The results suggest that the hydroxyl radical (OH˙) as well as ozone (O3) are the main oxidizing species during the discharge phase, being primarily formed in the gas phase through plasma-mediated reactions and then transferred to the liquid by diffusion, while the OH˙ production in the bulk liquid through the decomposition of peroxinitrous acid (O=NOOH) plays a major role in the IC degradation during the postdischarge. These results are associated with a noticeably increase in the energy-yield values observed at 24 h post-treatment.
Fil: Ferreyra, Matías Germán. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; Argentina
Fil: Fina, Brenda Lorena. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Milardovich, Natalio Jorge. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; Argentina
Fil: Chamorro Garcés, Juan Camilo. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Santamaria, Brenda. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; Argentina
Fil: Balestrasse, Karina Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Instituto de Investigaciones en Biociencias Agrícolas y Ambientales. Universidad de Buenos Aires. Facultad de Agronomía. Instituto de Investigaciones en Biociencias Agrícolas y Ambientales; Argentina
Fil: Prevosto, Leandro. Universidad Tecnológica Nacional. Facultad Regional Venado Tuerto; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description In recent years, one of the fastest growing technological applications in the field of nonthermal plasmas is the degradation of organic contaminants of water. In this work, the degradation of indigo carmine (IC) in water induced by a pulsed positive corona discharge operating in ambient air is reported. Degradation levels in different volumes of IC in solution with distilled water treated with different plasma exposure times immediately after discharge (0 h), and in the postdischarge up to 24 h were examined. To explain the IC discoloration in the postdischarge phase, a chemical model was developed. The stability of the reactive species in solution nitrate (NO3−), nitrite (NO2−) and hydrogen peroxide (H2O2), as well as the properties of the solution (electrical conductivity, pH) were also measured. The results suggest that the hydroxyl radical (OH˙) as well as ozone (O3) are the main oxidizing species during the discharge phase, being primarily formed in the gas phase through plasma-mediated reactions and then transferred to the liquid by diffusion, while the OH˙ production in the bulk liquid through the decomposition of peroxinitrous acid (O=NOOH) plays a major role in the IC degradation during the postdischarge. These results are associated with a noticeably increase in the energy-yield values observed at 24 h post-treatment.
publishDate 2022
dc.date.none.fl_str_mv 2022-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/212706
Ferreyra, Matías Germán; Fina, Brenda Lorena; Milardovich, Natalio Jorge; Chamorro Garcés, Juan Camilo; Santamaria, Brenda; et al.; Indigo Carmine Degradation in Water Induced by a Pulsed Positive Corona Discharge in Air: Discharge and Postdischarge Effects; MDPI; Plasma; 5; 2; 5-2022; 265-279
2571-6182
CONICET Digital
CONICET
url http://hdl.handle.net/11336/212706
identifier_str_mv Ferreyra, Matías Germán; Fina, Brenda Lorena; Milardovich, Natalio Jorge; Chamorro Garcés, Juan Camilo; Santamaria, Brenda; et al.; Indigo Carmine Degradation in Water Induced by a Pulsed Positive Corona Discharge in Air: Discharge and Postdischarge Effects; MDPI; Plasma; 5; 2; 5-2022; 265-279
2571-6182
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2571-6182/5/2/21
info:eu-repo/semantics/altIdentifier/doi/10.3390/plasma5020021
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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