Reversible hydrogen storage from 6LiBH4–MCl3 (M = Ce, Gd) composites by in-situ formation of MH2

Autores
Gennari, Fabiana Cristina; Fernández Albanesi, Luisa Francisca; Puszkiel, Julián Atilio; Arneodo Larochette, Pierre Paul
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Different destabilized LiBH4 systems with several interacting components are being explored for hydrogen storage applications. In this study, hydrogen sorption properties of as-milled 6LiBH4–MCl3 composites (M = Ce, Gd) are investigated by X-ray diffraction, differential scanning calorimetry and thermovolumetric measurements. The chemical interaction between metal halides and LiBH4 decreases the dehydrogenation temperature in comparison with as-milled LiBH4. Hydrogen release starts at 220 °C from the decomposition of M(BH4)3 formed during milling and proceeds through destabilization of LiBH4 by in-situ formed MH2. The dehydrogenation products CeB6–LiH and GdB4–LiH can be rehydrided under moderate conditions, i.e 400 °C and 6.0 MPa of hydrogen pressure for 2 h without catalyst. A new 6LiBH4–CeCl3–3LiH composite shows promissory hydrogen storage properties via the formation by milling of CeH2+x. Our study is the first work about reversible hydrogen storage in LiBH4–MCl3 composites destabilized by in-situ formed MH2.
Fil: Gennari, Fabiana Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Fernández Albanesi, Luisa Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Puszkiel, Julián Atilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Arneodo Larochette, Pierre Paul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Materia
COMPLEX
HYDRIDES
BOROHYDRIDES
COMPOSITE
POWDERS
MECHANICAL
MILLING
BORIDES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/271411
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Reversible hydrogen storage from 6LiBH4–MCl3 (M = Ce, Gd) composites by in-situ formation of MH2Gennari, Fabiana CristinaFernández Albanesi, Luisa FranciscaPuszkiel, Julián AtilioArneodo Larochette, Pierre PaulCOMPLEXHYDRIDESBOROHYDRIDESCOMPOSITEPOWDERSMECHANICALMILLINGBORIDEShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Different destabilized LiBH4 systems with several interacting components are being explored for hydrogen storage applications. In this study, hydrogen sorption properties of as-milled 6LiBH4–MCl3 composites (M = Ce, Gd) are investigated by X-ray diffraction, differential scanning calorimetry and thermovolumetric measurements. The chemical interaction between metal halides and LiBH4 decreases the dehydrogenation temperature in comparison with as-milled LiBH4. Hydrogen release starts at 220 °C from the decomposition of M(BH4)3 formed during milling and proceeds through destabilization of LiBH4 by in-situ formed MH2. The dehydrogenation products CeB6–LiH and GdB4–LiH can be rehydrided under moderate conditions, i.e 400 °C and 6.0 MPa of hydrogen pressure for 2 h without catalyst. A new 6LiBH4–CeCl3–3LiH composite shows promissory hydrogen storage properties via the formation by milling of CeH2+x. Our study is the first work about reversible hydrogen storage in LiBH4–MCl3 composites destabilized by in-situ formed MH2.Fil: Gennari, Fabiana Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; ArgentinaFil: Fernández Albanesi, Luisa Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; ArgentinaFil: Puszkiel, Julián Atilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; ArgentinaFil: Arneodo Larochette, Pierre Paul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; ArgentinaPergamon-Elsevier Science Ltd2011-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/271411Gennari, Fabiana Cristina; Fernández Albanesi, Luisa Francisca; Puszkiel, Julián Atilio; Arneodo Larochette, Pierre Paul; Reversible hydrogen storage from 6LiBH4–MCl3 (M = Ce, Gd) composites by in-situ formation of MH2; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 36; 1; 1-2011; 563-5700360-3199CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0360319910020574info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2010.10.010info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:46:11Zoai:ri.conicet.gov.ar:11336/271411instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:46:11.377CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Reversible hydrogen storage from 6LiBH4–MCl3 (M = Ce, Gd) composites by in-situ formation of MH2
title Reversible hydrogen storage from 6LiBH4–MCl3 (M = Ce, Gd) composites by in-situ formation of MH2
spellingShingle Reversible hydrogen storage from 6LiBH4–MCl3 (M = Ce, Gd) composites by in-situ formation of MH2
Gennari, Fabiana Cristina
COMPLEX
HYDRIDES
BOROHYDRIDES
COMPOSITE
POWDERS
MECHANICAL
MILLING
BORIDES
title_short Reversible hydrogen storage from 6LiBH4–MCl3 (M = Ce, Gd) composites by in-situ formation of MH2
title_full Reversible hydrogen storage from 6LiBH4–MCl3 (M = Ce, Gd) composites by in-situ formation of MH2
title_fullStr Reversible hydrogen storage from 6LiBH4–MCl3 (M = Ce, Gd) composites by in-situ formation of MH2
title_full_unstemmed Reversible hydrogen storage from 6LiBH4–MCl3 (M = Ce, Gd) composites by in-situ formation of MH2
title_sort Reversible hydrogen storage from 6LiBH4–MCl3 (M = Ce, Gd) composites by in-situ formation of MH2
dc.creator.none.fl_str_mv Gennari, Fabiana Cristina
Fernández Albanesi, Luisa Francisca
Puszkiel, Julián Atilio
Arneodo Larochette, Pierre Paul
author Gennari, Fabiana Cristina
author_facet Gennari, Fabiana Cristina
Fernández Albanesi, Luisa Francisca
Puszkiel, Julián Atilio
Arneodo Larochette, Pierre Paul
author_role author
author2 Fernández Albanesi, Luisa Francisca
Puszkiel, Julián Atilio
Arneodo Larochette, Pierre Paul
author2_role author
author
author
dc.subject.none.fl_str_mv COMPLEX
HYDRIDES
BOROHYDRIDES
COMPOSITE
POWDERS
MECHANICAL
MILLING
BORIDES
topic COMPLEX
HYDRIDES
BOROHYDRIDES
COMPOSITE
POWDERS
MECHANICAL
MILLING
BORIDES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Different destabilized LiBH4 systems with several interacting components are being explored for hydrogen storage applications. In this study, hydrogen sorption properties of as-milled 6LiBH4–MCl3 composites (M = Ce, Gd) are investigated by X-ray diffraction, differential scanning calorimetry and thermovolumetric measurements. The chemical interaction between metal halides and LiBH4 decreases the dehydrogenation temperature in comparison with as-milled LiBH4. Hydrogen release starts at 220 °C from the decomposition of M(BH4)3 formed during milling and proceeds through destabilization of LiBH4 by in-situ formed MH2. The dehydrogenation products CeB6–LiH and GdB4–LiH can be rehydrided under moderate conditions, i.e 400 °C and 6.0 MPa of hydrogen pressure for 2 h without catalyst. A new 6LiBH4–CeCl3–3LiH composite shows promissory hydrogen storage properties via the formation by milling of CeH2+x. Our study is the first work about reversible hydrogen storage in LiBH4–MCl3 composites destabilized by in-situ formed MH2.
Fil: Gennari, Fabiana Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Fernández Albanesi, Luisa Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Puszkiel, Julián Atilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Arneodo Larochette, Pierre Paul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
description Different destabilized LiBH4 systems with several interacting components are being explored for hydrogen storage applications. In this study, hydrogen sorption properties of as-milled 6LiBH4–MCl3 composites (M = Ce, Gd) are investigated by X-ray diffraction, differential scanning calorimetry and thermovolumetric measurements. The chemical interaction between metal halides and LiBH4 decreases the dehydrogenation temperature in comparison with as-milled LiBH4. Hydrogen release starts at 220 °C from the decomposition of M(BH4)3 formed during milling and proceeds through destabilization of LiBH4 by in-situ formed MH2. The dehydrogenation products CeB6–LiH and GdB4–LiH can be rehydrided under moderate conditions, i.e 400 °C and 6.0 MPa of hydrogen pressure for 2 h without catalyst. A new 6LiBH4–CeCl3–3LiH composite shows promissory hydrogen storage properties via the formation by milling of CeH2+x. Our study is the first work about reversible hydrogen storage in LiBH4–MCl3 composites destabilized by in-situ formed MH2.
publishDate 2011
dc.date.none.fl_str_mv 2011-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/271411
Gennari, Fabiana Cristina; Fernández Albanesi, Luisa Francisca; Puszkiel, Julián Atilio; Arneodo Larochette, Pierre Paul; Reversible hydrogen storage from 6LiBH4–MCl3 (M = Ce, Gd) composites by in-situ formation of MH2; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 36; 1; 1-2011; 563-570
0360-3199
CONICET Digital
CONICET
url http://hdl.handle.net/11336/271411
identifier_str_mv Gennari, Fabiana Cristina; Fernández Albanesi, Luisa Francisca; Puszkiel, Julián Atilio; Arneodo Larochette, Pierre Paul; Reversible hydrogen storage from 6LiBH4–MCl3 (M = Ce, Gd) composites by in-situ formation of MH2; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 36; 1; 1-2011; 563-570
0360-3199
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0360319910020574
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2010.10.010
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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