Fluorinated polyurethanes. XPS and AFM characterization

Autores
Penoff, Marcela Elisabeth; Schreiner, Wido; Oyanguren, Patricia Angelica; Montemartini, Pablo Ezequiel
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
fluorinated polyurethane films were obtained from 5-isocyanato-1-(isocyanatomethyl)-1,3,3-trimethyl-cyclohexane (IPDI) and polyethylene oxide (PEO), employing two monoalcohols with different chain lenghts as fluorinated modifiers, 1H,1H,2H,2H-tridecafluoro-1-n-octanol (EA600) and 1H,1H,2H,2H-heptadecafluoro-1-n-decanol (EA800). X-ray photoelectron spectroscopy (XPS) has demonstrated that fluorine surface enrichment takes place. Atomic force microscopy (AFM) was employed in order to characterize films surfaces, in terms of topography and differences in hydrophobicity from light and moderate tapping conditions.
Fil: Penoff, Marcela Elisabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Schreiner, Wido. Federal University of Parana. Surfaces and Interfaces Laboratory; Brasil
Fil: Oyanguren, Patricia Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Montemartini, Pablo Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Materia
Atomic Force Microscopy
Films
Fluoropolymers
Polyurethane
Surfaces
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/6244
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Fluorinated polyurethanes. XPS and AFM characterizationPenoff, Marcela ElisabethSchreiner, WidoOyanguren, Patricia AngelicaMontemartini, Pablo EzequielAtomic Force MicroscopyFilmsFluoropolymersPolyurethaneSurfaceshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1fluorinated polyurethane films were obtained from 5-isocyanato-1-(isocyanatomethyl)-1,3,3-trimethyl-cyclohexane (IPDI) and polyethylene oxide (PEO), employing two monoalcohols with different chain lenghts as fluorinated modifiers, 1H,1H,2H,2H-tridecafluoro-1-n-octanol (EA600) and 1H,1H,2H,2H-heptadecafluoro-1-n-decanol (EA800). X-ray photoelectron spectroscopy (XPS) has demonstrated that fluorine surface enrichment takes place. Atomic force microscopy (AFM) was employed in order to characterize films surfaces, in terms of topography and differences in hydrophobicity from light and moderate tapping conditions.Fil: Penoff, Marcela Elisabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Schreiner, Wido. Federal University of Parana. Surfaces and Interfaces Laboratory; BrasilFil: Oyanguren, Patricia Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Montemartini, Pablo Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaWiley2012-12-18info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/vnd.openxmlformats-officedocument.wordprocessingml.documentapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/6244Penoff, Marcela Elisabeth; Schreiner, Wido; Oyanguren, Patricia Angelica; Montemartini, Pablo Ezequiel; Fluorinated polyurethanes. XPS and AFM characterization; Wiley; Macromolecular Symposia; 321-322; 1; 18-12-2012; 186-1901022-1360enginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/masy.201251133/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/masy.201251133info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:19:03Zoai:ri.conicet.gov.ar:11336/6244instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:19:03.542CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Fluorinated polyurethanes. XPS and AFM characterization
title Fluorinated polyurethanes. XPS and AFM characterization
spellingShingle Fluorinated polyurethanes. XPS and AFM characterization
Penoff, Marcela Elisabeth
Atomic Force Microscopy
Films
Fluoropolymers
Polyurethane
Surfaces
title_short Fluorinated polyurethanes. XPS and AFM characterization
title_full Fluorinated polyurethanes. XPS and AFM characterization
title_fullStr Fluorinated polyurethanes. XPS and AFM characterization
title_full_unstemmed Fluorinated polyurethanes. XPS and AFM characterization
title_sort Fluorinated polyurethanes. XPS and AFM characterization
dc.creator.none.fl_str_mv Penoff, Marcela Elisabeth
Schreiner, Wido
Oyanguren, Patricia Angelica
Montemartini, Pablo Ezequiel
author Penoff, Marcela Elisabeth
author_facet Penoff, Marcela Elisabeth
Schreiner, Wido
Oyanguren, Patricia Angelica
Montemartini, Pablo Ezequiel
author_role author
author2 Schreiner, Wido
Oyanguren, Patricia Angelica
Montemartini, Pablo Ezequiel
author2_role author
author
author
dc.subject.none.fl_str_mv Atomic Force Microscopy
Films
Fluoropolymers
Polyurethane
Surfaces
topic Atomic Force Microscopy
Films
Fluoropolymers
Polyurethane
Surfaces
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv fluorinated polyurethane films were obtained from 5-isocyanato-1-(isocyanatomethyl)-1,3,3-trimethyl-cyclohexane (IPDI) and polyethylene oxide (PEO), employing two monoalcohols with different chain lenghts as fluorinated modifiers, 1H,1H,2H,2H-tridecafluoro-1-n-octanol (EA600) and 1H,1H,2H,2H-heptadecafluoro-1-n-decanol (EA800). X-ray photoelectron spectroscopy (XPS) has demonstrated that fluorine surface enrichment takes place. Atomic force microscopy (AFM) was employed in order to characterize films surfaces, in terms of topography and differences in hydrophobicity from light and moderate tapping conditions.
Fil: Penoff, Marcela Elisabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Schreiner, Wido. Federal University of Parana. Surfaces and Interfaces Laboratory; Brasil
Fil: Oyanguren, Patricia Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Montemartini, Pablo Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
description fluorinated polyurethane films were obtained from 5-isocyanato-1-(isocyanatomethyl)-1,3,3-trimethyl-cyclohexane (IPDI) and polyethylene oxide (PEO), employing two monoalcohols with different chain lenghts as fluorinated modifiers, 1H,1H,2H,2H-tridecafluoro-1-n-octanol (EA600) and 1H,1H,2H,2H-heptadecafluoro-1-n-decanol (EA800). X-ray photoelectron spectroscopy (XPS) has demonstrated that fluorine surface enrichment takes place. Atomic force microscopy (AFM) was employed in order to characterize films surfaces, in terms of topography and differences in hydrophobicity from light and moderate tapping conditions.
publishDate 2012
dc.date.none.fl_str_mv 2012-12-18
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/6244
Penoff, Marcela Elisabeth; Schreiner, Wido; Oyanguren, Patricia Angelica; Montemartini, Pablo Ezequiel; Fluorinated polyurethanes. XPS and AFM characterization; Wiley; Macromolecular Symposia; 321-322; 1; 18-12-2012; 186-190
1022-1360
url http://hdl.handle.net/11336/6244
identifier_str_mv Penoff, Marcela Elisabeth; Schreiner, Wido; Oyanguren, Patricia Angelica; Montemartini, Pablo Ezequiel; Fluorinated polyurethanes. XPS and AFM characterization; Wiley; Macromolecular Symposia; 321-322; 1; 18-12-2012; 186-190
1022-1360
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/masy.201251133/abstract
info:eu-repo/semantics/altIdentifier/doi/10.1002/masy.201251133
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/vnd.openxmlformats-officedocument.wordprocessingml.document
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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