Partially fluorinated polymer networks: Synthesis and structural characterization
- Autores
- Miccio, Luis Alejandro; Liaño, Rocio; Montemartini, Pablo Ezequiel; Oyanguren, Patricia Angelica
- Año de publicación
- 2011
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Functionalizacion of epoxy-based networks by the preferential surface enrichment of perfluorinated tails to achieve hydrophobic surface is described. The selected fluorinated epoxies (FE) were: 2,2,3,3,4,4,5,5,6,6,7,7,8,9,9,9-hexadecafluoro-8-trifluoromethyl nonyloxirane (FED3) and 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro nonyloxirane (FES3). Two series of crosslinked fluorinated epoxy-based materials containing variable fluorine contents (from 0 to 5 wt % F) were prepared using formulations based on partially fluorinated diamine, epoxy monomer and a curing agent. The epoxy monomer was based on diglycidyl ether of bisphenol A (DGEBA) while the curing agents were either propyleneoxide diamine (JEFFAMINE) or 4,4′-methylenebis(3-chloro 2,6-diethylaniline) (MCDEA). It was found that depending on the curing agent employed, homogeneous distribution of fluorine or phase separation distinguishable at micrometer or nanometer scale was obtained when curing blends initially homogeneous. The morphology and composition of partially fluorinated networks were investigated on a micrometer scale combining scanning electron microscopy and X-ray analysis. When curing with JEFFAMINE, samples were homogeneous for all fluorine proportions. In contrast, MCDEA-cured blends showed fluorine-rich zones dispersed in a continuous epoxy-rich phase. A completely different morphology, characterized by a distribution of irregular fluorine-rich domains dispersed in an epoxy-rich phase, was obtained when curing blends initially immiscible.
Fil: Miccio, Luis Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; Argentina
Fil: Liaño, Rocio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; Argentina
Fil: Montemartini, Pablo Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; Argentina
Fil: Oyanguren, Patricia Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; Argentina - Materia
-
Networks
Fluoropolymers
Phase Separation - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/16008
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Partially fluorinated polymer networks: Synthesis and structural characterizationMiccio, Luis AlejandroLiaño, RocioMontemartini, Pablo EzequielOyanguren, Patricia AngelicaNetworksFluoropolymersPhase Separationhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Functionalizacion of epoxy-based networks by the preferential surface enrichment of perfluorinated tails to achieve hydrophobic surface is described. The selected fluorinated epoxies (FE) were: 2,2,3,3,4,4,5,5,6,6,7,7,8,9,9,9-hexadecafluoro-8-trifluoromethyl nonyloxirane (FED3) and 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro nonyloxirane (FES3). Two series of crosslinked fluorinated epoxy-based materials containing variable fluorine contents (from 0 to 5 wt % F) were prepared using formulations based on partially fluorinated diamine, epoxy monomer and a curing agent. The epoxy monomer was based on diglycidyl ether of bisphenol A (DGEBA) while the curing agents were either propyleneoxide diamine (JEFFAMINE) or 4,4′-methylenebis(3-chloro 2,6-diethylaniline) (MCDEA). It was found that depending on the curing agent employed, homogeneous distribution of fluorine or phase separation distinguishable at micrometer or nanometer scale was obtained when curing blends initially homogeneous. The morphology and composition of partially fluorinated networks were investigated on a micrometer scale combining scanning electron microscopy and X-ray analysis. When curing with JEFFAMINE, samples were homogeneous for all fluorine proportions. In contrast, MCDEA-cured blends showed fluorine-rich zones dispersed in a continuous epoxy-rich phase. A completely different morphology, characterized by a distribution of irregular fluorine-rich domains dispersed in an epoxy-rich phase, was obtained when curing blends initially immiscible.Fil: Miccio, Luis Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; ArgentinaFil: Liaño, Rocio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; ArgentinaFil: Montemartini, Pablo Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; ArgentinaFil: Oyanguren, Patricia Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; ArgentinaWiley2011-10-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/16008Miccio, Luis Alejandro; Liaño, Rocio; Montemartini, Pablo Ezequiel; Oyanguren, Patricia Angelica; Partially fluorinated polymer networks: Synthesis and structural characterization; Wiley; Journal Of Applied Polymer Science; 122; 1; 4-10-2011; 608-6160021-8995enginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/app.34204/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/app.34204info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:32:20Zoai:ri.conicet.gov.ar:11336/16008instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:32:20.535CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Partially fluorinated polymer networks: Synthesis and structural characterization |
title |
Partially fluorinated polymer networks: Synthesis and structural characterization |
spellingShingle |
Partially fluorinated polymer networks: Synthesis and structural characterization Miccio, Luis Alejandro Networks Fluoropolymers Phase Separation |
title_short |
Partially fluorinated polymer networks: Synthesis and structural characterization |
title_full |
Partially fluorinated polymer networks: Synthesis and structural characterization |
title_fullStr |
Partially fluorinated polymer networks: Synthesis and structural characterization |
title_full_unstemmed |
Partially fluorinated polymer networks: Synthesis and structural characterization |
title_sort |
Partially fluorinated polymer networks: Synthesis and structural characterization |
dc.creator.none.fl_str_mv |
Miccio, Luis Alejandro Liaño, Rocio Montemartini, Pablo Ezequiel Oyanguren, Patricia Angelica |
author |
Miccio, Luis Alejandro |
author_facet |
Miccio, Luis Alejandro Liaño, Rocio Montemartini, Pablo Ezequiel Oyanguren, Patricia Angelica |
author_role |
author |
author2 |
Liaño, Rocio Montemartini, Pablo Ezequiel Oyanguren, Patricia Angelica |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Networks Fluoropolymers Phase Separation |
topic |
Networks Fluoropolymers Phase Separation |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Functionalizacion of epoxy-based networks by the preferential surface enrichment of perfluorinated tails to achieve hydrophobic surface is described. The selected fluorinated epoxies (FE) were: 2,2,3,3,4,4,5,5,6,6,7,7,8,9,9,9-hexadecafluoro-8-trifluoromethyl nonyloxirane (FED3) and 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro nonyloxirane (FES3). Two series of crosslinked fluorinated epoxy-based materials containing variable fluorine contents (from 0 to 5 wt % F) were prepared using formulations based on partially fluorinated diamine, epoxy monomer and a curing agent. The epoxy monomer was based on diglycidyl ether of bisphenol A (DGEBA) while the curing agents were either propyleneoxide diamine (JEFFAMINE) or 4,4′-methylenebis(3-chloro 2,6-diethylaniline) (MCDEA). It was found that depending on the curing agent employed, homogeneous distribution of fluorine or phase separation distinguishable at micrometer or nanometer scale was obtained when curing blends initially homogeneous. The morphology and composition of partially fluorinated networks were investigated on a micrometer scale combining scanning electron microscopy and X-ray analysis. When curing with JEFFAMINE, samples were homogeneous for all fluorine proportions. In contrast, MCDEA-cured blends showed fluorine-rich zones dispersed in a continuous epoxy-rich phase. A completely different morphology, characterized by a distribution of irregular fluorine-rich domains dispersed in an epoxy-rich phase, was obtained when curing blends initially immiscible. Fil: Miccio, Luis Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; Argentina Fil: Liaño, Rocio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; Argentina Fil: Montemartini, Pablo Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; Argentina Fil: Oyanguren, Patricia Angelica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones En Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones En Ciencia y Tecnología de Materiales; Argentina |
description |
Functionalizacion of epoxy-based networks by the preferential surface enrichment of perfluorinated tails to achieve hydrophobic surface is described. The selected fluorinated epoxies (FE) were: 2,2,3,3,4,4,5,5,6,6,7,7,8,9,9,9-hexadecafluoro-8-trifluoromethyl nonyloxirane (FED3) and 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro nonyloxirane (FES3). Two series of crosslinked fluorinated epoxy-based materials containing variable fluorine contents (from 0 to 5 wt % F) were prepared using formulations based on partially fluorinated diamine, epoxy monomer and a curing agent. The epoxy monomer was based on diglycidyl ether of bisphenol A (DGEBA) while the curing agents were either propyleneoxide diamine (JEFFAMINE) or 4,4′-methylenebis(3-chloro 2,6-diethylaniline) (MCDEA). It was found that depending on the curing agent employed, homogeneous distribution of fluorine or phase separation distinguishable at micrometer or nanometer scale was obtained when curing blends initially homogeneous. The morphology and composition of partially fluorinated networks were investigated on a micrometer scale combining scanning electron microscopy and X-ray analysis. When curing with JEFFAMINE, samples were homogeneous for all fluorine proportions. In contrast, MCDEA-cured blends showed fluorine-rich zones dispersed in a continuous epoxy-rich phase. A completely different morphology, characterized by a distribution of irregular fluorine-rich domains dispersed in an epoxy-rich phase, was obtained when curing blends initially immiscible. |
publishDate |
2011 |
dc.date.none.fl_str_mv |
2011-10-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/16008 Miccio, Luis Alejandro; Liaño, Rocio; Montemartini, Pablo Ezequiel; Oyanguren, Patricia Angelica; Partially fluorinated polymer networks: Synthesis and structural characterization; Wiley; Journal Of Applied Polymer Science; 122; 1; 4-10-2011; 608-616 0021-8995 |
url |
http://hdl.handle.net/11336/16008 |
identifier_str_mv |
Miccio, Luis Alejandro; Liaño, Rocio; Montemartini, Pablo Ezequiel; Oyanguren, Patricia Angelica; Partially fluorinated polymer networks: Synthesis and structural characterization; Wiley; Journal Of Applied Polymer Science; 122; 1; 4-10-2011; 608-616 0021-8995 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/app.34204/abstract info:eu-repo/semantics/altIdentifier/doi/10.1002/app.34204 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley |
publisher.none.fl_str_mv |
Wiley |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.070432 |