Tl2C2O4·H2C2O4: A new crystalline form of thallium(I) oxalate

Autores
Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Gonzalez Baro, Ana Cecilia; Baran, Enrique José
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The title compound was prepared by reaction, in aqueous solution, of Tl2CO3 and H2C2O4·2H2O in a molar ratio of 1:2. Its crystal structure was solved by X-ray diffraction methods. It crystallizes in the monoclinic space group P21/a with Z = 2 molecules per unit cell. The oxalic acid molecule and the oxalate anion are planar, residing on crystallographic inversion centers, and linked to each other by strong O-H⋯O hydrogen bonds giving rise to a polymeric structure. The Tl(I) ion is in a distorted polyhedral coordination with nine neighboring O atoms, five of oxalate anions and four others of oxalic acid molecules. The FTIR and FT-Raman spectra of the compound were also recorded and are briefly discussed.
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina
Fil: Echeverría, Gustavo Alberto. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Gonzalez Baro, Ana Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Materia
Crystal Structure
Ft-Raman Spectra
Ftir Spectra
Synthesis
Thallium(I) Oxalate-Oxalic Acid
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/37887
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/37887
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Tl2C2O4·H2C2O4: A new crystalline form of thallium(I) oxalatePiro, Oscar EnriqueEcheverría, Gustavo AlbertoGonzalez Baro, Ana CeciliaBaran, Enrique JoséCrystal StructureFt-Raman SpectraFtir SpectraSynthesisThallium(I) Oxalate-Oxalic Acidhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The title compound was prepared by reaction, in aqueous solution, of Tl2CO3 and H2C2O4·2H2O in a molar ratio of 1:2. Its crystal structure was solved by X-ray diffraction methods. It crystallizes in the monoclinic space group P21/a with Z = 2 molecules per unit cell. The oxalic acid molecule and the oxalate anion are planar, residing on crystallographic inversion centers, and linked to each other by strong O-H⋯O hydrogen bonds giving rise to a polymeric structure. The Tl(I) ion is in a distorted polyhedral coordination with nine neighboring O atoms, five of oxalate anions and four others of oxalic acid molecules. The FTIR and FT-Raman spectra of the compound were also recorded and are briefly discussed.Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Física; ArgentinaFil: Echeverría, Gustavo Alberto. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Gonzalez Baro, Ana Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; ArgentinaFil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; ArgentinaVerlag der Zeitschrift für Naturforschung2015-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/37887Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Gonzalez Baro, Ana Cecilia; Baran, Enrique José; Tl2C2O4·H2C2O4: A new crystalline form of thallium(I) oxalate; Verlag der Zeitschrift für Naturforschung; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 70; 4; 4-2015; 249-2520932-07761865-7117CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2014-0257info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/znb.2015.70.issue-4/znb-2014-0257/znb-2014-0257.xmlinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-12T09:37:41Zoai:ri.conicet.gov.ar:11336/37887instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-12 09:37:41.585CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Tl2C2O4·H2C2O4: A new crystalline form of thallium(I) oxalate
title Tl2C2O4·H2C2O4: A new crystalline form of thallium(I) oxalate
spellingShingle Tl2C2O4·H2C2O4: A new crystalline form of thallium(I) oxalate
Piro, Oscar Enrique
Crystal Structure
Ft-Raman Spectra
Ftir Spectra
Synthesis
Thallium(I) Oxalate-Oxalic Acid
title_short Tl2C2O4·H2C2O4: A new crystalline form of thallium(I) oxalate
title_full Tl2C2O4·H2C2O4: A new crystalline form of thallium(I) oxalate
title_fullStr Tl2C2O4·H2C2O4: A new crystalline form of thallium(I) oxalate
title_full_unstemmed Tl2C2O4·H2C2O4: A new crystalline form of thallium(I) oxalate
title_sort Tl2C2O4·H2C2O4: A new crystalline form of thallium(I) oxalate
dc.creator.none.fl_str_mv Piro, Oscar Enrique
Echeverría, Gustavo Alberto
Gonzalez Baro, Ana Cecilia
Baran, Enrique José
author Piro, Oscar Enrique
author_facet Piro, Oscar Enrique
Echeverría, Gustavo Alberto
Gonzalez Baro, Ana Cecilia
Baran, Enrique José
author_role author
author2 Echeverría, Gustavo Alberto
Gonzalez Baro, Ana Cecilia
Baran, Enrique José
author2_role author
author
author
dc.subject.none.fl_str_mv Crystal Structure
Ft-Raman Spectra
Ftir Spectra
Synthesis
Thallium(I) Oxalate-Oxalic Acid
topic Crystal Structure
Ft-Raman Spectra
Ftir Spectra
Synthesis
Thallium(I) Oxalate-Oxalic Acid
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The title compound was prepared by reaction, in aqueous solution, of Tl2CO3 and H2C2O4·2H2O in a molar ratio of 1:2. Its crystal structure was solved by X-ray diffraction methods. It crystallizes in the monoclinic space group P21/a with Z = 2 molecules per unit cell. The oxalic acid molecule and the oxalate anion are planar, residing on crystallographic inversion centers, and linked to each other by strong O-H⋯O hydrogen bonds giving rise to a polymeric structure. The Tl(I) ion is in a distorted polyhedral coordination with nine neighboring O atoms, five of oxalate anions and four others of oxalic acid molecules. The FTIR and FT-Raman spectra of the compound were also recorded and are briefly discussed.
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina
Fil: Echeverría, Gustavo Alberto. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Gonzalez Baro, Ana Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Fil: Baran, Enrique José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
description The title compound was prepared by reaction, in aqueous solution, of Tl2CO3 and H2C2O4·2H2O in a molar ratio of 1:2. Its crystal structure was solved by X-ray diffraction methods. It crystallizes in the monoclinic space group P21/a with Z = 2 molecules per unit cell. The oxalic acid molecule and the oxalate anion are planar, residing on crystallographic inversion centers, and linked to each other by strong O-H⋯O hydrogen bonds giving rise to a polymeric structure. The Tl(I) ion is in a distorted polyhedral coordination with nine neighboring O atoms, five of oxalate anions and four others of oxalic acid molecules. The FTIR and FT-Raman spectra of the compound were also recorded and are briefly discussed.
publishDate 2015
dc.date.none.fl_str_mv 2015-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/37887
Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Gonzalez Baro, Ana Cecilia; Baran, Enrique José; Tl2C2O4·H2C2O4: A new crystalline form of thallium(I) oxalate; Verlag der Zeitschrift für Naturforschung; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 70; 4; 4-2015; 249-252
0932-0776
1865-7117
CONICET Digital
CONICET
url http://hdl.handle.net/11336/37887
identifier_str_mv Piro, Oscar Enrique; Echeverría, Gustavo Alberto; Gonzalez Baro, Ana Cecilia; Baran, Enrique José; Tl2C2O4·H2C2O4: A new crystalline form of thallium(I) oxalate; Verlag der Zeitschrift für Naturforschung; Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences; 70; 4; 4-2015; 249-252
0932-0776
1865-7117
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2014-0257
info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/znb.2015.70.issue-4/znb-2014-0257/znb-2014-0257.xml
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Verlag der Zeitschrift für Naturforschung
publisher.none.fl_str_mv Verlag der Zeitschrift für Naturforschung
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.976206

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