Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate

Autores
Piro, Oscar Enrique; Echeverría, Gustavo Alberto; González Baró, Ana Cecilia; Baran, Enrique José
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The title compound was prepared by reaction, in aqueous solution, of Tl2CO3 and H2C2O4·2H2O in a molar ratio of 1:2. Its crystal structure was solved by X-ray diffraction methods. It crystallizes in the monoclinic space group P21/a with Z = 2 molecules per unit cell. The oxalic acid molecule and the oxalate anion are planar, residing on crystallographic inversion centers, and linked to each other by strong O–H···O hydrogen bonds giving rise to a polymeric structure. The Tl(I) ion is in a distorted polyhedral coordination with nine neighboring O atoms, five of oxalate anions and four others of oxalic acid molecules. The FTIR and FT-Raman spectra of the compound were also recorded and are briefly discussed.
Centro de Química Inorgánica
Materia
Química
crystal structure
FTIR spectra
FT-Raman spectra
synthesis
thallium(I) oxalate-oxalic acid
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/117142
Acceder
id SEDICI_427ead32a002693e1c732cdb3a5bf33e
oai_identifier_str oai:sedici.unlp.edu.ar:10915/117142
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalatePiro, Oscar EnriqueEcheverría, Gustavo AlbertoGonzález Baró, Ana CeciliaBaran, Enrique JoséQuímicacrystal structureFTIR spectraFT-Raman spectrasynthesisthallium(I) oxalate-oxalic acidThe title compound was prepared by reaction, in aqueous solution, of Tl2CO3 and H2C2O4·2H2O in a molar ratio of 1:2. Its crystal structure was solved by X-ray diffraction methods. It crystallizes in the monoclinic space group P21/a with Z = 2 molecules per unit cell. The oxalic acid molecule and the oxalate anion are planar, residing on crystallographic inversion centers, and linked to each other by strong O–H···O hydrogen bonds giving rise to a polymeric structure. The Tl(I) ion is in a distorted polyhedral coordination with nine neighboring O atoms, five of oxalate anions and four others of oxalic acid molecules. The FTIR and FT-Raman spectra of the compound were also recorded and are briefly discussed.Centro de Química Inorgánica2015info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf249-252http://sedici.unlp.edu.ar/handle/10915/117142enginfo:eu-repo/semantics/altIdentifier/issn/0932-0776info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2014-0257info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-03T10:59:42Zoai:sedici.unlp.edu.ar:10915/117142Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-03 10:59:42.319SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate
title Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate
spellingShingle Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate
Piro, Oscar Enrique
Química
crystal structure
FTIR spectra
FT-Raman spectra
synthesis
thallium(I) oxalate-oxalic acid
title_short Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate
title_full Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate
title_fullStr Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate
title_full_unstemmed Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate
title_sort Tl<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>·H<SUB>2</SUB>C<SUB>2</SUB>O<SUB>4</SUB>: a new crystalline form of thallium(I) oxalate
dc.creator.none.fl_str_mv Piro, Oscar Enrique
Echeverría, Gustavo Alberto
González Baró, Ana Cecilia
Baran, Enrique José
author Piro, Oscar Enrique
author_facet Piro, Oscar Enrique
Echeverría, Gustavo Alberto
González Baró, Ana Cecilia
Baran, Enrique José
author_role author
author2 Echeverría, Gustavo Alberto
González Baró, Ana Cecilia
Baran, Enrique José
author2_role author
author
author
dc.subject.none.fl_str_mv Química
crystal structure
FTIR spectra
FT-Raman spectra
synthesis
thallium(I) oxalate-oxalic acid
topic Química
crystal structure
FTIR spectra
FT-Raman spectra
synthesis
thallium(I) oxalate-oxalic acid
dc.description.none.fl_txt_mv The title compound was prepared by reaction, in aqueous solution, of Tl2CO3 and H2C2O4·2H2O in a molar ratio of 1:2. Its crystal structure was solved by X-ray diffraction methods. It crystallizes in the monoclinic space group P21/a with Z = 2 molecules per unit cell. The oxalic acid molecule and the oxalate anion are planar, residing on crystallographic inversion centers, and linked to each other by strong O–H···O hydrogen bonds giving rise to a polymeric structure. The Tl(I) ion is in a distorted polyhedral coordination with nine neighboring O atoms, five of oxalate anions and four others of oxalic acid molecules. The FTIR and FT-Raman spectra of the compound were also recorded and are briefly discussed.
Centro de Química Inorgánica
description The title compound was prepared by reaction, in aqueous solution, of Tl2CO3 and H2C2O4·2H2O in a molar ratio of 1:2. Its crystal structure was solved by X-ray diffraction methods. It crystallizes in the monoclinic space group P21/a with Z = 2 molecules per unit cell. The oxalic acid molecule and the oxalate anion are planar, residing on crystallographic inversion centers, and linked to each other by strong O–H···O hydrogen bonds giving rise to a polymeric structure. The Tl(I) ion is in a distorted polyhedral coordination with nine neighboring O atoms, five of oxalate anions and four others of oxalic acid molecules. The FTIR and FT-Raman spectra of the compound were also recorded and are briefly discussed.
publishDate 2015
dc.date.none.fl_str_mv 2015
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/117142
url http://sedici.unlp.edu.ar/handle/10915/117142
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0932-0776
info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-2014-0257
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
249-252
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.13397

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