A thermocatalytic perovskite-graphene oxide nanofiltration membrane for water depollution

Autores
Bortot Coelho, Fabricio E.; Nurisso, Federica; Boffa, Vittorio; Ma, Xianzheng; Rasse Suriani, Federico Ariel Osvaldo; Roslev, Peter; Magnacca, Giuliana; Candelario, Victor; Deganello, Francesca; La Parola, Valeria
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A novel nanofiltration membrane, whose active layer consists of 98.6 wt% of a thermocatalytic perovskite with composition Sr0.85Ce0.15FeO3-δ (CSF), 1.0 wt% of graphene oxide (GO), and 0.4 wt% of a humic acid-like (HAL) crosslinker, was deposited over a commercial flat-sheet polyethersulfone support with good reproducibility by a simple 1-step coating procedure. The synergistic coupling of CSF and the crosslinked GO resulted in an improved catalytic activity for bisphenol A (BPA) abatement as a model pollutant. The thermocatalytic CSF/GO/HAL (GOT) membrane was tested in a nanofiltration crossflow apparatus with a model BPA solution and with a real urban wastewater treatment plant effluent. Its performances were compared with those of a HAL crosslinked GO (GOHAL) reference membrane. The GOT membrane presented high rejection towards BPA, antifouling properties, and stability under the filtration conditions. Moreover, when compared to the GOHAL reference, the thermocatalytic GOT membrane was able to reduce the concentration of BPA and the total organic carbon in the feed during filtration. Hence, the GOT membrane appears to have high potential in water treatment due to its multifunctional characteristics, which include molecular sieving, thermocatalytic oxidation of organic pollutants, and self-cleaning properties. Additionally, the membrane material showed no significant toxicity to the aquatic model organisms Raphidocelis subcapitata, Aliivibrio fischeri, and Daphnia magna at concentrations below 50 ppm.
Fil: Bortot Coelho, Fabricio E.. Università di Torino; Italia. Liqtech International A/s; Dinamarca
Fil: Nurisso, Federica. Università di Torino; Italia. Aalborg University; Dinamarca
Fil: Boffa, Vittorio. Aalborg University; Dinamarca
Fil: Ma, Xianzheng. Aalborg University; Dinamarca
Fil: Rasse Suriani, Federico Ariel Osvaldo. Aalborg University; Dinamarca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Roslev, Peter. Aalborg University; Dinamarca
Fil: Magnacca, Giuliana. Università di Torino; Italia
Fil: Candelario, Victor. Liqtech International A/s; Dinamarca
Fil: Deganello, Francesca. Istituto Per Lo Studio Dei Materiali Nanostrutturati, Rome; Italia
Fil: La Parola, Valeria. Istituto Per Lo Studio Dei Materiali Nanostrutturati, Rome; Italia
Materia
CONTAMINANTS OF EMERGING CONCERN
NANOCOMPOSITE
STRONTIUM FERRATE
TOXICOLOGICAL TESTS
WASTEWATER
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/203810
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/203810
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A thermocatalytic perovskite-graphene oxide nanofiltration membrane for water depollutionBortot Coelho, Fabricio E.Nurisso, FedericaBoffa, VittorioMa, XianzhengRasse Suriani, Federico Ariel OsvaldoRoslev, PeterMagnacca, GiulianaCandelario, VictorDeganello, FrancescaLa Parola, ValeriaCONTAMINANTS OF EMERGING CONCERNNANOCOMPOSITESTRONTIUM FERRATETOXICOLOGICAL TESTSWASTEWATERhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2A novel nanofiltration membrane, whose active layer consists of 98.6 wt% of a thermocatalytic perovskite with composition Sr0.85Ce0.15FeO3-δ (CSF), 1.0 wt% of graphene oxide (GO), and 0.4 wt% of a humic acid-like (HAL) crosslinker, was deposited over a commercial flat-sheet polyethersulfone support with good reproducibility by a simple 1-step coating procedure. The synergistic coupling of CSF and the crosslinked GO resulted in an improved catalytic activity for bisphenol A (BPA) abatement as a model pollutant. The thermocatalytic CSF/GO/HAL (GOT) membrane was tested in a nanofiltration crossflow apparatus with a model BPA solution and with a real urban wastewater treatment plant effluent. Its performances were compared with those of a HAL crosslinked GO (GOHAL) reference membrane. The GOT membrane presented high rejection towards BPA, antifouling properties, and stability under the filtration conditions. Moreover, when compared to the GOHAL reference, the thermocatalytic GOT membrane was able to reduce the concentration of BPA and the total organic carbon in the feed during filtration. Hence, the GOT membrane appears to have high potential in water treatment due to its multifunctional characteristics, which include molecular sieving, thermocatalytic oxidation of organic pollutants, and self-cleaning properties. Additionally, the membrane material showed no significant toxicity to the aquatic model organisms Raphidocelis subcapitata, Aliivibrio fischeri, and Daphnia magna at concentrations below 50 ppm.Fil: Bortot Coelho, Fabricio E.. Università di Torino; Italia. Liqtech International A/s; DinamarcaFil: Nurisso, Federica. Università di Torino; Italia. Aalborg University; DinamarcaFil: Boffa, Vittorio. Aalborg University; DinamarcaFil: Ma, Xianzheng. Aalborg University; DinamarcaFil: Rasse Suriani, Federico Ariel Osvaldo. Aalborg University; Dinamarca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Roslev, Peter. Aalborg University; DinamarcaFil: Magnacca, Giuliana. Università di Torino; ItaliaFil: Candelario, Victor. Liqtech International A/s; DinamarcaFil: Deganello, Francesca. Istituto Per Lo Studio Dei Materiali Nanostrutturati, Rome; ItaliaFil: La Parola, Valeria. Istituto Per Lo Studio Dei Materiali Nanostrutturati, Rome; ItaliaElsevier2022-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/203810Bortot Coelho, Fabricio E.; Nurisso, Federica; Boffa, Vittorio; Ma, Xianzheng; Rasse Suriani, Federico Ariel Osvaldo; et al.; A thermocatalytic perovskite-graphene oxide nanofiltration membrane for water depollution; Elsevier; Journal of Water Process Engineering; 49; 102941; 10-2022; 1-112214-7144CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jwpe.2022.102941info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2214714422003853info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:06:01Zoai:ri.conicet.gov.ar:11336/203810instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:06:02.067CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A thermocatalytic perovskite-graphene oxide nanofiltration membrane for water depollution
title A thermocatalytic perovskite-graphene oxide nanofiltration membrane for water depollution
spellingShingle A thermocatalytic perovskite-graphene oxide nanofiltration membrane for water depollution
Bortot Coelho, Fabricio E.
CONTAMINANTS OF EMERGING CONCERN
NANOCOMPOSITE
STRONTIUM FERRATE
TOXICOLOGICAL TESTS
WASTEWATER
title_short A thermocatalytic perovskite-graphene oxide nanofiltration membrane for water depollution
title_full A thermocatalytic perovskite-graphene oxide nanofiltration membrane for water depollution
title_fullStr A thermocatalytic perovskite-graphene oxide nanofiltration membrane for water depollution
title_full_unstemmed A thermocatalytic perovskite-graphene oxide nanofiltration membrane for water depollution
title_sort A thermocatalytic perovskite-graphene oxide nanofiltration membrane for water depollution
dc.creator.none.fl_str_mv Bortot Coelho, Fabricio E.
Nurisso, Federica
Boffa, Vittorio
Ma, Xianzheng
Rasse Suriani, Federico Ariel Osvaldo
Roslev, Peter
Magnacca, Giuliana
Candelario, Victor
Deganello, Francesca
La Parola, Valeria
author Bortot Coelho, Fabricio E.
author_facet Bortot Coelho, Fabricio E.
Nurisso, Federica
Boffa, Vittorio
Ma, Xianzheng
Rasse Suriani, Federico Ariel Osvaldo
Roslev, Peter
Magnacca, Giuliana
Candelario, Victor
Deganello, Francesca
La Parola, Valeria
author_role author
author2 Nurisso, Federica
Boffa, Vittorio
Ma, Xianzheng
Rasse Suriani, Federico Ariel Osvaldo
Roslev, Peter
Magnacca, Giuliana
Candelario, Victor
Deganello, Francesca
La Parola, Valeria
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv CONTAMINANTS OF EMERGING CONCERN
NANOCOMPOSITE
STRONTIUM FERRATE
TOXICOLOGICAL TESTS
WASTEWATER
topic CONTAMINANTS OF EMERGING CONCERN
NANOCOMPOSITE
STRONTIUM FERRATE
TOXICOLOGICAL TESTS
WASTEWATER
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A novel nanofiltration membrane, whose active layer consists of 98.6 wt% of a thermocatalytic perovskite with composition Sr0.85Ce0.15FeO3-δ (CSF), 1.0 wt% of graphene oxide (GO), and 0.4 wt% of a humic acid-like (HAL) crosslinker, was deposited over a commercial flat-sheet polyethersulfone support with good reproducibility by a simple 1-step coating procedure. The synergistic coupling of CSF and the crosslinked GO resulted in an improved catalytic activity for bisphenol A (BPA) abatement as a model pollutant. The thermocatalytic CSF/GO/HAL (GOT) membrane was tested in a nanofiltration crossflow apparatus with a model BPA solution and with a real urban wastewater treatment plant effluent. Its performances were compared with those of a HAL crosslinked GO (GOHAL) reference membrane. The GOT membrane presented high rejection towards BPA, antifouling properties, and stability under the filtration conditions. Moreover, when compared to the GOHAL reference, the thermocatalytic GOT membrane was able to reduce the concentration of BPA and the total organic carbon in the feed during filtration. Hence, the GOT membrane appears to have high potential in water treatment due to its multifunctional characteristics, which include molecular sieving, thermocatalytic oxidation of organic pollutants, and self-cleaning properties. Additionally, the membrane material showed no significant toxicity to the aquatic model organisms Raphidocelis subcapitata, Aliivibrio fischeri, and Daphnia magna at concentrations below 50 ppm.
Fil: Bortot Coelho, Fabricio E.. Università di Torino; Italia. Liqtech International A/s; Dinamarca
Fil: Nurisso, Federica. Università di Torino; Italia. Aalborg University; Dinamarca
Fil: Boffa, Vittorio. Aalborg University; Dinamarca
Fil: Ma, Xianzheng. Aalborg University; Dinamarca
Fil: Rasse Suriani, Federico Ariel Osvaldo. Aalborg University; Dinamarca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Roslev, Peter. Aalborg University; Dinamarca
Fil: Magnacca, Giuliana. Università di Torino; Italia
Fil: Candelario, Victor. Liqtech International A/s; Dinamarca
Fil: Deganello, Francesca. Istituto Per Lo Studio Dei Materiali Nanostrutturati, Rome; Italia
Fil: La Parola, Valeria. Istituto Per Lo Studio Dei Materiali Nanostrutturati, Rome; Italia
description A novel nanofiltration membrane, whose active layer consists of 98.6 wt% of a thermocatalytic perovskite with composition Sr0.85Ce0.15FeO3-δ (CSF), 1.0 wt% of graphene oxide (GO), and 0.4 wt% of a humic acid-like (HAL) crosslinker, was deposited over a commercial flat-sheet polyethersulfone support with good reproducibility by a simple 1-step coating procedure. The synergistic coupling of CSF and the crosslinked GO resulted in an improved catalytic activity for bisphenol A (BPA) abatement as a model pollutant. The thermocatalytic CSF/GO/HAL (GOT) membrane was tested in a nanofiltration crossflow apparatus with a model BPA solution and with a real urban wastewater treatment plant effluent. Its performances were compared with those of a HAL crosslinked GO (GOHAL) reference membrane. The GOT membrane presented high rejection towards BPA, antifouling properties, and stability under the filtration conditions. Moreover, when compared to the GOHAL reference, the thermocatalytic GOT membrane was able to reduce the concentration of BPA and the total organic carbon in the feed during filtration. Hence, the GOT membrane appears to have high potential in water treatment due to its multifunctional characteristics, which include molecular sieving, thermocatalytic oxidation of organic pollutants, and self-cleaning properties. Additionally, the membrane material showed no significant toxicity to the aquatic model organisms Raphidocelis subcapitata, Aliivibrio fischeri, and Daphnia magna at concentrations below 50 ppm.
publishDate 2022
dc.date.none.fl_str_mv 2022-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/203810
Bortot Coelho, Fabricio E.; Nurisso, Federica; Boffa, Vittorio; Ma, Xianzheng; Rasse Suriani, Federico Ariel Osvaldo; et al.; A thermocatalytic perovskite-graphene oxide nanofiltration membrane for water depollution; Elsevier; Journal of Water Process Engineering; 49; 102941; 10-2022; 1-11
2214-7144
CONICET Digital
CONICET
url http://hdl.handle.net/11336/203810
identifier_str_mv Bortot Coelho, Fabricio E.; Nurisso, Federica; Boffa, Vittorio; Ma, Xianzheng; Rasse Suriani, Federico Ariel Osvaldo; et al.; A thermocatalytic perovskite-graphene oxide nanofiltration membrane for water depollution; Elsevier; Journal of Water Process Engineering; 49; 102941; 10-2022; 1-11
2214-7144
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jwpe.2022.102941
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2214714422003853
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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