Alternatives to free molecular halogens as chemoselective reactants: Catalysis of organic reactions with reusable complexes of halogen metal salts

Autores
Rossi, Laura Isabel; Velasco, Manuel Isaac
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Organometallic complexes of halogen metallic salts have been used as catalysts in different organic reactions, mainly the oxidation of organic compounds. Their use has not only allowed the reduction of the amounts of catalyst (since they can be reused) but also a lower generation of by-products and wastes. The different reaction media developed through the research were analyzed by several green parameters and the best results were obtained with complexes that have cyclodextrins as organic ligands. The proposed methodology is an alternative to use of molecular halogen as oxidant or catalyst when halogens are significant chemoselective reactants.
Fil: Rossi, Laura Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Velasco, Manuel Isaac. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Materia
CATALYST
CHEMOSELECTIVITY
CYCLODEXTRIN-IRON COMPLEXES
HALOGEN DERIVATIVES
SULFOXIDATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/81391
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Alternatives to free molecular halogens as chemoselective reactants: Catalysis of organic reactions with reusable complexes of halogen metal saltsRossi, Laura IsabelVelasco, Manuel IsaacCATALYSTCHEMOSELECTIVITYCYCLODEXTRIN-IRON COMPLEXESHALOGEN DERIVATIVESSULFOXIDATIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Organometallic complexes of halogen metallic salts have been used as catalysts in different organic reactions, mainly the oxidation of organic compounds. Their use has not only allowed the reduction of the amounts of catalyst (since they can be reused) but also a lower generation of by-products and wastes. The different reaction media developed through the research were analyzed by several green parameters and the best results were obtained with complexes that have cyclodextrins as organic ligands. The proposed methodology is an alternative to use of molecular halogen as oxidant or catalyst when halogens are significant chemoselective reactants.Fil: Rossi, Laura Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Velasco, Manuel Isaac. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaInt Union Pure Applied Chemistry2012-02-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/81391Rossi, Laura Isabel; Velasco, Manuel Isaac; Alternatives to free molecular halogens as chemoselective reactants: Catalysis of organic reactions with reusable complexes of halogen metal salts; Int Union Pure Applied Chemistry; Pure and Applied Chemistry; 84; 3; 6-2-2012; 819-8260033-45451365-3075CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1351/PAC-CON-11-07-13info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/pac.2012.84.issue-3/pac-con-11-07-13/pac-con-11-07-13.xmlinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:31:57Zoai:ri.conicet.gov.ar:11336/81391instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:31:57.607CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Alternatives to free molecular halogens as chemoselective reactants: Catalysis of organic reactions with reusable complexes of halogen metal salts
title Alternatives to free molecular halogens as chemoselective reactants: Catalysis of organic reactions with reusable complexes of halogen metal salts
spellingShingle Alternatives to free molecular halogens as chemoselective reactants: Catalysis of organic reactions with reusable complexes of halogen metal salts
Rossi, Laura Isabel
CATALYST
CHEMOSELECTIVITY
CYCLODEXTRIN-IRON COMPLEXES
HALOGEN DERIVATIVES
SULFOXIDATION
title_short Alternatives to free molecular halogens as chemoselective reactants: Catalysis of organic reactions with reusable complexes of halogen metal salts
title_full Alternatives to free molecular halogens as chemoselective reactants: Catalysis of organic reactions with reusable complexes of halogen metal salts
title_fullStr Alternatives to free molecular halogens as chemoselective reactants: Catalysis of organic reactions with reusable complexes of halogen metal salts
title_full_unstemmed Alternatives to free molecular halogens as chemoselective reactants: Catalysis of organic reactions with reusable complexes of halogen metal salts
title_sort Alternatives to free molecular halogens as chemoselective reactants: Catalysis of organic reactions with reusable complexes of halogen metal salts
dc.creator.none.fl_str_mv Rossi, Laura Isabel
Velasco, Manuel Isaac
author Rossi, Laura Isabel
author_facet Rossi, Laura Isabel
Velasco, Manuel Isaac
author_role author
author2 Velasco, Manuel Isaac
author2_role author
dc.subject.none.fl_str_mv CATALYST
CHEMOSELECTIVITY
CYCLODEXTRIN-IRON COMPLEXES
HALOGEN DERIVATIVES
SULFOXIDATION
topic CATALYST
CHEMOSELECTIVITY
CYCLODEXTRIN-IRON COMPLEXES
HALOGEN DERIVATIVES
SULFOXIDATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Organometallic complexes of halogen metallic salts have been used as catalysts in different organic reactions, mainly the oxidation of organic compounds. Their use has not only allowed the reduction of the amounts of catalyst (since they can be reused) but also a lower generation of by-products and wastes. The different reaction media developed through the research were analyzed by several green parameters and the best results were obtained with complexes that have cyclodextrins as organic ligands. The proposed methodology is an alternative to use of molecular halogen as oxidant or catalyst when halogens are significant chemoselective reactants.
Fil: Rossi, Laura Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Velasco, Manuel Isaac. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
description Organometallic complexes of halogen metallic salts have been used as catalysts in different organic reactions, mainly the oxidation of organic compounds. Their use has not only allowed the reduction of the amounts of catalyst (since they can be reused) but also a lower generation of by-products and wastes. The different reaction media developed through the research were analyzed by several green parameters and the best results were obtained with complexes that have cyclodextrins as organic ligands. The proposed methodology is an alternative to use of molecular halogen as oxidant or catalyst when halogens are significant chemoselective reactants.
publishDate 2012
dc.date.none.fl_str_mv 2012-02-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/81391
Rossi, Laura Isabel; Velasco, Manuel Isaac; Alternatives to free molecular halogens as chemoselective reactants: Catalysis of organic reactions with reusable complexes of halogen metal salts; Int Union Pure Applied Chemistry; Pure and Applied Chemistry; 84; 3; 6-2-2012; 819-826
0033-4545
1365-3075
CONICET Digital
CONICET
url http://hdl.handle.net/11336/81391
identifier_str_mv Rossi, Laura Isabel; Velasco, Manuel Isaac; Alternatives to free molecular halogens as chemoselective reactants: Catalysis of organic reactions with reusable complexes of halogen metal salts; Int Union Pure Applied Chemistry; Pure and Applied Chemistry; 84; 3; 6-2-2012; 819-826
0033-4545
1365-3075
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1351/PAC-CON-11-07-13
info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/pac.2012.84.issue-3/pac-con-11-07-13/pac-con-11-07-13.xml
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Int Union Pure Applied Chemistry
publisher.none.fl_str_mv Int Union Pure Applied Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.928904

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