Perfluoroalkylation Reactions by Electron Donor‐Acceptor Complexes: Recent Advances

Autores
Yerien, Damián Emilio; Barata Vallejo, Sebastian; Postigo, Jose Alberto
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This Perspective analyses the perfluoroalkylation reactions by electron donor-acceptor (EDA) complexes since 2018, while summarizes, in Tables 1-3, the vast majority of representative perfluoroalkylation reactions of various classes of organic compounds by EDA complexes and halogen-bonding interactions. Numerous intriguing reaction methodologies and valuable synthetic instances have emerged. We aim to delve into these new examples comprehensively, while also contemplating the future directions in the field. Subsequent sections will elaborate on the perfluoroalkylation of (hetero)aromatic compounds, carbon-carbon multiple bonds, perfluoroalkylation of carbonyl compounds, and perfluoroalkylation of isocyanides, covering their synthetic scope and mechanistic insights.
Fil: Yerien, Damián Emilio. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Fil: Postigo, Jose Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina
Materia
EDA COMPLEX
PERFLUOROALKYLATION
CATALYST-FREE
HALOGEN BONDING
Nivel de accesibilidad
acceso embargado
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/235595
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Perfluoroalkylation Reactions by Electron Donor‐Acceptor Complexes: Recent AdvancesYerien, Damián EmilioBarata Vallejo, SebastianPostigo, Jose AlbertoEDA COMPLEXPERFLUOROALKYLATIONCATALYST-FREEHALOGEN BONDINGhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This Perspective analyses the perfluoroalkylation reactions by electron donor-acceptor (EDA) complexes since 2018, while summarizes, in Tables 1-3, the vast majority of representative perfluoroalkylation reactions of various classes of organic compounds by EDA complexes and halogen-bonding interactions. Numerous intriguing reaction methodologies and valuable synthetic instances have emerged. We aim to delve into these new examples comprehensively, while also contemplating the future directions in the field. Subsequent sections will elaborate on the perfluoroalkylation of (hetero)aromatic compounds, carbon-carbon multiple bonds, perfluoroalkylation of carbonyl compounds, and perfluoroalkylation of isocyanides, covering their synthetic scope and mechanistic insights.Fil: Yerien, Damián Emilio. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; ArgentinaFil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; ArgentinaFil: Postigo, Jose Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; ArgentinaWiley2024-05info:eu-repo/date/embargoEnd/2024-11-17info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/235595Yerien, Damián Emilio; Barata Vallejo, Sebastian; Postigo, Jose Alberto; Perfluoroalkylation Reactions by Electron Donor‐Acceptor Complexes: Recent Advances; Wiley; ChemPhotoChem; 8; 25; 5-2024; 1-102367-0932CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cptc.202400112info:eu-repo/semantics/altIdentifier/doi/10.1002/cptc.202400112info:eu-repo/semantics/embargoedAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:27:28Zoai:ri.conicet.gov.ar:11336/235595instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:27:29.227CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Perfluoroalkylation Reactions by Electron Donor‐Acceptor Complexes: Recent Advances
title Perfluoroalkylation Reactions by Electron Donor‐Acceptor Complexes: Recent Advances
spellingShingle Perfluoroalkylation Reactions by Electron Donor‐Acceptor Complexes: Recent Advances
Yerien, Damián Emilio
EDA COMPLEX
PERFLUOROALKYLATION
CATALYST-FREE
HALOGEN BONDING
title_short Perfluoroalkylation Reactions by Electron Donor‐Acceptor Complexes: Recent Advances
title_full Perfluoroalkylation Reactions by Electron Donor‐Acceptor Complexes: Recent Advances
title_fullStr Perfluoroalkylation Reactions by Electron Donor‐Acceptor Complexes: Recent Advances
title_full_unstemmed Perfluoroalkylation Reactions by Electron Donor‐Acceptor Complexes: Recent Advances
title_sort Perfluoroalkylation Reactions by Electron Donor‐Acceptor Complexes: Recent Advances
dc.creator.none.fl_str_mv Yerien, Damián Emilio
Barata Vallejo, Sebastian
Postigo, Jose Alberto
author Yerien, Damián Emilio
author_facet Yerien, Damián Emilio
Barata Vallejo, Sebastian
Postigo, Jose Alberto
author_role author
author2 Barata Vallejo, Sebastian
Postigo, Jose Alberto
author2_role author
author
dc.subject.none.fl_str_mv EDA COMPLEX
PERFLUOROALKYLATION
CATALYST-FREE
HALOGEN BONDING
topic EDA COMPLEX
PERFLUOROALKYLATION
CATALYST-FREE
HALOGEN BONDING
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This Perspective analyses the perfluoroalkylation reactions by electron donor-acceptor (EDA) complexes since 2018, while summarizes, in Tables 1-3, the vast majority of representative perfluoroalkylation reactions of various classes of organic compounds by EDA complexes and halogen-bonding interactions. Numerous intriguing reaction methodologies and valuable synthetic instances have emerged. We aim to delve into these new examples comprehensively, while also contemplating the future directions in the field. Subsequent sections will elaborate on the perfluoroalkylation of (hetero)aromatic compounds, carbon-carbon multiple bonds, perfluoroalkylation of carbonyl compounds, and perfluoroalkylation of isocyanides, covering their synthetic scope and mechanistic insights.
Fil: Yerien, Damián Emilio. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Fil: Postigo, Jose Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica. Cátedra de Química Orgánica I; Argentina
description This Perspective analyses the perfluoroalkylation reactions by electron donor-acceptor (EDA) complexes since 2018, while summarizes, in Tables 1-3, the vast majority of representative perfluoroalkylation reactions of various classes of organic compounds by EDA complexes and halogen-bonding interactions. Numerous intriguing reaction methodologies and valuable synthetic instances have emerged. We aim to delve into these new examples comprehensively, while also contemplating the future directions in the field. Subsequent sections will elaborate on the perfluoroalkylation of (hetero)aromatic compounds, carbon-carbon multiple bonds, perfluoroalkylation of carbonyl compounds, and perfluoroalkylation of isocyanides, covering their synthetic scope and mechanistic insights.
publishDate 2024
dc.date.none.fl_str_mv 2024-05
info:eu-repo/date/embargoEnd/2024-11-17
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/235595
Yerien, Damián Emilio; Barata Vallejo, Sebastian; Postigo, Jose Alberto; Perfluoroalkylation Reactions by Electron Donor‐Acceptor Complexes: Recent Advances; Wiley; ChemPhotoChem; 8; 25; 5-2024; 1-10
2367-0932
CONICET Digital
CONICET
url http://hdl.handle.net/11336/235595
identifier_str_mv Yerien, Damián Emilio; Barata Vallejo, Sebastian; Postigo, Jose Alberto; Perfluoroalkylation Reactions by Electron Donor‐Acceptor Complexes: Recent Advances; Wiley; ChemPhotoChem; 8; 25; 5-2024; 1-10
2367-0932
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
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info:eu-repo/semantics/altIdentifier/doi/10.1002/cptc.202400112
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eu_rights_str_mv embargoedAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
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instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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