A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration
- Autores
- Di Nezio, Maria Susana; Palomeque, Miriam Edid; Fernández Band, Beatriz Susana
- Año de publicación
- 2004
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A new flow injection (FI) system for the determination of Pb(II) at trace level with a preconcentration step and spectrophotometric detection is proposed. It is based on preconcentration of lead ions on chitosan and dithizone-lead complex formation in aqueous medium (pH 9). The chemicals and FIA variables influencing the performance of the system were optimized and applied to the determination of lead in natural, well, and drinking water samples. It is a simple, highly sensitive, and low cost alternative methodology. The method provided a linear rage between 25 and 250 μg l-1, a detection limit of 5.0 ng ml-1 and a sample throughput of 15 h-1. The obtained results of spiked samples are in good agreement between the proposed method and ICP-AES.
Fil: Di Nezio, Maria Susana. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Palomeque, Miriam Edid. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Fernández Band, Beatriz Susana. Universidad Nacional del Sur. Departamento de Química; Argentina - Materia
-
FIA
LEAD
PRECONCENTRATION
SPECTROPHOTOMETRIC - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/96903
Ver los metadatos del registro completo
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A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentrationDi Nezio, Maria SusanaPalomeque, Miriam EdidFernández Band, Beatriz SusanaFIALEADPRECONCENTRATIONSPECTROPHOTOMETRIChttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A new flow injection (FI) system for the determination of Pb(II) at trace level with a preconcentration step and spectrophotometric detection is proposed. It is based on preconcentration of lead ions on chitosan and dithizone-lead complex formation in aqueous medium (pH 9). The chemicals and FIA variables influencing the performance of the system were optimized and applied to the determination of lead in natural, well, and drinking water samples. It is a simple, highly sensitive, and low cost alternative methodology. The method provided a linear rage between 25 and 250 μg l-1, a detection limit of 5.0 ng ml-1 and a sample throughput of 15 h-1. The obtained results of spiked samples are in good agreement between the proposed method and ICP-AES.Fil: Di Nezio, Maria Susana. Universidad Nacional del Sur. Departamento de Química; ArgentinaFil: Palomeque, Miriam Edid. Universidad Nacional del Sur. Departamento de Química; ArgentinaFil: Fernández Band, Beatriz Susana. Universidad Nacional del Sur. Departamento de Química; ArgentinaElsevier Science2004-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/96903Di Nezio, Maria Susana; Palomeque, Miriam Edid; Fernández Band, Beatriz Susana; A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration; Elsevier Science; Talanta; 63; 2; 12-2004; 405-4090039-9140CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2003.11.012info:eu-repo/semantics/altIdentifier/url/sciencedirect.com/science/article/pii/S0039914003006660info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:48:10Zoai:ri.conicet.gov.ar:11336/96903instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:48:10.669CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration |
title |
A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration |
spellingShingle |
A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration Di Nezio, Maria Susana FIA LEAD PRECONCENTRATION SPECTROPHOTOMETRIC |
title_short |
A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration |
title_full |
A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration |
title_fullStr |
A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration |
title_full_unstemmed |
A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration |
title_sort |
A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration |
dc.creator.none.fl_str_mv |
Di Nezio, Maria Susana Palomeque, Miriam Edid Fernández Band, Beatriz Susana |
author |
Di Nezio, Maria Susana |
author_facet |
Di Nezio, Maria Susana Palomeque, Miriam Edid Fernández Band, Beatriz Susana |
author_role |
author |
author2 |
Palomeque, Miriam Edid Fernández Band, Beatriz Susana |
author2_role |
author author |
dc.subject.none.fl_str_mv |
FIA LEAD PRECONCENTRATION SPECTROPHOTOMETRIC |
topic |
FIA LEAD PRECONCENTRATION SPECTROPHOTOMETRIC |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
A new flow injection (FI) system for the determination of Pb(II) at trace level with a preconcentration step and spectrophotometric detection is proposed. It is based on preconcentration of lead ions on chitosan and dithizone-lead complex formation in aqueous medium (pH 9). The chemicals and FIA variables influencing the performance of the system were optimized and applied to the determination of lead in natural, well, and drinking water samples. It is a simple, highly sensitive, and low cost alternative methodology. The method provided a linear rage between 25 and 250 μg l-1, a detection limit of 5.0 ng ml-1 and a sample throughput of 15 h-1. The obtained results of spiked samples are in good agreement between the proposed method and ICP-AES. Fil: Di Nezio, Maria Susana. Universidad Nacional del Sur. Departamento de Química; Argentina Fil: Palomeque, Miriam Edid. Universidad Nacional del Sur. Departamento de Química; Argentina Fil: Fernández Band, Beatriz Susana. Universidad Nacional del Sur. Departamento de Química; Argentina |
description |
A new flow injection (FI) system for the determination of Pb(II) at trace level with a preconcentration step and spectrophotometric detection is proposed. It is based on preconcentration of lead ions on chitosan and dithizone-lead complex formation in aqueous medium (pH 9). The chemicals and FIA variables influencing the performance of the system were optimized and applied to the determination of lead in natural, well, and drinking water samples. It is a simple, highly sensitive, and low cost alternative methodology. The method provided a linear rage between 25 and 250 μg l-1, a detection limit of 5.0 ng ml-1 and a sample throughput of 15 h-1. The obtained results of spiked samples are in good agreement between the proposed method and ICP-AES. |
publishDate |
2004 |
dc.date.none.fl_str_mv |
2004-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/96903 Di Nezio, Maria Susana; Palomeque, Miriam Edid; Fernández Band, Beatriz Susana; A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration; Elsevier Science; Talanta; 63; 2; 12-2004; 405-409 0039-9140 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/96903 |
identifier_str_mv |
Di Nezio, Maria Susana; Palomeque, Miriam Edid; Fernández Band, Beatriz Susana; A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration; Elsevier Science; Talanta; 63; 2; 12-2004; 405-409 0039-9140 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2003.11.012 info:eu-repo/semantics/altIdentifier/url/sciencedirect.com/science/article/pii/S0039914003006660 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842268907963940864 |
score |
13.13397 |