A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration

Autores
Di Nezio, Maria Susana; Palomeque, Miriam Edid; Fernández Band, Beatriz Susana
Año de publicación
2004
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A new flow injection (FI) system for the determination of Pb(II) at trace level with a preconcentration step and spectrophotometric detection is proposed. It is based on preconcentration of lead ions on chitosan and dithizone-lead complex formation in aqueous medium (pH 9). The chemicals and FIA variables influencing the performance of the system were optimized and applied to the determination of lead in natural, well, and drinking water samples. It is a simple, highly sensitive, and low cost alternative methodology. The method provided a linear rage between 25 and 250 μg l-1, a detection limit of 5.0 ng ml-1 and a sample throughput of 15 h-1. The obtained results of spiked samples are in good agreement between the proposed method and ICP-AES.
Fil: Di Nezio, Maria Susana. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Palomeque, Miriam Edid. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Fernández Band, Beatriz Susana. Universidad Nacional del Sur. Departamento de Química; Argentina
Materia
FIA
LEAD
PRECONCENTRATION
SPECTROPHOTOMETRIC
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/96903
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/96903
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentrationDi Nezio, Maria SusanaPalomeque, Miriam EdidFernández Band, Beatriz SusanaFIALEADPRECONCENTRATIONSPECTROPHOTOMETRIChttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A new flow injection (FI) system for the determination of Pb(II) at trace level with a preconcentration step and spectrophotometric detection is proposed. It is based on preconcentration of lead ions on chitosan and dithizone-lead complex formation in aqueous medium (pH 9). The chemicals and FIA variables influencing the performance of the system were optimized and applied to the determination of lead in natural, well, and drinking water samples. It is a simple, highly sensitive, and low cost alternative methodology. The method provided a linear rage between 25 and 250 μg l-1, a detection limit of 5.0 ng ml-1 and a sample throughput of 15 h-1. The obtained results of spiked samples are in good agreement between the proposed method and ICP-AES.Fil: Di Nezio, Maria Susana. Universidad Nacional del Sur. Departamento de Química; ArgentinaFil: Palomeque, Miriam Edid. Universidad Nacional del Sur. Departamento de Química; ArgentinaFil: Fernández Band, Beatriz Susana. Universidad Nacional del Sur. Departamento de Química; ArgentinaElsevier Science2004-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/96903Di Nezio, Maria Susana; Palomeque, Miriam Edid; Fernández Band, Beatriz Susana; A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration; Elsevier Science; Talanta; 63; 2; 12-2004; 405-4090039-9140CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2003.11.012info:eu-repo/semantics/altIdentifier/url/sciencedirect.com/science/article/pii/S0039914003006660info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:41:04Zoai:ri.conicet.gov.ar:11336/96903instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:41:04.37CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration
title A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration
spellingShingle A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration
Di Nezio, Maria Susana
FIA
LEAD
PRECONCENTRATION
SPECTROPHOTOMETRIC
title_short A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration
title_full A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration
title_fullStr A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration
title_full_unstemmed A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration
title_sort A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration
dc.creator.none.fl_str_mv Di Nezio, Maria Susana
Palomeque, Miriam Edid
Fernández Band, Beatriz Susana
author Di Nezio, Maria Susana
author_facet Di Nezio, Maria Susana
Palomeque, Miriam Edid
Fernández Band, Beatriz Susana
author_role author
author2 Palomeque, Miriam Edid
Fernández Band, Beatriz Susana
author2_role author
author
dc.subject.none.fl_str_mv FIA
LEAD
PRECONCENTRATION
SPECTROPHOTOMETRIC
topic FIA
LEAD
PRECONCENTRATION
SPECTROPHOTOMETRIC
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A new flow injection (FI) system for the determination of Pb(II) at trace level with a preconcentration step and spectrophotometric detection is proposed. It is based on preconcentration of lead ions on chitosan and dithizone-lead complex formation in aqueous medium (pH 9). The chemicals and FIA variables influencing the performance of the system were optimized and applied to the determination of lead in natural, well, and drinking water samples. It is a simple, highly sensitive, and low cost alternative methodology. The method provided a linear rage between 25 and 250 μg l-1, a detection limit of 5.0 ng ml-1 and a sample throughput of 15 h-1. The obtained results of spiked samples are in good agreement between the proposed method and ICP-AES.
Fil: Di Nezio, Maria Susana. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Palomeque, Miriam Edid. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Fernández Band, Beatriz Susana. Universidad Nacional del Sur. Departamento de Química; Argentina
description A new flow injection (FI) system for the determination of Pb(II) at trace level with a preconcentration step and spectrophotometric detection is proposed. It is based on preconcentration of lead ions on chitosan and dithizone-lead complex formation in aqueous medium (pH 9). The chemicals and FIA variables influencing the performance of the system were optimized and applied to the determination of lead in natural, well, and drinking water samples. It is a simple, highly sensitive, and low cost alternative methodology. The method provided a linear rage between 25 and 250 μg l-1, a detection limit of 5.0 ng ml-1 and a sample throughput of 15 h-1. The obtained results of spiked samples are in good agreement between the proposed method and ICP-AES.
publishDate 2004
dc.date.none.fl_str_mv 2004-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/96903
Di Nezio, Maria Susana; Palomeque, Miriam Edid; Fernández Band, Beatriz Susana; A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration; Elsevier Science; Talanta; 63; 2; 12-2004; 405-409
0039-9140
CONICET Digital
CONICET
url http://hdl.handle.net/11336/96903
identifier_str_mv Di Nezio, Maria Susana; Palomeque, Miriam Edid; Fernández Band, Beatriz Susana; A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration; Elsevier Science; Talanta; 63; 2; 12-2004; 405-409
0039-9140
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2003.11.012
info:eu-repo/semantics/altIdentifier/url/sciencedirect.com/science/article/pii/S0039914003006660
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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