On-line preconcentration/determination of lead traces in bee honey by inductively coupled plasma optical emission spectrometry (ICP-OES) using a conical minicolumn packed with acti...

Autores
Cerutti, Estela Soledad; Orsi, Ricardo Fernández; Gásquez, José A.; Olsina, Roberto Antonio; Martinez, Luis Dante
Año de publicación
2003
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this study, the preconcentration of Pb2+ using a conical minicolumn packed with activated carbon (AC) was studied for preconcentration of Pb2+. The experiments showed that Pb2+ reacts with 8-hydroxyquinoline to form a complex at pH 10.0 and can be retained "on-line" on a conical minicolumn packed with activated carbon, then eluted with 20% (v/v) nitric acid. The conditions for the quantitative and reproducible preconcentration and subsequent ICP-OES determination with ultrasonic nebulization system (USN) were studied. A total enhancement factor (N) of 500 was obtained with respect to ICP-OES using pneumatic nebulization (10 for USN and 50 for enrichment factor) for a sample volume of 25 mL. The detection limit (DL) was 0.04 μg L-1. The relative standard deviation (RSD) were 3.0%. The optimized procedure was successfully applied to the determination of trace levels of Pb+2 in bee honey samples.
Fil: Cerutti, Estela Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Orsi, Ricardo Fernández. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química Analítica; Argentina
Fil: Gásquez, José A.. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química Analítica; Argentina
Fil: Olsina, Roberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Martinez, Luis Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Materia
ACTIVATED CARBON
BEE HONEY
LEAD DETERMINATION
ON-LINE PRECONCENTRATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/99337
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/99337
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling On-line preconcentration/determination of lead traces in bee honey by inductively coupled plasma optical emission spectrometry (ICP-OES) using a conical minicolumn packed with activated carbonCerutti, Estela SoledadOrsi, Ricardo FernándezGásquez, José A.Olsina, Roberto AntonioMartinez, Luis DanteACTIVATED CARBONBEE HONEYLEAD DETERMINATIONON-LINE PRECONCENTRATIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this study, the preconcentration of Pb2+ using a conical minicolumn packed with activated carbon (AC) was studied for preconcentration of Pb2+. The experiments showed that Pb2+ reacts with 8-hydroxyquinoline to form a complex at pH 10.0 and can be retained "on-line" on a conical minicolumn packed with activated carbon, then eluted with 20% (v/v) nitric acid. The conditions for the quantitative and reproducible preconcentration and subsequent ICP-OES determination with ultrasonic nebulization system (USN) were studied. A total enhancement factor (N) of 500 was obtained with respect to ICP-OES using pneumatic nebulization (10 for USN and 50 for enrichment factor) for a sample volume of 25 mL. The detection limit (DL) was 0.04 μg L-1. The relative standard deviation (RSD) were 3.0%. The optimized procedure was successfully applied to the determination of trace levels of Pb+2 in bee honey samples.Fil: Cerutti, Estela Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaFil: Orsi, Ricardo Fernández. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química Analítica; ArgentinaFil: Gásquez, José A.. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química Analítica; ArgentinaFil: Olsina, Roberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaFil: Martinez, Luis Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaTaylor & Francis2003-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/99337Cerutti, Estela Soledad; Orsi, Ricardo Fernández; Gásquez, José A.; Olsina, Roberto Antonio; Martinez, Luis Dante; On-line preconcentration/determination of lead traces in bee honey by inductively coupled plasma optical emission spectrometry (ICP-OES) using a conical minicolumn packed with activated carbon; Taylor & Francis; Journal Of Trace And Microprobe Techniques; 21; 3; 8-2003; 421-4320733-4680CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1081/TMA-120023059info:eu-repo/semantics/altIdentifier/doi/10.1081/TMA-120023059info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:27:12Zoai:ri.conicet.gov.ar:11336/99337instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:27:12.923CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv On-line preconcentration/determination of lead traces in bee honey by inductively coupled plasma optical emission spectrometry (ICP-OES) using a conical minicolumn packed with activated carbon
title On-line preconcentration/determination of lead traces in bee honey by inductively coupled plasma optical emission spectrometry (ICP-OES) using a conical minicolumn packed with activated carbon
spellingShingle On-line preconcentration/determination of lead traces in bee honey by inductively coupled plasma optical emission spectrometry (ICP-OES) using a conical minicolumn packed with activated carbon
Cerutti, Estela Soledad
ACTIVATED CARBON
BEE HONEY
LEAD DETERMINATION
ON-LINE PRECONCENTRATION
title_short On-line preconcentration/determination of lead traces in bee honey by inductively coupled plasma optical emission spectrometry (ICP-OES) using a conical minicolumn packed with activated carbon
title_full On-line preconcentration/determination of lead traces in bee honey by inductively coupled plasma optical emission spectrometry (ICP-OES) using a conical minicolumn packed with activated carbon
title_fullStr On-line preconcentration/determination of lead traces in bee honey by inductively coupled plasma optical emission spectrometry (ICP-OES) using a conical minicolumn packed with activated carbon
title_full_unstemmed On-line preconcentration/determination of lead traces in bee honey by inductively coupled plasma optical emission spectrometry (ICP-OES) using a conical minicolumn packed with activated carbon
title_sort On-line preconcentration/determination of lead traces in bee honey by inductively coupled plasma optical emission spectrometry (ICP-OES) using a conical minicolumn packed with activated carbon
dc.creator.none.fl_str_mv Cerutti, Estela Soledad
Orsi, Ricardo Fernández
Gásquez, José A.
Olsina, Roberto Antonio
Martinez, Luis Dante
author Cerutti, Estela Soledad
author_facet Cerutti, Estela Soledad
Orsi, Ricardo Fernández
Gásquez, José A.
Olsina, Roberto Antonio
Martinez, Luis Dante
author_role author
author2 Orsi, Ricardo Fernández
Gásquez, José A.
Olsina, Roberto Antonio
Martinez, Luis Dante
author2_role author
author
author
author
dc.subject.none.fl_str_mv ACTIVATED CARBON
BEE HONEY
LEAD DETERMINATION
ON-LINE PRECONCENTRATION
topic ACTIVATED CARBON
BEE HONEY
LEAD DETERMINATION
ON-LINE PRECONCENTRATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this study, the preconcentration of Pb2+ using a conical minicolumn packed with activated carbon (AC) was studied for preconcentration of Pb2+. The experiments showed that Pb2+ reacts with 8-hydroxyquinoline to form a complex at pH 10.0 and can be retained "on-line" on a conical minicolumn packed with activated carbon, then eluted with 20% (v/v) nitric acid. The conditions for the quantitative and reproducible preconcentration and subsequent ICP-OES determination with ultrasonic nebulization system (USN) were studied. A total enhancement factor (N) of 500 was obtained with respect to ICP-OES using pneumatic nebulization (10 for USN and 50 for enrichment factor) for a sample volume of 25 mL. The detection limit (DL) was 0.04 μg L-1. The relative standard deviation (RSD) were 3.0%. The optimized procedure was successfully applied to the determination of trace levels of Pb+2 in bee honey samples.
Fil: Cerutti, Estela Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Orsi, Ricardo Fernández. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química Analítica; Argentina
Fil: Gásquez, José A.. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química Analítica; Argentina
Fil: Olsina, Roberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Martinez, Luis Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
description In this study, the preconcentration of Pb2+ using a conical minicolumn packed with activated carbon (AC) was studied for preconcentration of Pb2+. The experiments showed that Pb2+ reacts with 8-hydroxyquinoline to form a complex at pH 10.0 and can be retained "on-line" on a conical minicolumn packed with activated carbon, then eluted with 20% (v/v) nitric acid. The conditions for the quantitative and reproducible preconcentration and subsequent ICP-OES determination with ultrasonic nebulization system (USN) were studied. A total enhancement factor (N) of 500 was obtained with respect to ICP-OES using pneumatic nebulization (10 for USN and 50 for enrichment factor) for a sample volume of 25 mL. The detection limit (DL) was 0.04 μg L-1. The relative standard deviation (RSD) were 3.0%. The optimized procedure was successfully applied to the determination of trace levels of Pb+2 in bee honey samples.
publishDate 2003
dc.date.none.fl_str_mv 2003-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/99337
Cerutti, Estela Soledad; Orsi, Ricardo Fernández; Gásquez, José A.; Olsina, Roberto Antonio; Martinez, Luis Dante; On-line preconcentration/determination of lead traces in bee honey by inductively coupled plasma optical emission spectrometry (ICP-OES) using a conical minicolumn packed with activated carbon; Taylor & Francis; Journal Of Trace And Microprobe Techniques; 21; 3; 8-2003; 421-432
0733-4680
CONICET Digital
CONICET
url http://hdl.handle.net/11336/99337
identifier_str_mv Cerutti, Estela Soledad; Orsi, Ricardo Fernández; Gásquez, José A.; Olsina, Roberto Antonio; Martinez, Luis Dante; On-line preconcentration/determination of lead traces in bee honey by inductively coupled plasma optical emission spectrometry (ICP-OES) using a conical minicolumn packed with activated carbon; Taylor & Francis; Journal Of Trace And Microprobe Techniques; 21; 3; 8-2003; 421-432
0733-4680
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1081/TMA-120023059
info:eu-repo/semantics/altIdentifier/doi/10.1081/TMA-120023059
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis
publisher.none.fl_str_mv Taylor & Francis
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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