Generalization of a classic thin double layer polarization theory of colloidal suspensions to electrolyte solutions with different ion valences

Autores
Grosse, Constantino
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The classic Dukhin-Shilov theory for the thin double layer polarization of colloidal suspensions in binary electrolyte solutions was developed for symmetric electrolytes: equal counterion and co-ion valences. A rigorous generalization of this theory to asymmetric electrolytes, such that the valence of counterions is double or half the valence of co-ions, is presented. This generalization is possible because analytical solutions of the intervening integrals exist for these two particular cases but do not exist in the general case of different counterion and co-ion valences, a result apparently overlooked or ignored in the past.
Fil: Grosse, Constantino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina
Materia
Colloids
Counterions
Static Polarization
Theory
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/77883
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/77883
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network_name_str CONICET Digital (CONICET)
spelling Generalization of a classic thin double layer polarization theory of colloidal suspensions to electrolyte solutions with different ion valencesGrosse, ConstantinoColloidsCounterionsStatic PolarizationTheoryhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The classic Dukhin-Shilov theory for the thin double layer polarization of colloidal suspensions in binary electrolyte solutions was developed for symmetric electrolytes: equal counterion and co-ion valences. A rigorous generalization of this theory to asymmetric electrolytes, such that the valence of counterions is double or half the valence of co-ions, is presented. This generalization is possible because analytical solutions of the intervening integrals exist for these two particular cases but do not exist in the general case of different counterion and co-ion valences, a result apparently overlooked or ignored in the past.Fil: Grosse, Constantino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; ArgentinaAmerican Chemical Society2009-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/77883Grosse, Constantino; Generalization of a classic thin double layer polarization theory of colloidal suspensions to electrolyte solutions with different ion valences; American Chemical Society; Journal of Physical Chemistry B; 113; 26; 7-2009; 8911-89241520-6106CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/jp8112057info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jp8112057info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:33:00Zoai:ri.conicet.gov.ar:11336/77883instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:33:00.977CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Generalization of a classic thin double layer polarization theory of colloidal suspensions to electrolyte solutions with different ion valences
title Generalization of a classic thin double layer polarization theory of colloidal suspensions to electrolyte solutions with different ion valences
spellingShingle Generalization of a classic thin double layer polarization theory of colloidal suspensions to electrolyte solutions with different ion valences
Grosse, Constantino
Colloids
Counterions
Static Polarization
Theory
title_short Generalization of a classic thin double layer polarization theory of colloidal suspensions to electrolyte solutions with different ion valences
title_full Generalization of a classic thin double layer polarization theory of colloidal suspensions to electrolyte solutions with different ion valences
title_fullStr Generalization of a classic thin double layer polarization theory of colloidal suspensions to electrolyte solutions with different ion valences
title_full_unstemmed Generalization of a classic thin double layer polarization theory of colloidal suspensions to electrolyte solutions with different ion valences
title_sort Generalization of a classic thin double layer polarization theory of colloidal suspensions to electrolyte solutions with different ion valences
dc.creator.none.fl_str_mv Grosse, Constantino
author Grosse, Constantino
author_facet Grosse, Constantino
author_role author
dc.subject.none.fl_str_mv Colloids
Counterions
Static Polarization
Theory
topic Colloids
Counterions
Static Polarization
Theory
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The classic Dukhin-Shilov theory for the thin double layer polarization of colloidal suspensions in binary electrolyte solutions was developed for symmetric electrolytes: equal counterion and co-ion valences. A rigorous generalization of this theory to asymmetric electrolytes, such that the valence of counterions is double or half the valence of co-ions, is presented. This generalization is possible because analytical solutions of the intervening integrals exist for these two particular cases but do not exist in the general case of different counterion and co-ion valences, a result apparently overlooked or ignored in the past.
Fil: Grosse, Constantino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán; Argentina
description The classic Dukhin-Shilov theory for the thin double layer polarization of colloidal suspensions in binary electrolyte solutions was developed for symmetric electrolytes: equal counterion and co-ion valences. A rigorous generalization of this theory to asymmetric electrolytes, such that the valence of counterions is double or half the valence of co-ions, is presented. This generalization is possible because analytical solutions of the intervening integrals exist for these two particular cases but do not exist in the general case of different counterion and co-ion valences, a result apparently overlooked or ignored in the past.
publishDate 2009
dc.date.none.fl_str_mv 2009-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/77883
Grosse, Constantino; Generalization of a classic thin double layer polarization theory of colloidal suspensions to electrolyte solutions with different ion valences; American Chemical Society; Journal of Physical Chemistry B; 113; 26; 7-2009; 8911-8924
1520-6106
CONICET Digital
CONICET
url http://hdl.handle.net/11336/77883
identifier_str_mv Grosse, Constantino; Generalization of a classic thin double layer polarization theory of colloidal suspensions to electrolyte solutions with different ion valences; American Chemical Society; Journal of Physical Chemistry B; 113; 26; 7-2009; 8911-8924
1520-6106
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/jp8112057
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jp8112057
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613011212337152
score 13.070432

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