Tetrahydroborates: Development and Potential as Hydrogen Storage Medium

Autores
Puszkiel, Julián Atilio; Garroni, Sebastiano; Milanese, Chiara; Gennari, Fabiana Cristina; Klassen, Thomas; Dornheim, Martin; Pistidda, Claudio
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The use of fossil fuels as an energy supply becomes increasingly problematic from the point of view of both environmental emissions and energy sustainability. As an alternative, hydrogen is widely regarded as a key element for a potential energy solution. However, different from fossil fuels such as oil, gas, and coal, the production of hydrogen requires energy. Alternative and intermittent renewable sources such as solar power, wind power, etc., present multiple advantages for the production of hydrogen. On one hand, the renewable sources contribute to a remarkable reduction of pollutants released to the air. On the other hand, they significantly enhance the sustainability of energy supply. In addition, the storage of energy in form of hydrogen has a huge potential to balance an effective and synergetic utilization of the renewable energy sources. In this regard, hydrogen storage technology presents a key roadblock towards the practical application of hydrogen as “energy carrier”. Among the methods available to store hydrogen, solid-state storage is the most attractive alternative both from the safety and the volumetric energy density points of view. Because of their appealing hydrogen content, complex hydrides and complex hydride-based systems have attracted considerable attention as potential energy vectors for mobile and stationary applications. In this review, the progresses made over the last century on the development in the synthesis and research on the decomposition reactions of homoleptic tetrahydroborates is summarized. Furthermore, theoretical and experimental investigations on the thermodynamic and kinetic tuning of tetrahydroborates for hydrogen storage purposes are herein reviewed.
Fil: Puszkiel, Julián Atilio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Institute of Materials Research; Alemania. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Garroni, Sebastiano. Universidad de Burgos; España
Fil: Milanese, Chiara. University of Pavia; Italia
Fil: Gennari, Fabiana Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Klassen, Thomas. Institute of Materials Research; Alemania. Helmut Schmidt University; Alemania
Fil: Dornheim, Martin. Institute of Materials Research; Alemania
Fil: Pistidda, Claudio. Institute of Materials Research; Alemania
Materia
TETRAHYDROBORATES
SYNTHESIS
DECOMPOSITION PATHWAY
SOLID STATE HYDROGE STORAGE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/34995
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Tetrahydroborates: Development and Potential as Hydrogen Storage MediumPuszkiel, Julián AtilioGarroni, SebastianoMilanese, ChiaraGennari, Fabiana CristinaKlassen, ThomasDornheim, MartinPistidda, ClaudioTETRAHYDROBORATESSYNTHESISDECOMPOSITION PATHWAYSOLID STATE HYDROGE STORAGEThe use of fossil fuels as an energy supply becomes increasingly problematic from the point of view of both environmental emissions and energy sustainability. As an alternative, hydrogen is widely regarded as a key element for a potential energy solution. However, different from fossil fuels such as oil, gas, and coal, the production of hydrogen requires energy. Alternative and intermittent renewable sources such as solar power, wind power, etc., present multiple advantages for the production of hydrogen. On one hand, the renewable sources contribute to a remarkable reduction of pollutants released to the air. On the other hand, they significantly enhance the sustainability of energy supply. In addition, the storage of energy in form of hydrogen has a huge potential to balance an effective and synergetic utilization of the renewable energy sources. In this regard, hydrogen storage technology presents a key roadblock towards the practical application of hydrogen as “energy carrier”. Among the methods available to store hydrogen, solid-state storage is the most attractive alternative both from the safety and the volumetric energy density points of view. Because of their appealing hydrogen content, complex hydrides and complex hydride-based systems have attracted considerable attention as potential energy vectors for mobile and stationary applications. In this review, the progresses made over the last century on the development in the synthesis and research on the decomposition reactions of homoleptic tetrahydroborates is summarized. Furthermore, theoretical and experimental investigations on the thermodynamic and kinetic tuning of tetrahydroborates for hydrogen storage purposes are herein reviewed.Fil: Puszkiel, Julián Atilio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Institute of Materials Research; Alemania. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; ArgentinaFil: Garroni, Sebastiano. Universidad de Burgos; EspañaFil: Milanese, Chiara. University of Pavia; ItaliaFil: Gennari, Fabiana Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; ArgentinaFil: Klassen, Thomas. Institute of Materials Research; Alemania. Helmut Schmidt University; AlemaniaFil: Dornheim, Martin. Institute of Materials Research; AlemaniaFil: Pistidda, Claudio. Institute of Materials Research; AlemaniaMultidisciplinary Digital Publishing Institute MDPI2017-10-31info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/34995Puszkiel, Julián Atilio; Garroni, Sebastiano; Milanese, Chiara; Gennari, Fabiana Cristina; Klassen, Thomas; et al.; Tetrahydroborates: Development and Potential as Hydrogen Storage Medium; Multidisciplinary Digital Publishing Institute MDPI; Inorganics; 5; 4; 31-10-2017; 1-232304-6740CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.mdpi.com/2304-6740/5/4/74info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.3390/inorganics5040074info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:42:33Zoai:ri.conicet.gov.ar:11336/34995instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:42:33.62CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Tetrahydroborates: Development and Potential as Hydrogen Storage Medium
title Tetrahydroborates: Development and Potential as Hydrogen Storage Medium
spellingShingle Tetrahydroborates: Development and Potential as Hydrogen Storage Medium
Puszkiel, Julián Atilio
TETRAHYDROBORATES
SYNTHESIS
DECOMPOSITION PATHWAY
SOLID STATE HYDROGE STORAGE
title_short Tetrahydroborates: Development and Potential as Hydrogen Storage Medium
title_full Tetrahydroborates: Development and Potential as Hydrogen Storage Medium
title_fullStr Tetrahydroborates: Development and Potential as Hydrogen Storage Medium
title_full_unstemmed Tetrahydroborates: Development and Potential as Hydrogen Storage Medium
title_sort Tetrahydroborates: Development and Potential as Hydrogen Storage Medium
dc.creator.none.fl_str_mv Puszkiel, Julián Atilio
Garroni, Sebastiano
Milanese, Chiara
Gennari, Fabiana Cristina
Klassen, Thomas
Dornheim, Martin
Pistidda, Claudio
author Puszkiel, Julián Atilio
author_facet Puszkiel, Julián Atilio
Garroni, Sebastiano
Milanese, Chiara
Gennari, Fabiana Cristina
Klassen, Thomas
Dornheim, Martin
Pistidda, Claudio
author_role author
author2 Garroni, Sebastiano
Milanese, Chiara
Gennari, Fabiana Cristina
Klassen, Thomas
Dornheim, Martin
Pistidda, Claudio
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv TETRAHYDROBORATES
SYNTHESIS
DECOMPOSITION PATHWAY
SOLID STATE HYDROGE STORAGE
topic TETRAHYDROBORATES
SYNTHESIS
DECOMPOSITION PATHWAY
SOLID STATE HYDROGE STORAGE
dc.description.none.fl_txt_mv The use of fossil fuels as an energy supply becomes increasingly problematic from the point of view of both environmental emissions and energy sustainability. As an alternative, hydrogen is widely regarded as a key element for a potential energy solution. However, different from fossil fuels such as oil, gas, and coal, the production of hydrogen requires energy. Alternative and intermittent renewable sources such as solar power, wind power, etc., present multiple advantages for the production of hydrogen. On one hand, the renewable sources contribute to a remarkable reduction of pollutants released to the air. On the other hand, they significantly enhance the sustainability of energy supply. In addition, the storage of energy in form of hydrogen has a huge potential to balance an effective and synergetic utilization of the renewable energy sources. In this regard, hydrogen storage technology presents a key roadblock towards the practical application of hydrogen as “energy carrier”. Among the methods available to store hydrogen, solid-state storage is the most attractive alternative both from the safety and the volumetric energy density points of view. Because of their appealing hydrogen content, complex hydrides and complex hydride-based systems have attracted considerable attention as potential energy vectors for mobile and stationary applications. In this review, the progresses made over the last century on the development in the synthesis and research on the decomposition reactions of homoleptic tetrahydroborates is summarized. Furthermore, theoretical and experimental investigations on the thermodynamic and kinetic tuning of tetrahydroborates for hydrogen storage purposes are herein reviewed.
Fil: Puszkiel, Julián Atilio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Institute of Materials Research; Alemania. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Garroni, Sebastiano. Universidad de Burgos; España
Fil: Milanese, Chiara. University of Pavia; Italia
Fil: Gennari, Fabiana Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Klassen, Thomas. Institute of Materials Research; Alemania. Helmut Schmidt University; Alemania
Fil: Dornheim, Martin. Institute of Materials Research; Alemania
Fil: Pistidda, Claudio. Institute of Materials Research; Alemania
description The use of fossil fuels as an energy supply becomes increasingly problematic from the point of view of both environmental emissions and energy sustainability. As an alternative, hydrogen is widely regarded as a key element for a potential energy solution. However, different from fossil fuels such as oil, gas, and coal, the production of hydrogen requires energy. Alternative and intermittent renewable sources such as solar power, wind power, etc., present multiple advantages for the production of hydrogen. On one hand, the renewable sources contribute to a remarkable reduction of pollutants released to the air. On the other hand, they significantly enhance the sustainability of energy supply. In addition, the storage of energy in form of hydrogen has a huge potential to balance an effective and synergetic utilization of the renewable energy sources. In this regard, hydrogen storage technology presents a key roadblock towards the practical application of hydrogen as “energy carrier”. Among the methods available to store hydrogen, solid-state storage is the most attractive alternative both from the safety and the volumetric energy density points of view. Because of their appealing hydrogen content, complex hydrides and complex hydride-based systems have attracted considerable attention as potential energy vectors for mobile and stationary applications. In this review, the progresses made over the last century on the development in the synthesis and research on the decomposition reactions of homoleptic tetrahydroborates is summarized. Furthermore, theoretical and experimental investigations on the thermodynamic and kinetic tuning of tetrahydroborates for hydrogen storage purposes are herein reviewed.
publishDate 2017
dc.date.none.fl_str_mv 2017-10-31
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/34995
Puszkiel, Julián Atilio; Garroni, Sebastiano; Milanese, Chiara; Gennari, Fabiana Cristina; Klassen, Thomas; et al.; Tetrahydroborates: Development and Potential as Hydrogen Storage Medium; Multidisciplinary Digital Publishing Institute MDPI; Inorganics; 5; 4; 31-10-2017; 1-23
2304-6740
CONICET Digital
CONICET
url http://hdl.handle.net/11336/34995
identifier_str_mv Puszkiel, Julián Atilio; Garroni, Sebastiano; Milanese, Chiara; Gennari, Fabiana Cristina; Klassen, Thomas; et al.; Tetrahydroborates: Development and Potential as Hydrogen Storage Medium; Multidisciplinary Digital Publishing Institute MDPI; Inorganics; 5; 4; 31-10-2017; 1-23
2304-6740
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.mdpi.com/2304-6740/5/4/74
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.3390/inorganics5040074
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute MDPI
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute MDPI
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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