Protonic Conduction in the BaNdInO 4 Structure Achieved by Acceptor Doping

Autores
Zhou, Yu; Shiraiwa, Masahiro; Nagao, Masanori; Fujii, Kotaro; Tanaka, Isao; Yashima, Masatomo; Baque, Laura Cecilia; Basbus, Juan Felipe; Mogni, Liliana Verónica; Skinner, Stephen J.
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The potential of calcium-doped layered perovskite compounds, BaNd1-xCaxInO4-x/2 (where x is the excess Ca content), as protonic conductors was experimentally investigated. The acceptor-doped ceramics exhibit improved total conductivities that were 1-2 orders of magnitude higher than those of the pristine material, BaNdInO4. The highest total conductivity of 2.6 × 10-3 S cm-1 was obtained in the BaNd0.8Ca0.2InO3.90 sample at a temperature of 750 °C in air. Electrochemical impedance spectroscopy measurements of the x = 0.1 and x = 0.2 substituted samples showed higher total conductivity under humid environments than those measured in a dry environment over a large temperature range (250-750 °C). At 500 °C, the total conductivity of the 20% substituted sample in humid air (∼3% H2O) was 1.3 × 10-4 S cm-1. The incorporation of water vapor decreased the activation energies of the bulk conductivity of the BaNd0.8Ca0.2InO3.90 sample from 0.755(2) to 0.678(2) eV in air. The saturated BaNd0.8Ca0.2InO3.90 sample contained 2.2 mol % protonic defects, which caused an expansion in the lattice according to the high-temperature X-ray diffraction data. Combining the studies of the impedance behavior with four-probe DC conductivity measurements obtained in humid air, which showed a decrease in the resistance of the x = 0.2 sample, we conclude that experimental evidence indicates that BaNd1-xCaxInO4-x/2 is a fast proton conductor.
Fil: Zhou, Yu. Imperial College London; Reino Unido
Fil: Shiraiwa, Masahiro. Tokyo Institute Of Technology; Japón
Fil: Nagao, Masanori. University Of Yamanashi; Japón
Fil: Fujii, Kotaro. Tokyo Institute Of Technology; Japón
Fil: Tanaka, Isao. University Of Yamanashi; Japón
Fil: Yashima, Masatomo. Tokyo Institute Of Technology; Japón
Fil: Baque, Laura Cecilia. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; Argentina
Fil: Basbus, Juan Felipe. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; Argentina
Fil: Mogni, Liliana Verónica. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; Argentina
Fil: Skinner, Stephen J.. Imperial College London; Reino Unido
Materia
PROTON CONDUCTOR
OXIDE
CONDUCTIVITY
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/181704
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Protonic Conduction in the BaNdInO 4 Structure Achieved by Acceptor DopingZhou, YuShiraiwa, MasahiroNagao, MasanoriFujii, KotaroTanaka, IsaoYashima, MasatomoBaque, Laura CeciliaBasbus, Juan FelipeMogni, Liliana VerónicaSkinner, Stephen J.PROTON CONDUCTOROXIDECONDUCTIVITYhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The potential of calcium-doped layered perovskite compounds, BaNd1-xCaxInO4-x/2 (where x is the excess Ca content), as protonic conductors was experimentally investigated. The acceptor-doped ceramics exhibit improved total conductivities that were 1-2 orders of magnitude higher than those of the pristine material, BaNdInO4. The highest total conductivity of 2.6 × 10-3 S cm-1 was obtained in the BaNd0.8Ca0.2InO3.90 sample at a temperature of 750 °C in air. Electrochemical impedance spectroscopy measurements of the x = 0.1 and x = 0.2 substituted samples showed higher total conductivity under humid environments than those measured in a dry environment over a large temperature range (250-750 °C). At 500 °C, the total conductivity of the 20% substituted sample in humid air (∼3% H2O) was 1.3 × 10-4 S cm-1. The incorporation of water vapor decreased the activation energies of the bulk conductivity of the BaNd0.8Ca0.2InO3.90 sample from 0.755(2) to 0.678(2) eV in air. The saturated BaNd0.8Ca0.2InO3.90 sample contained 2.2 mol % protonic defects, which caused an expansion in the lattice according to the high-temperature X-ray diffraction data. Combining the studies of the impedance behavior with four-probe DC conductivity measurements obtained in humid air, which showed a decrease in the resistance of the x = 0.2 sample, we conclude that experimental evidence indicates that BaNd1-xCaxInO4-x/2 is a fast proton conductor.Fil: Zhou, Yu. Imperial College London; Reino UnidoFil: Shiraiwa, Masahiro. Tokyo Institute Of Technology; JapónFil: Nagao, Masanori. University Of Yamanashi; JapónFil: Fujii, Kotaro. Tokyo Institute Of Technology; JapónFil: Tanaka, Isao. University Of Yamanashi; JapónFil: Yashima, Masatomo. Tokyo Institute Of Technology; JapónFil: Baque, Laura Cecilia. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; ArgentinaFil: Basbus, Juan Felipe. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; ArgentinaFil: Mogni, Liliana Verónica. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; ArgentinaFil: Skinner, Stephen J.. Imperial College London; Reino UnidoAmerican Chemical Society2021-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/181704Zhou, Yu; Shiraiwa, Masahiro; Nagao, Masanori; Fujii, Kotaro; Tanaka, Isao; et al.; Protonic Conduction in the BaNdInO 4 Structure Achieved by Acceptor Doping; American Chemical Society; Chemistry Of Materials; 33; 6; 3-2021; 2139-21460897-4756CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.chemmater.0c04828info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.chemmater.0c04828info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:40:14Zoai:ri.conicet.gov.ar:11336/181704instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:40:14.363CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Protonic Conduction in the BaNdInO 4 Structure Achieved by Acceptor Doping
title Protonic Conduction in the BaNdInO 4 Structure Achieved by Acceptor Doping
spellingShingle Protonic Conduction in the BaNdInO 4 Structure Achieved by Acceptor Doping
Zhou, Yu
PROTON CONDUCTOR
OXIDE
CONDUCTIVITY
title_short Protonic Conduction in the BaNdInO 4 Structure Achieved by Acceptor Doping
title_full Protonic Conduction in the BaNdInO 4 Structure Achieved by Acceptor Doping
title_fullStr Protonic Conduction in the BaNdInO 4 Structure Achieved by Acceptor Doping
title_full_unstemmed Protonic Conduction in the BaNdInO 4 Structure Achieved by Acceptor Doping
title_sort Protonic Conduction in the BaNdInO 4 Structure Achieved by Acceptor Doping
dc.creator.none.fl_str_mv Zhou, Yu
Shiraiwa, Masahiro
Nagao, Masanori
Fujii, Kotaro
Tanaka, Isao
Yashima, Masatomo
Baque, Laura Cecilia
Basbus, Juan Felipe
Mogni, Liliana Verónica
Skinner, Stephen J.
author Zhou, Yu
author_facet Zhou, Yu
Shiraiwa, Masahiro
Nagao, Masanori
Fujii, Kotaro
Tanaka, Isao
Yashima, Masatomo
Baque, Laura Cecilia
Basbus, Juan Felipe
Mogni, Liliana Verónica
Skinner, Stephen J.
author_role author
author2 Shiraiwa, Masahiro
Nagao, Masanori
Fujii, Kotaro
Tanaka, Isao
Yashima, Masatomo
Baque, Laura Cecilia
Basbus, Juan Felipe
Mogni, Liliana Verónica
Skinner, Stephen J.
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv PROTON CONDUCTOR
OXIDE
CONDUCTIVITY
topic PROTON CONDUCTOR
OXIDE
CONDUCTIVITY
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The potential of calcium-doped layered perovskite compounds, BaNd1-xCaxInO4-x/2 (where x is the excess Ca content), as protonic conductors was experimentally investigated. The acceptor-doped ceramics exhibit improved total conductivities that were 1-2 orders of magnitude higher than those of the pristine material, BaNdInO4. The highest total conductivity of 2.6 × 10-3 S cm-1 was obtained in the BaNd0.8Ca0.2InO3.90 sample at a temperature of 750 °C in air. Electrochemical impedance spectroscopy measurements of the x = 0.1 and x = 0.2 substituted samples showed higher total conductivity under humid environments than those measured in a dry environment over a large temperature range (250-750 °C). At 500 °C, the total conductivity of the 20% substituted sample in humid air (∼3% H2O) was 1.3 × 10-4 S cm-1. The incorporation of water vapor decreased the activation energies of the bulk conductivity of the BaNd0.8Ca0.2InO3.90 sample from 0.755(2) to 0.678(2) eV in air. The saturated BaNd0.8Ca0.2InO3.90 sample contained 2.2 mol % protonic defects, which caused an expansion in the lattice according to the high-temperature X-ray diffraction data. Combining the studies of the impedance behavior with four-probe DC conductivity measurements obtained in humid air, which showed a decrease in the resistance of the x = 0.2 sample, we conclude that experimental evidence indicates that BaNd1-xCaxInO4-x/2 is a fast proton conductor.
Fil: Zhou, Yu. Imperial College London; Reino Unido
Fil: Shiraiwa, Masahiro. Tokyo Institute Of Technology; Japón
Fil: Nagao, Masanori. University Of Yamanashi; Japón
Fil: Fujii, Kotaro. Tokyo Institute Of Technology; Japón
Fil: Tanaka, Isao. University Of Yamanashi; Japón
Fil: Yashima, Masatomo. Tokyo Institute Of Technology; Japón
Fil: Baque, Laura Cecilia. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; Argentina
Fil: Basbus, Juan Felipe. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; Argentina
Fil: Mogni, Liliana Verónica. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche | Comision Nacional de Energia Atomica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia. Unidad Ejecutora Instituto de Nanociencia y Nanotecnologia - Nodo Bariloche.; Argentina
Fil: Skinner, Stephen J.. Imperial College London; Reino Unido
description The potential of calcium-doped layered perovskite compounds, BaNd1-xCaxInO4-x/2 (where x is the excess Ca content), as protonic conductors was experimentally investigated. The acceptor-doped ceramics exhibit improved total conductivities that were 1-2 orders of magnitude higher than those of the pristine material, BaNdInO4. The highest total conductivity of 2.6 × 10-3 S cm-1 was obtained in the BaNd0.8Ca0.2InO3.90 sample at a temperature of 750 °C in air. Electrochemical impedance spectroscopy measurements of the x = 0.1 and x = 0.2 substituted samples showed higher total conductivity under humid environments than those measured in a dry environment over a large temperature range (250-750 °C). At 500 °C, the total conductivity of the 20% substituted sample in humid air (∼3% H2O) was 1.3 × 10-4 S cm-1. The incorporation of water vapor decreased the activation energies of the bulk conductivity of the BaNd0.8Ca0.2InO3.90 sample from 0.755(2) to 0.678(2) eV in air. The saturated BaNd0.8Ca0.2InO3.90 sample contained 2.2 mol % protonic defects, which caused an expansion in the lattice according to the high-temperature X-ray diffraction data. Combining the studies of the impedance behavior with four-probe DC conductivity measurements obtained in humid air, which showed a decrease in the resistance of the x = 0.2 sample, we conclude that experimental evidence indicates that BaNd1-xCaxInO4-x/2 is a fast proton conductor.
publishDate 2021
dc.date.none.fl_str_mv 2021-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/181704
Zhou, Yu; Shiraiwa, Masahiro; Nagao, Masanori; Fujii, Kotaro; Tanaka, Isao; et al.; Protonic Conduction in the BaNdInO 4 Structure Achieved by Acceptor Doping; American Chemical Society; Chemistry Of Materials; 33; 6; 3-2021; 2139-2146
0897-4756
CONICET Digital
CONICET
url http://hdl.handle.net/11336/181704
identifier_str_mv Zhou, Yu; Shiraiwa, Masahiro; Nagao, Masanori; Fujii, Kotaro; Tanaka, Isao; et al.; Protonic Conduction in the BaNdInO 4 Structure Achieved by Acceptor Doping; American Chemical Society; Chemistry Of Materials; 33; 6; 3-2021; 2139-2146
0897-4756
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.chemmater.0c04828
info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.chemmater.0c04828
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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