Increasing Conductivity in Proton Conductors BaCeO3-d doped with Pr

Autores
Basbus, Juan Felipe; Caneiro, Alberto; Mogni, Liliana Verónica
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work we explore the effect of partial substitution of Ce for
Pr ions in BaCe1-xPrxO3-δ (0 ≤ x ≤0.8) perovskites with the aim of increasing the oxygen vacancies concentration and H+ charge carriers. The oxides were obtained by Pechini combustion method and sintered at 1350°C. The Pr incorporation improves the capability of to obtain dense samples at this temperature. Crystal structure were studied by X-ray diffraction, while morphology by SEM. The conductivity was studied by Electrical Impedance Spectroscopy (EIS) under 20 % O2/Ar and 10 % H2/Ar, both with 2% humidity. We found that the Pr content diminished the lattice parameters, increase the sintering capacity and the conductivity under wet oxidant atmosphere, but it decreases the stability under reducing atmosphere
Fil: Basbus, Juan Felipe. Comisión Nacional de Energía Atómica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Caneiro, Alberto. Comisión Nacional de Energía Atómica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Mogni, Liliana Verónica. Comisión Nacional de Energía Atómica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Materia
Proton Conductor
Ceramic
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/17663
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Increasing Conductivity in Proton Conductors BaCeO3-d doped with PrBasbus, Juan FelipeCaneiro, AlbertoMogni, Liliana VerónicaProton ConductorCeramichttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2In this work we explore the effect of partial substitution of Ce for<br />Pr ions in BaCe1-xPrxO3-δ (0 ≤ x ≤0.8) perovskites with the aim of increasing the oxygen vacancies concentration and H+ charge carriers. The oxides were obtained by Pechini combustion method and sintered at 1350°C. The Pr incorporation improves the capability of to obtain dense samples at this temperature. Crystal structure were studied by X-ray diffraction, while morphology by SEM. The conductivity was studied by Electrical Impedance Spectroscopy (EIS) under 20 % O2/Ar and 10 % H2/Ar, both with 2% humidity. We found that the Pr content diminished the lattice parameters, increase the sintering capacity and the conductivity under wet oxidant atmosphere, but it decreases the stability under reducing atmosphereFil: Basbus, Juan Felipe. Comisión Nacional de Energía Atómica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Caneiro, Alberto. Comisión Nacional de Energía Atómica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Mogni, Liliana Verónica. Comisión Nacional de Energía Atómica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaElectrochemical Society2013-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/17663Basbus, Juan Felipe; Caneiro, Alberto; Mogni, Liliana Verónica; Increasing Conductivity in Proton Conductors BaCeO3-d doped with Pr; Electrochemical Society; ECS Transactions; 58; 2; 10-2013; 173-1811938-5862enginfo:eu-repo/semantics/altIdentifier/doi/10.1149/05802.0173ecstinfo:eu-repo/semantics/altIdentifier/url/http://ecst.ecsdl.org/content/58/2/173.abstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:21:12Zoai:ri.conicet.gov.ar:11336/17663instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:21:12.824CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Increasing Conductivity in Proton Conductors BaCeO3-d doped with Pr
title Increasing Conductivity in Proton Conductors BaCeO3-d doped with Pr
spellingShingle Increasing Conductivity in Proton Conductors BaCeO3-d doped with Pr
Basbus, Juan Felipe
Proton Conductor
Ceramic
title_short Increasing Conductivity in Proton Conductors BaCeO3-d doped with Pr
title_full Increasing Conductivity in Proton Conductors BaCeO3-d doped with Pr
title_fullStr Increasing Conductivity in Proton Conductors BaCeO3-d doped with Pr
title_full_unstemmed Increasing Conductivity in Proton Conductors BaCeO3-d doped with Pr
title_sort Increasing Conductivity in Proton Conductors BaCeO3-d doped with Pr
dc.creator.none.fl_str_mv Basbus, Juan Felipe
Caneiro, Alberto
Mogni, Liliana Verónica
author Basbus, Juan Felipe
author_facet Basbus, Juan Felipe
Caneiro, Alberto
Mogni, Liliana Verónica
author_role author
author2 Caneiro, Alberto
Mogni, Liliana Verónica
author2_role author
author
dc.subject.none.fl_str_mv Proton Conductor
Ceramic
topic Proton Conductor
Ceramic
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this work we explore the effect of partial substitution of Ce for<br />Pr ions in BaCe1-xPrxO3-δ (0 ≤ x ≤0.8) perovskites with the aim of increasing the oxygen vacancies concentration and H+ charge carriers. The oxides were obtained by Pechini combustion method and sintered at 1350°C. The Pr incorporation improves the capability of to obtain dense samples at this temperature. Crystal structure were studied by X-ray diffraction, while morphology by SEM. The conductivity was studied by Electrical Impedance Spectroscopy (EIS) under 20 % O2/Ar and 10 % H2/Ar, both with 2% humidity. We found that the Pr content diminished the lattice parameters, increase the sintering capacity and the conductivity under wet oxidant atmosphere, but it decreases the stability under reducing atmosphere
Fil: Basbus, Juan Felipe. Comisión Nacional de Energía Atómica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Caneiro, Alberto. Comisión Nacional de Energía Atómica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Mogni, Liliana Verónica. Comisión Nacional de Energía Atómica. Gerencia de Area de Aplicaciones de la Tecnología Nuclear. Gerencia de Investigación Aplicada; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
description In this work we explore the effect of partial substitution of Ce for<br />Pr ions in BaCe1-xPrxO3-δ (0 ≤ x ≤0.8) perovskites with the aim of increasing the oxygen vacancies concentration and H+ charge carriers. The oxides were obtained by Pechini combustion method and sintered at 1350°C. The Pr incorporation improves the capability of to obtain dense samples at this temperature. Crystal structure were studied by X-ray diffraction, while morphology by SEM. The conductivity was studied by Electrical Impedance Spectroscopy (EIS) under 20 % O2/Ar and 10 % H2/Ar, both with 2% humidity. We found that the Pr content diminished the lattice parameters, increase the sintering capacity and the conductivity under wet oxidant atmosphere, but it decreases the stability under reducing atmosphere
publishDate 2013
dc.date.none.fl_str_mv 2013-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/17663
Basbus, Juan Felipe; Caneiro, Alberto; Mogni, Liliana Verónica; Increasing Conductivity in Proton Conductors BaCeO3-d doped with Pr; Electrochemical Society; ECS Transactions; 58; 2; 10-2013; 173-181
1938-5862
url http://hdl.handle.net/11336/17663
identifier_str_mv Basbus, Juan Felipe; Caneiro, Alberto; Mogni, Liliana Verónica; Increasing Conductivity in Proton Conductors BaCeO3-d doped with Pr; Electrochemical Society; ECS Transactions; 58; 2; 10-2013; 173-181
1938-5862
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1149/05802.0173ecst
info:eu-repo/semantics/altIdentifier/url/http://ecst.ecsdl.org/content/58/2/173.abstract
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Electrochemical Society
publisher.none.fl_str_mv Electrochemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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