Effects of the electrode configuration, phase relationship and microstructure on the polarization resistance of La0.3Ba0.7CoO3−δ as cathode material for IT-SOFC

Autores
Martinez, Cristian Fabricio; Prado, Fernando Daniel; Florio, D. Z. de
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The polarization resistance of La0.3Ba0.7CoO3−δ (LBC7) as cathode material was studied by impedance spectroscopy measurements in the temperature range of 450 ≤ T ≤ 750 °C, in air, on samples prepared by the solid state reaction (SSR) method and a wet chemical (WC) route, using symmetrical cells with single-layer and graded composition electrodes. While the LBC7 sample prepared by the SSR method and cooled at a rate of 10 °C/min turned out to be single phase with cubic symmetry, the sample prepared by the WC route is a mixture of the cubic phase and the 2H hexagonal phase. The lowest polarization resistance at 600 °C, Rp ∼ 0.06 Ω cm2, was obtained for the graded composition electrodes. Our results suggest that the electrode configuration is a key factor in order to reduce the polarization resistance of the LBC7 electrode material.
Fil: Martinez, Cristian Fabricio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Prado, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina
Fil: Florio, D. Z. de. Universidade Federal do ABC; Brasil
Materia
Oxidos Conductores Mixtos
Perovskitas
Cátodos
Sofc
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/29821
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/29821
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effects of the electrode configuration, phase relationship and microstructure on the polarization resistance of La0.3Ba0.7CoO3−δ as cathode material for IT-SOFCMartinez, Cristian FabricioPrado, Fernando DanielFlorio, D. Z. deOxidos Conductores MixtosPerovskitasCátodosSofchttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The polarization resistance of La0.3Ba0.7CoO3−δ (LBC7) as cathode material was studied by impedance spectroscopy measurements in the temperature range of 450 ≤ T ≤ 750 °C, in air, on samples prepared by the solid state reaction (SSR) method and a wet chemical (WC) route, using symmetrical cells with single-layer and graded composition electrodes. While the LBC7 sample prepared by the SSR method and cooled at a rate of 10 °C/min turned out to be single phase with cubic symmetry, the sample prepared by the WC route is a mixture of the cubic phase and the 2H hexagonal phase. The lowest polarization resistance at 600 °C, Rp ∼ 0.06 Ω cm2, was obtained for the graded composition electrodes. Our results suggest that the electrode configuration is a key factor in order to reduce the polarization resistance of the LBC7 electrode material.Fil: Martinez, Cristian Fabricio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Prado, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; ArgentinaFil: Florio, D. Z. de. Universidade Federal do ABC; BrasilElsevier2014-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/29821Martinez, Cristian Fabricio; Prado, Fernando Daniel; Florio, D. Z. de; Effects of the electrode configuration, phase relationship and microstructure on the polarization resistance of La0.3Ba0.7CoO3−δ as cathode material for IT-SOFC; Elsevier; International Journal of Hydrogen Energy; 39; 16; 6-2014; 8738-87430360-3199CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2013.12.040info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0360319913029741info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:23:29Zoai:ri.conicet.gov.ar:11336/29821instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:23:29.581CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effects of the electrode configuration, phase relationship and microstructure on the polarization resistance of La0.3Ba0.7CoO3−δ as cathode material for IT-SOFC
title Effects of the electrode configuration, phase relationship and microstructure on the polarization resistance of La0.3Ba0.7CoO3−δ as cathode material for IT-SOFC
spellingShingle Effects of the electrode configuration, phase relationship and microstructure on the polarization resistance of La0.3Ba0.7CoO3−δ as cathode material for IT-SOFC
Martinez, Cristian Fabricio
Oxidos Conductores Mixtos
Perovskitas
Cátodos
Sofc
title_short Effects of the electrode configuration, phase relationship and microstructure on the polarization resistance of La0.3Ba0.7CoO3−δ as cathode material for IT-SOFC
title_full Effects of the electrode configuration, phase relationship and microstructure on the polarization resistance of La0.3Ba0.7CoO3−δ as cathode material for IT-SOFC
title_fullStr Effects of the electrode configuration, phase relationship and microstructure on the polarization resistance of La0.3Ba0.7CoO3−δ as cathode material for IT-SOFC
title_full_unstemmed Effects of the electrode configuration, phase relationship and microstructure on the polarization resistance of La0.3Ba0.7CoO3−δ as cathode material for IT-SOFC
title_sort Effects of the electrode configuration, phase relationship and microstructure on the polarization resistance of La0.3Ba0.7CoO3−δ as cathode material for IT-SOFC
dc.creator.none.fl_str_mv Martinez, Cristian Fabricio
Prado, Fernando Daniel
Florio, D. Z. de
author Martinez, Cristian Fabricio
author_facet Martinez, Cristian Fabricio
Prado, Fernando Daniel
Florio, D. Z. de
author_role author
author2 Prado, Fernando Daniel
Florio, D. Z. de
author2_role author
author
dc.subject.none.fl_str_mv Oxidos Conductores Mixtos
Perovskitas
Cátodos
Sofc
topic Oxidos Conductores Mixtos
Perovskitas
Cátodos
Sofc
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The polarization resistance of La0.3Ba0.7CoO3−δ (LBC7) as cathode material was studied by impedance spectroscopy measurements in the temperature range of 450 ≤ T ≤ 750 °C, in air, on samples prepared by the solid state reaction (SSR) method and a wet chemical (WC) route, using symmetrical cells with single-layer and graded composition electrodes. While the LBC7 sample prepared by the SSR method and cooled at a rate of 10 °C/min turned out to be single phase with cubic symmetry, the sample prepared by the WC route is a mixture of the cubic phase and the 2H hexagonal phase. The lowest polarization resistance at 600 °C, Rp ∼ 0.06 Ω cm2, was obtained for the graded composition electrodes. Our results suggest that the electrode configuration is a key factor in order to reduce the polarization resistance of the LBC7 electrode material.
Fil: Martinez, Cristian Fabricio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Prado, Fernando Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina
Fil: Florio, D. Z. de. Universidade Federal do ABC; Brasil
description The polarization resistance of La0.3Ba0.7CoO3−δ (LBC7) as cathode material was studied by impedance spectroscopy measurements in the temperature range of 450 ≤ T ≤ 750 °C, in air, on samples prepared by the solid state reaction (SSR) method and a wet chemical (WC) route, using symmetrical cells with single-layer and graded composition electrodes. While the LBC7 sample prepared by the SSR method and cooled at a rate of 10 °C/min turned out to be single phase with cubic symmetry, the sample prepared by the WC route is a mixture of the cubic phase and the 2H hexagonal phase. The lowest polarization resistance at 600 °C, Rp ∼ 0.06 Ω cm2, was obtained for the graded composition electrodes. Our results suggest that the electrode configuration is a key factor in order to reduce the polarization resistance of the LBC7 electrode material.
publishDate 2014
dc.date.none.fl_str_mv 2014-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/29821
Martinez, Cristian Fabricio; Prado, Fernando Daniel; Florio, D. Z. de; Effects of the electrode configuration, phase relationship and microstructure on the polarization resistance of La0.3Ba0.7CoO3−δ as cathode material for IT-SOFC; Elsevier; International Journal of Hydrogen Energy; 39; 16; 6-2014; 8738-8743
0360-3199
CONICET Digital
CONICET
url http://hdl.handle.net/11336/29821
identifier_str_mv Martinez, Cristian Fabricio; Prado, Fernando Daniel; Florio, D. Z. de; Effects of the electrode configuration, phase relationship and microstructure on the polarization resistance of La0.3Ba0.7CoO3−δ as cathode material for IT-SOFC; Elsevier; International Journal of Hydrogen Energy; 39; 16; 6-2014; 8738-8743
0360-3199
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2013.12.040
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0360319913029741
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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