Authentication and Discrimination of Whiskies of High Commercial Value by Pattern Recognition

Autores
Cantarelli, Miguel Angel; Azcarate, Silvana Mariela; Savio, Marianela; Marchevsky, Eduardo Jorge; Camiña, José Manuel
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
An analytical method for a rapid and non-destructive classification and authentication of whiskies of high commercial value based on trademark and years of aging is presented. Molecular absorption spectroscopy was performed with a minimum manipulation of the sample. Different conditions previous to the chemometric analysis, such as dilution and pH effect were studied. Fifteen commercial trademarks of whiskies with different years of aging were acquired from the local market. The pattern recognition was performed using principal component analysis (PCA), linear discriminant analysis (LDA) and partial least squares discriminant analysis (PLS-DA) to obtain models that allowed the classification and discrimination of whiskies based in trademarks and years of aging respectively. Results show that by LDA, a mean of 99.15% of samples were correctly classified according to trademark. On the other hand, by PLS-DA a 100% of correct classification and discrimination was achieved with several aging labels (6, 8, 12 and 15 years of aging).
Fil: Cantarelli, Miguel Angel. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Instituto de Ciencias de la Tierra y Ambientales de la Pampa; Argentina. Universidad Nacional de La Pampa. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Azcarate, Silvana Mariela. Consejo Nacional de Investigaciones Cienti­ficas y Tecnicas. Instituto de Ciencias de la Tierra y Ambientales de la Pampa; Argentina. Universidad Nacional de La Pampa. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Savio, Marianela. Consejo Nacional de Investigaciones Cienti­ficas y Tecnicas. Instituto de Ciencias de la Tierra y Ambientales de la Pampa; Argentina. Universidad Nacional de La Pampa. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Marchevsky, Eduardo Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Camiña, José Manuel. Consejo Nacional de Investigaciones Cienti­ficas y Tecnicas. Instituto de Ciencias de la Tierra y Ambientales de la Pampa; Argentina. Universidad Nacional de La Pampa. Facultad de Ciencias Exactas y Naturales; Argentina
Materia
Whiskies
Trademark
Years of Aging
Classification
Discrimination
Pattern Recongnition
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5785
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Authentication and Discrimination of Whiskies of High Commercial Value by Pattern RecognitionCantarelli, Miguel AngelAzcarate, Silvana MarielaSavio, MarianelaMarchevsky, Eduardo JorgeCamiña, José ManuelWhiskiesTrademarkYears of AgingClassificationDiscriminationPattern Recongnitionhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1An analytical method for a rapid and non-destructive classification and authentication of whiskies of high commercial value based on trademark and years of aging is presented. Molecular absorption spectroscopy was performed with a minimum manipulation of the sample. Different conditions previous to the chemometric analysis, such as dilution and pH effect were studied. Fifteen commercial trademarks of whiskies with different years of aging were acquired from the local market. The pattern recognition was performed using principal component analysis (PCA), linear discriminant analysis (LDA) and partial least squares discriminant analysis (PLS-DA) to obtain models that allowed the classification and discrimination of whiskies based in trademarks and years of aging respectively. Results show that by LDA, a mean of 99.15% of samples were correctly classified according to trademark. On the other hand, by PLS-DA a 100% of correct classification and discrimination was achieved with several aging labels (6, 8, 12 and 15 years of aging).Fil: Cantarelli, Miguel Angel. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Instituto de Ciencias de la Tierra y Ambientales de la Pampa; Argentina. Universidad Nacional de La Pampa. Facultad de Ciencias Exactas y Naturales; ArgentinaFil: Azcarate, Silvana Mariela. Consejo Nacional de Investigaciones Cienti­ficas y Tecnicas. Instituto de Ciencias de la Tierra y Ambientales de la Pampa; Argentina. Universidad Nacional de La Pampa. Facultad de Ciencias Exactas y Naturales; ArgentinaFil: Savio, Marianela. Consejo Nacional de Investigaciones Cienti­ficas y Tecnicas. Instituto de Ciencias de la Tierra y Ambientales de la Pampa; Argentina. Universidad Nacional de La Pampa. Facultad de Ciencias Exactas y Naturales; ArgentinaFil: Marchevsky, Eduardo Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Camiña, José Manuel. Consejo Nacional de Investigaciones Cienti­ficas y Tecnicas. Instituto de Ciencias de la Tierra y Ambientales de la Pampa; Argentina. Universidad Nacional de La Pampa. Facultad de Ciencias Exactas y Naturales; ArgentinaSpringer2014-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5785Cantarelli, Miguel Angel; Azcarate, Silvana Mariela; Savio, Marianela; Marchevsky, Eduardo Jorge; Camiña, José Manuel; Authentication and Discrimination of Whiskies of High Commercial Value by Pattern Recognition; Springer; Food Analytical Methods; 8; 3; 8-2014; 790-7981936-9751enginfo:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1007/s12161-014-9958-8info:eu-repo/semantics/altIdentifier/doi/10.1007/s12161-014-9958-8info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:08:48Zoai:ri.conicet.gov.ar:11336/5785instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:08:49.259CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Authentication and Discrimination of Whiskies of High Commercial Value by Pattern Recognition
title Authentication and Discrimination of Whiskies of High Commercial Value by Pattern Recognition
spellingShingle Authentication and Discrimination of Whiskies of High Commercial Value by Pattern Recognition
Cantarelli, Miguel Angel
Whiskies
Trademark
Years of Aging
Classification
Discrimination
Pattern Recongnition
title_short Authentication and Discrimination of Whiskies of High Commercial Value by Pattern Recognition
title_full Authentication and Discrimination of Whiskies of High Commercial Value by Pattern Recognition
title_fullStr Authentication and Discrimination of Whiskies of High Commercial Value by Pattern Recognition
title_full_unstemmed Authentication and Discrimination of Whiskies of High Commercial Value by Pattern Recognition
title_sort Authentication and Discrimination of Whiskies of High Commercial Value by Pattern Recognition
dc.creator.none.fl_str_mv Cantarelli, Miguel Angel
Azcarate, Silvana Mariela
Savio, Marianela
Marchevsky, Eduardo Jorge
Camiña, José Manuel
author Cantarelli, Miguel Angel
author_facet Cantarelli, Miguel Angel
Azcarate, Silvana Mariela
Savio, Marianela
Marchevsky, Eduardo Jorge
Camiña, José Manuel
author_role author
author2 Azcarate, Silvana Mariela
Savio, Marianela
Marchevsky, Eduardo Jorge
Camiña, José Manuel
author2_role author
author
author
author
dc.subject.none.fl_str_mv Whiskies
Trademark
Years of Aging
Classification
Discrimination
Pattern Recongnition
topic Whiskies
Trademark
Years of Aging
Classification
Discrimination
Pattern Recongnition
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv An analytical method for a rapid and non-destructive classification and authentication of whiskies of high commercial value based on trademark and years of aging is presented. Molecular absorption spectroscopy was performed with a minimum manipulation of the sample. Different conditions previous to the chemometric analysis, such as dilution and pH effect were studied. Fifteen commercial trademarks of whiskies with different years of aging were acquired from the local market. The pattern recognition was performed using principal component analysis (PCA), linear discriminant analysis (LDA) and partial least squares discriminant analysis (PLS-DA) to obtain models that allowed the classification and discrimination of whiskies based in trademarks and years of aging respectively. Results show that by LDA, a mean of 99.15% of samples were correctly classified according to trademark. On the other hand, by PLS-DA a 100% of correct classification and discrimination was achieved with several aging labels (6, 8, 12 and 15 years of aging).
Fil: Cantarelli, Miguel Angel. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Instituto de Ciencias de la Tierra y Ambientales de la Pampa; Argentina. Universidad Nacional de La Pampa. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Azcarate, Silvana Mariela. Consejo Nacional de Investigaciones Cienti­ficas y Tecnicas. Instituto de Ciencias de la Tierra y Ambientales de la Pampa; Argentina. Universidad Nacional de La Pampa. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Savio, Marianela. Consejo Nacional de Investigaciones Cienti­ficas y Tecnicas. Instituto de Ciencias de la Tierra y Ambientales de la Pampa; Argentina. Universidad Nacional de La Pampa. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Marchevsky, Eduardo Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Camiña, José Manuel. Consejo Nacional de Investigaciones Cienti­ficas y Tecnicas. Instituto de Ciencias de la Tierra y Ambientales de la Pampa; Argentina. Universidad Nacional de La Pampa. Facultad de Ciencias Exactas y Naturales; Argentina
description An analytical method for a rapid and non-destructive classification and authentication of whiskies of high commercial value based on trademark and years of aging is presented. Molecular absorption spectroscopy was performed with a minimum manipulation of the sample. Different conditions previous to the chemometric analysis, such as dilution and pH effect were studied. Fifteen commercial trademarks of whiskies with different years of aging were acquired from the local market. The pattern recognition was performed using principal component analysis (PCA), linear discriminant analysis (LDA) and partial least squares discriminant analysis (PLS-DA) to obtain models that allowed the classification and discrimination of whiskies based in trademarks and years of aging respectively. Results show that by LDA, a mean of 99.15% of samples were correctly classified according to trademark. On the other hand, by PLS-DA a 100% of correct classification and discrimination was achieved with several aging labels (6, 8, 12 and 15 years of aging).
publishDate 2014
dc.date.none.fl_str_mv 2014-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5785
Cantarelli, Miguel Angel; Azcarate, Silvana Mariela; Savio, Marianela; Marchevsky, Eduardo Jorge; Camiña, José Manuel; Authentication and Discrimination of Whiskies of High Commercial Value by Pattern Recognition; Springer; Food Analytical Methods; 8; 3; 8-2014; 790-798
1936-9751
url http://hdl.handle.net/11336/5785
identifier_str_mv Cantarelli, Miguel Angel; Azcarate, Silvana Mariela; Savio, Marianela; Marchevsky, Eduardo Jorge; Camiña, José Manuel; Authentication and Discrimination of Whiskies of High Commercial Value by Pattern Recognition; Springer; Food Analytical Methods; 8; 3; 8-2014; 790-798
1936-9751
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1007/s12161-014-9958-8
info:eu-repo/semantics/altIdentifier/doi/10.1007/s12161-014-9958-8
info:eu-repo/semantics/altIdentifier/doi/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
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dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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