Upgrading argan shell wastes in wood plastic composites with biobased polyethylene matrix and different compatibilizers

Autores
Jorda Reolid, Maria; Gomez Caturla, Jaume; Ivorra Martinez, Juan; Stefani, Pablo Marcelo; Rojas Lema, Sandra; Quiles Carrillo, Luis
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The present study reports on the development of wood plastic composites (WPC) based on micronized argan shell (MAS) as a filler and high-density polyethylene obtained from sugarcane (Bio-HDPE), following the principles proposed by the circular economy in which the aim is to achieve zero waste by the introduction of residues of argan as a filler. The blends were prepared by extrusion and injection molding processes. In order to improve compatibility between the argan particles and the green polyolefin, different compatibilizers and additional filler were used, namely polyethylene grafted maleic anhydride (PE-g-MA 3 wt.-%), maleinized linseed oil (MLO 7.5 phr), halloysite nanotubes (HNTs 7.5 phr), and a combination of MLO and HNTs (3.75 phr each). The mechanical, morphological, thermal, thermomechanical, colorimetric, and wettability properties of each blend were analyzed. The results show that MAS acts as a reinforcing filler, increasing the stiffness of the Bio-HDPE, and that HNTs further increases this reinforcing effect. MLO and PE-g-MA, altogether with HNTs, improve the compatibility between MAS and Bio-HDPE, particularly due to bonds formed between oxygen-based groups present in each compound. Thermal stability was also improved provided by the addition of MAS and HNTs. All in all, reddish-like brown wood plastic composites with improved stiffness, good thermal stability, enhanced compatibility, and good wettability properties were obtained.
Fil: Jorda Reolid, Maria. Asociación de Investigación de la Industria del Juguete; Argentina
Fil: Gomez Caturla, Jaume. Universidad Politécnica de Valencia; España
Fil: Ivorra Martinez, Juan. Universidad Politécnica de Valencia; España
Fil: Stefani, Pablo Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Rojas Lema, Sandra. Asociación de Investigación de la Industria del Juguete; Argentina
Fil: Quiles Carrillo, Luis. Asociación de Investigación de la Industria del Juguete; Argentina
Materia
ARGAN SHELL PARTICLES
COM-PATIBILIZATION
MECHANICAL PROPERTIES
POLYETHYLENE
WOOD PLASTIC COMPOSITE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/179360
Acceder
id CONICETDig_40cbea3b44b753d07c936f5ce8442a8b
oai_identifier_str oai:ri.conicet.gov.ar:11336/179360
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Upgrading argan shell wastes in wood plastic composites with biobased polyethylene matrix and different compatibilizersJorda Reolid, MariaGomez Caturla, JaumeIvorra Martinez, JuanStefani, Pablo MarceloRojas Lema, SandraQuiles Carrillo, LuisARGAN SHELL PARTICLESCOM-PATIBILIZATIONMECHANICAL PROPERTIESPOLYETHYLENEWOOD PLASTIC COMPOSITEhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The present study reports on the development of wood plastic composites (WPC) based on micronized argan shell (MAS) as a filler and high-density polyethylene obtained from sugarcane (Bio-HDPE), following the principles proposed by the circular economy in which the aim is to achieve zero waste by the introduction of residues of argan as a filler. The blends were prepared by extrusion and injection molding processes. In order to improve compatibility between the argan particles and the green polyolefin, different compatibilizers and additional filler were used, namely polyethylene grafted maleic anhydride (PE-g-MA 3 wt.-%), maleinized linseed oil (MLO 7.5 phr), halloysite nanotubes (HNTs 7.5 phr), and a combination of MLO and HNTs (3.75 phr each). The mechanical, morphological, thermal, thermomechanical, colorimetric, and wettability properties of each blend were analyzed. The results show that MAS acts as a reinforcing filler, increasing the stiffness of the Bio-HDPE, and that HNTs further increases this reinforcing effect. MLO and PE-g-MA, altogether with HNTs, improve the compatibility between MAS and Bio-HDPE, particularly due to bonds formed between oxygen-based groups present in each compound. Thermal stability was also improved provided by the addition of MAS and HNTs. All in all, reddish-like brown wood plastic composites with improved stiffness, good thermal stability, enhanced compatibility, and good wettability properties were obtained.Fil: Jorda Reolid, Maria. Asociación de Investigación de la Industria del Juguete; ArgentinaFil: Gomez Caturla, Jaume. Universidad Politécnica de Valencia; EspañaFil: Ivorra Martinez, Juan. Universidad Politécnica de Valencia; EspañaFil: Stefani, Pablo Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Rojas Lema, Sandra. Asociación de Investigación de la Industria del Juguete; ArgentinaFil: Quiles Carrillo, Luis. Asociación de Investigación de la Industria del Juguete; ArgentinaMultidisciplinary Digital Publishing Institute2021-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/179360Jorda Reolid, Maria; Gomez Caturla, Jaume; Ivorra Martinez, Juan; Stefani, Pablo Marcelo; Rojas Lema, Sandra; et al.; Upgrading argan shell wastes in wood plastic composites with biobased polyethylene matrix and different compatibilizers; Multidisciplinary Digital Publishing Institute; Polymers; 13; 6; 3-2021; 1-242073-4360CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.3390/polym13060922info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4360/13/6/922info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:59:16Zoai:ri.conicet.gov.ar:11336/179360instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:59:16.607CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Upgrading argan shell wastes in wood plastic composites with biobased polyethylene matrix and different compatibilizers
title Upgrading argan shell wastes in wood plastic composites with biobased polyethylene matrix and different compatibilizers
spellingShingle Upgrading argan shell wastes in wood plastic composites with biobased polyethylene matrix and different compatibilizers
Jorda Reolid, Maria
ARGAN SHELL PARTICLES
COM-PATIBILIZATION
MECHANICAL PROPERTIES
POLYETHYLENE
WOOD PLASTIC COMPOSITE
title_short Upgrading argan shell wastes in wood plastic composites with biobased polyethylene matrix and different compatibilizers
title_full Upgrading argan shell wastes in wood plastic composites with biobased polyethylene matrix and different compatibilizers
title_fullStr Upgrading argan shell wastes in wood plastic composites with biobased polyethylene matrix and different compatibilizers
title_full_unstemmed Upgrading argan shell wastes in wood plastic composites with biobased polyethylene matrix and different compatibilizers
title_sort Upgrading argan shell wastes in wood plastic composites with biobased polyethylene matrix and different compatibilizers
dc.creator.none.fl_str_mv Jorda Reolid, Maria
Gomez Caturla, Jaume
Ivorra Martinez, Juan
Stefani, Pablo Marcelo
Rojas Lema, Sandra
Quiles Carrillo, Luis
author Jorda Reolid, Maria
author_facet Jorda Reolid, Maria
Gomez Caturla, Jaume
Ivorra Martinez, Juan
Stefani, Pablo Marcelo
Rojas Lema, Sandra
Quiles Carrillo, Luis
author_role author
author2 Gomez Caturla, Jaume
Ivorra Martinez, Juan
Stefani, Pablo Marcelo
Rojas Lema, Sandra
Quiles Carrillo, Luis
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv ARGAN SHELL PARTICLES
COM-PATIBILIZATION
MECHANICAL PROPERTIES
POLYETHYLENE
WOOD PLASTIC COMPOSITE
topic ARGAN SHELL PARTICLES
COM-PATIBILIZATION
MECHANICAL PROPERTIES
POLYETHYLENE
WOOD PLASTIC COMPOSITE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The present study reports on the development of wood plastic composites (WPC) based on micronized argan shell (MAS) as a filler and high-density polyethylene obtained from sugarcane (Bio-HDPE), following the principles proposed by the circular economy in which the aim is to achieve zero waste by the introduction of residues of argan as a filler. The blends were prepared by extrusion and injection molding processes. In order to improve compatibility between the argan particles and the green polyolefin, different compatibilizers and additional filler were used, namely polyethylene grafted maleic anhydride (PE-g-MA 3 wt.-%), maleinized linseed oil (MLO 7.5 phr), halloysite nanotubes (HNTs 7.5 phr), and a combination of MLO and HNTs (3.75 phr each). The mechanical, morphological, thermal, thermomechanical, colorimetric, and wettability properties of each blend were analyzed. The results show that MAS acts as a reinforcing filler, increasing the stiffness of the Bio-HDPE, and that HNTs further increases this reinforcing effect. MLO and PE-g-MA, altogether with HNTs, improve the compatibility between MAS and Bio-HDPE, particularly due to bonds formed between oxygen-based groups present in each compound. Thermal stability was also improved provided by the addition of MAS and HNTs. All in all, reddish-like brown wood plastic composites with improved stiffness, good thermal stability, enhanced compatibility, and good wettability properties were obtained.
Fil: Jorda Reolid, Maria. Asociación de Investigación de la Industria del Juguete; Argentina
Fil: Gomez Caturla, Jaume. Universidad Politécnica de Valencia; España
Fil: Ivorra Martinez, Juan. Universidad Politécnica de Valencia; España
Fil: Stefani, Pablo Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Rojas Lema, Sandra. Asociación de Investigación de la Industria del Juguete; Argentina
Fil: Quiles Carrillo, Luis. Asociación de Investigación de la Industria del Juguete; Argentina
description The present study reports on the development of wood plastic composites (WPC) based on micronized argan shell (MAS) as a filler and high-density polyethylene obtained from sugarcane (Bio-HDPE), following the principles proposed by the circular economy in which the aim is to achieve zero waste by the introduction of residues of argan as a filler. The blends were prepared by extrusion and injection molding processes. In order to improve compatibility between the argan particles and the green polyolefin, different compatibilizers and additional filler were used, namely polyethylene grafted maleic anhydride (PE-g-MA 3 wt.-%), maleinized linseed oil (MLO 7.5 phr), halloysite nanotubes (HNTs 7.5 phr), and a combination of MLO and HNTs (3.75 phr each). The mechanical, morphological, thermal, thermomechanical, colorimetric, and wettability properties of each blend were analyzed. The results show that MAS acts as a reinforcing filler, increasing the stiffness of the Bio-HDPE, and that HNTs further increases this reinforcing effect. MLO and PE-g-MA, altogether with HNTs, improve the compatibility between MAS and Bio-HDPE, particularly due to bonds formed between oxygen-based groups present in each compound. Thermal stability was also improved provided by the addition of MAS and HNTs. All in all, reddish-like brown wood plastic composites with improved stiffness, good thermal stability, enhanced compatibility, and good wettability properties were obtained.
publishDate 2021
dc.date.none.fl_str_mv 2021-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/179360
Jorda Reolid, Maria; Gomez Caturla, Jaume; Ivorra Martinez, Juan; Stefani, Pablo Marcelo; Rojas Lema, Sandra; et al.; Upgrading argan shell wastes in wood plastic composites with biobased polyethylene matrix and different compatibilizers; Multidisciplinary Digital Publishing Institute; Polymers; 13; 6; 3-2021; 1-24
2073-4360
CONICET Digital
CONICET
url http://hdl.handle.net/11336/179360
identifier_str_mv Jorda Reolid, Maria; Gomez Caturla, Jaume; Ivorra Martinez, Juan; Stefani, Pablo Marcelo; Rojas Lema, Sandra; et al.; Upgrading argan shell wastes in wood plastic composites with biobased polyethylene matrix and different compatibilizers; Multidisciplinary Digital Publishing Institute; Polymers; 13; 6; 3-2021; 1-24
2073-4360
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.3390/polym13060922
info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4360/13/6/922
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083133964812288
score 13.22299

Publicaciones similares