Valorisation of argan seeds: Production of cathode material for high-performance lithium-sulphur batteries

Autores
Marri, Imane; Edfouf, Zineb; Caballero, Alvaro; Tesio, Alvaro Yamil
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Porous carbon is considered a key factor in mitigating the shuttle effect, which remains one of the biggest challenges to developing lithium-sulphur (Li-S) batteries. Reusing agricultural waste as a raw material is a sustainable and eco-friendly source for producing carbon. Here we propose fabricating carbonaceous material from argan shells by simple pyrolysis. The synthesis of argan shell carbon (ASC) involved a straightforward approach with non-activating pyrolysis. Carbonisation at three different temperatures was employed to obtain ASC. A high sulphur loading of 70 % was incorporated into the ASC using the melt diffusion method, resulting in the formation of three different sulphur‑carbon composites (ASC@S). All of the prepared materials were characterised and evaluated as cathodes for Li-S batteries. The electrochemical performance of composites was compared, and ASC-800@S was identified as the best-performing composite. Thanks to its excellent properties this material combines (surface area, pore volume, conductivity), it delivers a capacity of 674 mAh g−1 and 513 mAh g−1 after 500 cycles at C/10 and 1C rate, respectively. This work provides a simple, economical, and effective strategy for preparing advanced carbonaceous sulphur host materials and significant improvement of Li-S cell performance.
Fil: Marri, Imane. Universidad de Córdoba; España
Fil: Edfouf, Zineb. No especifíca;
Fil: Caballero, Alvaro. Universidad de Córdoba; España
Fil: Tesio, Alvaro Yamil. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro de Investigación y Desarrollo en Materiales Avanzados y Almacenamiento de Energía de Jujuy - Universidad Nacional de Jujuy. Centro de Investigación y Desarrollo en Materiales Avanzados y Almacenamiento de Energía de Jujuy - Gobierno de la Provincia de Jujuy. Centro de Investigación y Desarrollo en Materiales Avanzados y Almacenamiento de Energía de Jujuy; Argentina
Materia
ACTIVATED CARBON
ARGAN SHELL
BIOMASS
LITHIUM–SULPHUR BATTERIES
POROUS CARBON
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/233521
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Valorisation of argan seeds: Production of cathode material for high-performance lithium-sulphur batteriesMarri, ImaneEdfouf, ZinebCaballero, AlvaroTesio, Alvaro YamilACTIVATED CARBONARGAN SHELLBIOMASSLITHIUM–SULPHUR BATTERIESPOROUS CARBONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Porous carbon is considered a key factor in mitigating the shuttle effect, which remains one of the biggest challenges to developing lithium-sulphur (Li-S) batteries. Reusing agricultural waste as a raw material is a sustainable and eco-friendly source for producing carbon. Here we propose fabricating carbonaceous material from argan shells by simple pyrolysis. The synthesis of argan shell carbon (ASC) involved a straightforward approach with non-activating pyrolysis. Carbonisation at three different temperatures was employed to obtain ASC. A high sulphur loading of 70 % was incorporated into the ASC using the melt diffusion method, resulting in the formation of three different sulphur‑carbon composites (ASC@S). All of the prepared materials were characterised and evaluated as cathodes for Li-S batteries. The electrochemical performance of composites was compared, and ASC-800@S was identified as the best-performing composite. Thanks to its excellent properties this material combines (surface area, pore volume, conductivity), it delivers a capacity of 674 mAh g−1 and 513 mAh g−1 after 500 cycles at C/10 and 1C rate, respectively. This work provides a simple, economical, and effective strategy for preparing advanced carbonaceous sulphur host materials and significant improvement of Li-S cell performance.Fil: Marri, Imane. Universidad de Córdoba; EspañaFil: Edfouf, Zineb. No especifíca;Fil: Caballero, Alvaro. Universidad de Córdoba; EspañaFil: Tesio, Alvaro Yamil. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro de Investigación y Desarrollo en Materiales Avanzados y Almacenamiento de Energía de Jujuy - Universidad Nacional de Jujuy. Centro de Investigación y Desarrollo en Materiales Avanzados y Almacenamiento de Energía de Jujuy - Gobierno de la Provincia de Jujuy. Centro de Investigación y Desarrollo en Materiales Avanzados y Almacenamiento de Energía de Jujuy; ArgentinaElsevier2024-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/233521Marri, Imane; Edfouf, Zineb; Caballero, Alvaro; Tesio, Alvaro Yamil; Valorisation of argan seeds: Production of cathode material for high-performance lithium-sulphur batteries; Elsevier; Journal of Energy Storage; 82; 3-2024; 1-102352-152XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.est.2024.110518info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-29T12:29:14Zoai:ri.conicet.gov.ar:11336/233521instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-29 12:29:14.461CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Valorisation of argan seeds: Production of cathode material for high-performance lithium-sulphur batteries
title Valorisation of argan seeds: Production of cathode material for high-performance lithium-sulphur batteries
spellingShingle Valorisation of argan seeds: Production of cathode material for high-performance lithium-sulphur batteries
Marri, Imane
ACTIVATED CARBON
ARGAN SHELL
BIOMASS
LITHIUM–SULPHUR BATTERIES
POROUS CARBON
title_short Valorisation of argan seeds: Production of cathode material for high-performance lithium-sulphur batteries
title_full Valorisation of argan seeds: Production of cathode material for high-performance lithium-sulphur batteries
title_fullStr Valorisation of argan seeds: Production of cathode material for high-performance lithium-sulphur batteries
title_full_unstemmed Valorisation of argan seeds: Production of cathode material for high-performance lithium-sulphur batteries
title_sort Valorisation of argan seeds: Production of cathode material for high-performance lithium-sulphur batteries
dc.creator.none.fl_str_mv Marri, Imane
Edfouf, Zineb
Caballero, Alvaro
Tesio, Alvaro Yamil
author Marri, Imane
author_facet Marri, Imane
Edfouf, Zineb
Caballero, Alvaro
Tesio, Alvaro Yamil
author_role author
author2 Edfouf, Zineb
Caballero, Alvaro
Tesio, Alvaro Yamil
author2_role author
author
author
dc.subject.none.fl_str_mv ACTIVATED CARBON
ARGAN SHELL
BIOMASS
LITHIUM–SULPHUR BATTERIES
POROUS CARBON
topic ACTIVATED CARBON
ARGAN SHELL
BIOMASS
LITHIUM–SULPHUR BATTERIES
POROUS CARBON
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Porous carbon is considered a key factor in mitigating the shuttle effect, which remains one of the biggest challenges to developing lithium-sulphur (Li-S) batteries. Reusing agricultural waste as a raw material is a sustainable and eco-friendly source for producing carbon. Here we propose fabricating carbonaceous material from argan shells by simple pyrolysis. The synthesis of argan shell carbon (ASC) involved a straightforward approach with non-activating pyrolysis. Carbonisation at three different temperatures was employed to obtain ASC. A high sulphur loading of 70 % was incorporated into the ASC using the melt diffusion method, resulting in the formation of three different sulphur‑carbon composites (ASC@S). All of the prepared materials were characterised and evaluated as cathodes for Li-S batteries. The electrochemical performance of composites was compared, and ASC-800@S was identified as the best-performing composite. Thanks to its excellent properties this material combines (surface area, pore volume, conductivity), it delivers a capacity of 674 mAh g−1 and 513 mAh g−1 after 500 cycles at C/10 and 1C rate, respectively. This work provides a simple, economical, and effective strategy for preparing advanced carbonaceous sulphur host materials and significant improvement of Li-S cell performance.
Fil: Marri, Imane. Universidad de Córdoba; España
Fil: Edfouf, Zineb. No especifíca;
Fil: Caballero, Alvaro. Universidad de Córdoba; España
Fil: Tesio, Alvaro Yamil. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro de Investigación y Desarrollo en Materiales Avanzados y Almacenamiento de Energía de Jujuy - Universidad Nacional de Jujuy. Centro de Investigación y Desarrollo en Materiales Avanzados y Almacenamiento de Energía de Jujuy - Gobierno de la Provincia de Jujuy. Centro de Investigación y Desarrollo en Materiales Avanzados y Almacenamiento de Energía de Jujuy; Argentina
description Porous carbon is considered a key factor in mitigating the shuttle effect, which remains one of the biggest challenges to developing lithium-sulphur (Li-S) batteries. Reusing agricultural waste as a raw material is a sustainable and eco-friendly source for producing carbon. Here we propose fabricating carbonaceous material from argan shells by simple pyrolysis. The synthesis of argan shell carbon (ASC) involved a straightforward approach with non-activating pyrolysis. Carbonisation at three different temperatures was employed to obtain ASC. A high sulphur loading of 70 % was incorporated into the ASC using the melt diffusion method, resulting in the formation of three different sulphur‑carbon composites (ASC@S). All of the prepared materials were characterised and evaluated as cathodes for Li-S batteries. The electrochemical performance of composites was compared, and ASC-800@S was identified as the best-performing composite. Thanks to its excellent properties this material combines (surface area, pore volume, conductivity), it delivers a capacity of 674 mAh g−1 and 513 mAh g−1 after 500 cycles at C/10 and 1C rate, respectively. This work provides a simple, economical, and effective strategy for preparing advanced carbonaceous sulphur host materials and significant improvement of Li-S cell performance.
publishDate 2024
dc.date.none.fl_str_mv 2024-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/233521
Marri, Imane; Edfouf, Zineb; Caballero, Alvaro; Tesio, Alvaro Yamil; Valorisation of argan seeds: Production of cathode material for high-performance lithium-sulphur batteries; Elsevier; Journal of Energy Storage; 82; 3-2024; 1-10
2352-152X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/233521
identifier_str_mv Marri, Imane; Edfouf, Zineb; Caballero, Alvaro; Tesio, Alvaro Yamil; Valorisation of argan seeds: Production of cathode material for high-performance lithium-sulphur batteries; Elsevier; Journal of Energy Storage; 82; 3-2024; 1-10
2352-152X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.est.2024.110518
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.589754

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