Polyethylene-Based Nanocomposite Films: Structure/Properties Relationship

Autores
Martini, Raquel Evangelina; La Tegola, Simone; Terenzi, Andrea; Kenny, José M.; Barbosa, Silvia Elena
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Polyethylene (PE) is the most used thermoplastic commodity as a consequence of its convenient cost-processing-performance relationship and it can be used in the form of films for food, goods and farming packaging. On the other hand, sepiolite is a high surface area and porosity hydrated magnesium silicate with both remarkable adsorptive and absorptive properties. Thus, PE and sepiolite can combine their properties synergetically to obtain new materials with enhanced properties. In this work, a systematic study of final properties of PE-sepiolite nanocomposite films was performed to investigate the influence of the sepiolite content and modification on the PE properties. Nanocomposites films with 1, 3, 5 and 10 wt % of sepiolite, with and without surface modification, were prepared by cast film extrusion and tested. The filler dispersion and distribution were evaluated by Transmission Electron Microscopy (TEM) and Fourier Transform Infrared Spectroscopy (FTIR), whereas the film crystalline morphology was analyzed using Atomic Force Microscopy (AFM), Differential Scanning Calorimetry (DSC) and X-ray Diffraction (XRD). Final properties as mechanical ones, oxygen permeability and transparency were also studied and related with the film structure. Mechanical properties, crystallization and oxygen permeability were increased maintaining good film translucency.
Fil: Martini, Raquel Evangelina. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina
Fil: La Tegola, Simone. Universita Di Perugia; Italia
Fil: Terenzi, Andrea. Universita Di Perugia; Italia
Fil: Kenny, José M.. Universita Di Perugia; Italia
Fil: Barbosa, Silvia Elena. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina
Materia
Nanocomposite Films
Packaging
Polyethylene
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/11857
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Polyethylene-Based Nanocomposite Films: Structure/Properties RelationshipMartini, Raquel EvangelinaLa Tegola, SimoneTerenzi, AndreaKenny, José M.Barbosa, Silvia ElenaNanocomposite FilmsPackagingPolyethylenehttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Polyethylene (PE) is the most used thermoplastic commodity as a consequence of its convenient cost-processing-performance relationship and it can be used in the form of films for food, goods and farming packaging. On the other hand, sepiolite is a high surface area and porosity hydrated magnesium silicate with both remarkable adsorptive and absorptive properties. Thus, PE and sepiolite can combine their properties synergetically to obtain new materials with enhanced properties. In this work, a systematic study of final properties of PE-sepiolite nanocomposite films was performed to investigate the influence of the sepiolite content and modification on the PE properties. Nanocomposites films with 1, 3, 5 and 10 wt % of sepiolite, with and without surface modification, were prepared by cast film extrusion and tested. The filler dispersion and distribution were evaluated by Transmission Electron Microscopy (TEM) and Fourier Transform Infrared Spectroscopy (FTIR), whereas the film crystalline morphology was analyzed using Atomic Force Microscopy (AFM), Differential Scanning Calorimetry (DSC) and X-ray Diffraction (XRD). Final properties as mechanical ones, oxygen permeability and transparency were also studied and related with the film structure. Mechanical properties, crystallization and oxygen permeability were increased maintaining good film translucency.Fil: Martini, Raquel Evangelina. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; ArgentinaFil: La Tegola, Simone. Universita Di Perugia; ItaliaFil: Terenzi, Andrea. Universita Di Perugia; ItaliaFil: Kenny, José M.. Universita Di Perugia; ItaliaFil: Barbosa, Silvia Elena. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; ArgentinaWiley2013-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/11857Martini, Raquel Evangelina; La Tegola, Simone; Terenzi, Andrea; Kenny, José M.; Barbosa, Silvia Elena; Polyethylene-Based Nanocomposite Films: Structure/Properties Relationship; Wiley; Polymer Engineering And Science; 54; 8; 5-2013; 1931-19400032-3888enginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/pen.23743/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/pen.23743info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:09:45Zoai:ri.conicet.gov.ar:11336/11857instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:09:46.159CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Polyethylene-Based Nanocomposite Films: Structure/Properties Relationship
title Polyethylene-Based Nanocomposite Films: Structure/Properties Relationship
spellingShingle Polyethylene-Based Nanocomposite Films: Structure/Properties Relationship
Martini, Raquel Evangelina
Nanocomposite Films
Packaging
Polyethylene
title_short Polyethylene-Based Nanocomposite Films: Structure/Properties Relationship
title_full Polyethylene-Based Nanocomposite Films: Structure/Properties Relationship
title_fullStr Polyethylene-Based Nanocomposite Films: Structure/Properties Relationship
title_full_unstemmed Polyethylene-Based Nanocomposite Films: Structure/Properties Relationship
title_sort Polyethylene-Based Nanocomposite Films: Structure/Properties Relationship
dc.creator.none.fl_str_mv Martini, Raquel Evangelina
La Tegola, Simone
Terenzi, Andrea
Kenny, José M.
Barbosa, Silvia Elena
author Martini, Raquel Evangelina
author_facet Martini, Raquel Evangelina
La Tegola, Simone
Terenzi, Andrea
Kenny, José M.
Barbosa, Silvia Elena
author_role author
author2 La Tegola, Simone
Terenzi, Andrea
Kenny, José M.
Barbosa, Silvia Elena
author2_role author
author
author
author
dc.subject.none.fl_str_mv Nanocomposite Films
Packaging
Polyethylene
topic Nanocomposite Films
Packaging
Polyethylene
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Polyethylene (PE) is the most used thermoplastic commodity as a consequence of its convenient cost-processing-performance relationship and it can be used in the form of films for food, goods and farming packaging. On the other hand, sepiolite is a high surface area and porosity hydrated magnesium silicate with both remarkable adsorptive and absorptive properties. Thus, PE and sepiolite can combine their properties synergetically to obtain new materials with enhanced properties. In this work, a systematic study of final properties of PE-sepiolite nanocomposite films was performed to investigate the influence of the sepiolite content and modification on the PE properties. Nanocomposites films with 1, 3, 5 and 10 wt % of sepiolite, with and without surface modification, were prepared by cast film extrusion and tested. The filler dispersion and distribution were evaluated by Transmission Electron Microscopy (TEM) and Fourier Transform Infrared Spectroscopy (FTIR), whereas the film crystalline morphology was analyzed using Atomic Force Microscopy (AFM), Differential Scanning Calorimetry (DSC) and X-ray Diffraction (XRD). Final properties as mechanical ones, oxygen permeability and transparency were also studied and related with the film structure. Mechanical properties, crystallization and oxygen permeability were increased maintaining good film translucency.
Fil: Martini, Raquel Evangelina. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina
Fil: La Tegola, Simone. Universita Di Perugia; Italia
Fil: Terenzi, Andrea. Universita Di Perugia; Italia
Fil: Kenny, José M.. Universita Di Perugia; Italia
Fil: Barbosa, Silvia Elena. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina
description Polyethylene (PE) is the most used thermoplastic commodity as a consequence of its convenient cost-processing-performance relationship and it can be used in the form of films for food, goods and farming packaging. On the other hand, sepiolite is a high surface area and porosity hydrated magnesium silicate with both remarkable adsorptive and absorptive properties. Thus, PE and sepiolite can combine their properties synergetically to obtain new materials with enhanced properties. In this work, a systematic study of final properties of PE-sepiolite nanocomposite films was performed to investigate the influence of the sepiolite content and modification on the PE properties. Nanocomposites films with 1, 3, 5 and 10 wt % of sepiolite, with and without surface modification, were prepared by cast film extrusion and tested. The filler dispersion and distribution were evaluated by Transmission Electron Microscopy (TEM) and Fourier Transform Infrared Spectroscopy (FTIR), whereas the film crystalline morphology was analyzed using Atomic Force Microscopy (AFM), Differential Scanning Calorimetry (DSC) and X-ray Diffraction (XRD). Final properties as mechanical ones, oxygen permeability and transparency were also studied and related with the film structure. Mechanical properties, crystallization and oxygen permeability were increased maintaining good film translucency.
publishDate 2013
dc.date.none.fl_str_mv 2013-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/11857
Martini, Raquel Evangelina; La Tegola, Simone; Terenzi, Andrea; Kenny, José M.; Barbosa, Silvia Elena; Polyethylene-Based Nanocomposite Films: Structure/Properties Relationship; Wiley; Polymer Engineering And Science; 54; 8; 5-2013; 1931-1940
0032-3888
url http://hdl.handle.net/11336/11857
identifier_str_mv Martini, Raquel Evangelina; La Tegola, Simone; Terenzi, Andrea; Kenny, José M.; Barbosa, Silvia Elena; Polyethylene-Based Nanocomposite Films: Structure/Properties Relationship; Wiley; Polymer Engineering And Science; 54; 8; 5-2013; 1931-1940
0032-3888
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/pen.23743/abstract
info:eu-repo/semantics/altIdentifier/doi/10.1002/pen.23743
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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