Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato
- Autores
- Tognana, Sebastian Alberto; Silva, Leonel Ignacio; Salgueiro, Walter Alberto
- Año de publicación
- 2013
- Idioma
- español castellano
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In this work, epoxy/poly-3-hydroxybutyrate (PHB) blends in two different proportions, 90/10 and 85/15, were studied. For this purpose, the samples were submitted to 80ºC and 120ºC for the curing process of epoxy. The phase separation and the crystallization were analyzed using optical microscopy and differential scanning calorimetry. Likewise, the lamellar structure of PHB was characterized using small angle X-ray scattering. Significant differences between the two proportions studied were found; while the 90/10 sample presents miscibility, the 85/15 sample indicates a phase separation. Besides, the lamellar structure of PHB is affected due to the epoxy, mainly in the 90/10 sample. The results were analyzed on the basis of the competition between crystallization and phase separation processes.
Fil: Tognana, Sebastian Alberto. Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Provincia de Buenos Aires. Gobernacion. Comision de Invest.cientificas; Argentina;
Fil: Silva, Leonel Ignacio. Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Argentina; Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina;
Fil: Salgueiro, Walter Alberto. Provincia de Buenos Aires. Gobernacion. Comision de Invest.cientificas; Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Argentina; - Materia
-
MEZCLAS
EPOXI
PHB
CRISTALIZACIÓN - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/871
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Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutiratoTognana, Sebastian AlbertoSilva, Leonel IgnacioSalgueiro, Walter AlbertoMEZCLASEPOXIPHBCRISTALIZACIÓNhttps://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.3In this work, epoxy/poly-3-hydroxybutyrate (PHB) blends in two different proportions, 90/10 and 85/15, were studied. For this purpose, the samples were submitted to 80ºC and 120ºC for the curing process of epoxy. The phase separation and the crystallization were analyzed using optical microscopy and differential scanning calorimetry. Likewise, the lamellar structure of PHB was characterized using small angle X-ray scattering. Significant differences between the two proportions studied were found; while the 90/10 sample presents miscibility, the 85/15 sample indicates a phase separation. Besides, the lamellar structure of PHB is affected due to the epoxy, mainly in the 90/10 sample. The results were analyzed on the basis of the competition between crystallization and phase separation processes.Fil: Tognana, Sebastian Alberto. Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Provincia de Buenos Aires. Gobernacion. Comision de Invest.cientificas; Argentina;Fil: Silva, Leonel Ignacio. Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Argentina; Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina;Fil: Salgueiro, Walter Alberto. Provincia de Buenos Aires. Gobernacion. Comision de Invest.cientificas; Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Argentina;Assoc Brasil Polimeros2013-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/871Tognana, Sebastian Alberto; Silva, Leonel Ignacio; Salgueiro, Walter Alberto; Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato; Assoc Brasil Polimeros; Polímeros; 23; 12-2013; 358-3650104-14281678-5169spainfo:eu-repo/semantics/altIdentifier/doi/10.4322/polimeros.2013.033info:eu-repo/semantics/altIdentifier/url/http://www.scielo.br/scielo.php?pid=S0104-14282013000300012&script=sci_arttextinfo:eu-repo/semantics/altIdentifier/url/http://revistapolimeros.org.br/doi/10.4322/polimeros.2013.033info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:37:59Zoai:ri.conicet.gov.ar:11336/871instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:38:00.134CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato |
title |
Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato |
spellingShingle |
Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato Tognana, Sebastian Alberto MEZCLAS EPOXI PHB CRISTALIZACIÓN |
title_short |
Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato |
title_full |
Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato |
title_fullStr |
Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato |
title_full_unstemmed |
Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato |
title_sort |
Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato |
dc.creator.none.fl_str_mv |
Tognana, Sebastian Alberto Silva, Leonel Ignacio Salgueiro, Walter Alberto |
author |
Tognana, Sebastian Alberto |
author_facet |
Tognana, Sebastian Alberto Silva, Leonel Ignacio Salgueiro, Walter Alberto |
author_role |
author |
author2 |
Silva, Leonel Ignacio Salgueiro, Walter Alberto |
author2_role |
author author |
dc.subject.none.fl_str_mv |
MEZCLAS EPOXI PHB CRISTALIZACIÓN |
topic |
MEZCLAS EPOXI PHB CRISTALIZACIÓN |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1 https://purl.org/becyt/ford/1.3 |
dc.description.none.fl_txt_mv |
In this work, epoxy/poly-3-hydroxybutyrate (PHB) blends in two different proportions, 90/10 and 85/15, were studied. For this purpose, the samples were submitted to 80ºC and 120ºC for the curing process of epoxy. The phase separation and the crystallization were analyzed using optical microscopy and differential scanning calorimetry. Likewise, the lamellar structure of PHB was characterized using small angle X-ray scattering. Significant differences between the two proportions studied were found; while the 90/10 sample presents miscibility, the 85/15 sample indicates a phase separation. Besides, the lamellar structure of PHB is affected due to the epoxy, mainly in the 90/10 sample. The results were analyzed on the basis of the competition between crystallization and phase separation processes. Fil: Tognana, Sebastian Alberto. Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Provincia de Buenos Aires. Gobernacion. Comision de Invest.cientificas; Argentina; Fil: Silva, Leonel Ignacio. Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Argentina; Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina; Fil: Salgueiro, Walter Alberto. Provincia de Buenos Aires. Gobernacion. Comision de Invest.cientificas; Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Argentina; |
description |
In this work, epoxy/poly-3-hydroxybutyrate (PHB) blends in two different proportions, 90/10 and 85/15, were studied. For this purpose, the samples were submitted to 80ºC and 120ºC for the curing process of epoxy. The phase separation and the crystallization were analyzed using optical microscopy and differential scanning calorimetry. Likewise, the lamellar structure of PHB was characterized using small angle X-ray scattering. Significant differences between the two proportions studied were found; while the 90/10 sample presents miscibility, the 85/15 sample indicates a phase separation. Besides, the lamellar structure of PHB is affected due to the epoxy, mainly in the 90/10 sample. The results were analyzed on the basis of the competition between crystallization and phase separation processes. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/871 Tognana, Sebastian Alberto; Silva, Leonel Ignacio; Salgueiro, Walter Alberto; Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato; Assoc Brasil Polimeros; Polímeros; 23; 12-2013; 358-365 0104-1428 1678-5169 |
url |
http://hdl.handle.net/11336/871 |
identifier_str_mv |
Tognana, Sebastian Alberto; Silva, Leonel Ignacio; Salgueiro, Walter Alberto; Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato; Assoc Brasil Polimeros; Polímeros; 23; 12-2013; 358-365 0104-1428 1678-5169 |
dc.language.none.fl_str_mv |
spa |
language |
spa |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.4322/polimeros.2013.033 info:eu-repo/semantics/altIdentifier/url/http://www.scielo.br/scielo.php?pid=S0104-14282013000300012&script=sci_arttext info:eu-repo/semantics/altIdentifier/url/http://revistapolimeros.org.br/doi/10.4322/polimeros.2013.033 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Assoc Brasil Polimeros |
publisher.none.fl_str_mv |
Assoc Brasil Polimeros |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614401300103168 |
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13.070432 |