Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato

Autores
Tognana, Sebastian Alberto; Silva, Leonel Ignacio; Salgueiro, Walter Alberto
Año de publicación
2013
Idioma
español castellano
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, epoxy/poly-3-hydroxybutyrate (PHB) blends in two different proportions, 90/10 and 85/15, were studied. For this purpose, the samples were submitted to 80ºC and 120ºC for the curing process of epoxy. The phase separation and the crystallization were analyzed using optical microscopy and differential scanning calorimetry. Likewise, the lamellar structure of PHB was characterized using small angle X-ray scattering. Significant differences between the two proportions studied were found; while the 90/10 sample presents miscibility, the 85/15 sample indicates a phase separation. Besides, the lamellar structure of PHB is affected due to the epoxy, mainly in the 90/10 sample. The results were analyzed on the basis of the competition between crystallization and phase separation processes.
Fil: Tognana, Sebastian Alberto. Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Provincia de Buenos Aires. Gobernacion. Comision de Invest.cientificas; Argentina;
Fil: Silva, Leonel Ignacio. Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Argentina; Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina;
Fil: Salgueiro, Walter Alberto. Provincia de Buenos Aires. Gobernacion. Comision de Invest.cientificas; Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Argentina;
Materia
MEZCLAS
EPOXI
PHB
CRISTALIZACIÓN
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/871

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network_name_str CONICET Digital (CONICET)
spelling Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutiratoTognana, Sebastian AlbertoSilva, Leonel IgnacioSalgueiro, Walter AlbertoMEZCLASEPOXIPHBCRISTALIZACIÓNhttps://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.3In this work, epoxy/poly-3-hydroxybutyrate (PHB) blends in two different proportions, 90/10 and 85/15, were studied. For this purpose, the samples were submitted to 80ºC and 120ºC for the curing process of epoxy. The phase separation and the crystallization were analyzed using optical microscopy and differential scanning calorimetry. Likewise, the lamellar structure of PHB was characterized using small angle X-ray scattering. Significant differences between the two proportions studied were found; while the 90/10 sample presents miscibility, the 85/15 sample indicates a phase separation. Besides, the lamellar structure of PHB is affected due to the epoxy, mainly in the 90/10 sample. The results were analyzed on the basis of the competition between crystallization and phase separation processes.Fil: Tognana, Sebastian Alberto. Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Provincia de Buenos Aires. Gobernacion. Comision de Invest.cientificas; Argentina;Fil: Silva, Leonel Ignacio. Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Argentina; Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina;Fil: Salgueiro, Walter Alberto. Provincia de Buenos Aires. Gobernacion. Comision de Invest.cientificas; Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Argentina;Assoc Brasil Polimeros2013-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/871Tognana, Sebastian Alberto; Silva, Leonel Ignacio; Salgueiro, Walter Alberto; Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato; Assoc Brasil Polimeros; Polímeros; 23; 12-2013; 358-3650104-14281678-5169spainfo:eu-repo/semantics/altIdentifier/doi/10.4322/polimeros.2013.033info:eu-repo/semantics/altIdentifier/url/http://www.scielo.br/scielo.php?pid=S0104-14282013000300012&script=sci_arttextinfo:eu-repo/semantics/altIdentifier/url/http://revistapolimeros.org.br/doi/10.4322/polimeros.2013.033info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:37:59Zoai:ri.conicet.gov.ar:11336/871instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:38:00.134CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato
title Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato
spellingShingle Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato
Tognana, Sebastian Alberto
MEZCLAS
EPOXI
PHB
CRISTALIZACIÓN
title_short Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato
title_full Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato
title_fullStr Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato
title_full_unstemmed Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato
title_sort Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato
dc.creator.none.fl_str_mv Tognana, Sebastian Alberto
Silva, Leonel Ignacio
Salgueiro, Walter Alberto
author Tognana, Sebastian Alberto
author_facet Tognana, Sebastian Alberto
Silva, Leonel Ignacio
Salgueiro, Walter Alberto
author_role author
author2 Silva, Leonel Ignacio
Salgueiro, Walter Alberto
author2_role author
author
dc.subject.none.fl_str_mv MEZCLAS
EPOXI
PHB
CRISTALIZACIÓN
topic MEZCLAS
EPOXI
PHB
CRISTALIZACIÓN
purl_subject.fl_str_mv https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/1.3
dc.description.none.fl_txt_mv In this work, epoxy/poly-3-hydroxybutyrate (PHB) blends in two different proportions, 90/10 and 85/15, were studied. For this purpose, the samples were submitted to 80ºC and 120ºC for the curing process of epoxy. The phase separation and the crystallization were analyzed using optical microscopy and differential scanning calorimetry. Likewise, the lamellar structure of PHB was characterized using small angle X-ray scattering. Significant differences between the two proportions studied were found; while the 90/10 sample presents miscibility, the 85/15 sample indicates a phase separation. Besides, the lamellar structure of PHB is affected due to the epoxy, mainly in the 90/10 sample. The results were analyzed on the basis of the competition between crystallization and phase separation processes.
Fil: Tognana, Sebastian Alberto. Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Provincia de Buenos Aires. Gobernacion. Comision de Invest.cientificas; Argentina;
Fil: Silva, Leonel Ignacio. Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Argentina; Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina;
Fil: Salgueiro, Walter Alberto. Provincia de Buenos Aires. Gobernacion. Comision de Invest.cientificas; Universidad Nacional del Centro de la Provincia de Bs.as.. Facultad de Cs.exactas. Instituto de Fisica de Materiales Tandil; Argentina;
description In this work, epoxy/poly-3-hydroxybutyrate (PHB) blends in two different proportions, 90/10 and 85/15, were studied. For this purpose, the samples were submitted to 80ºC and 120ºC for the curing process of epoxy. The phase separation and the crystallization were analyzed using optical microscopy and differential scanning calorimetry. Likewise, the lamellar structure of PHB was characterized using small angle X-ray scattering. Significant differences between the two proportions studied were found; while the 90/10 sample presents miscibility, the 85/15 sample indicates a phase separation. Besides, the lamellar structure of PHB is affected due to the epoxy, mainly in the 90/10 sample. The results were analyzed on the basis of the competition between crystallization and phase separation processes.
publishDate 2013
dc.date.none.fl_str_mv 2013-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/871
Tognana, Sebastian Alberto; Silva, Leonel Ignacio; Salgueiro, Walter Alberto; Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato; Assoc Brasil Polimeros; Polímeros; 23; 12-2013; 358-365
0104-1428
1678-5169
url http://hdl.handle.net/11336/871
identifier_str_mv Tognana, Sebastian Alberto; Silva, Leonel Ignacio; Salgueiro, Walter Alberto; Separación de fases y cristalinidad en mezclas epoxy/poli-3-hidroxibutirato; Assoc Brasil Polimeros; Polímeros; 23; 12-2013; 358-365
0104-1428
1678-5169
dc.language.none.fl_str_mv spa
language spa
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.4322/polimeros.2013.033
info:eu-repo/semantics/altIdentifier/url/http://www.scielo.br/scielo.php?pid=S0104-14282013000300012&script=sci_arttext
info:eu-repo/semantics/altIdentifier/url/http://revistapolimeros.org.br/doi/10.4322/polimeros.2013.033
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Assoc Brasil Polimeros
publisher.none.fl_str_mv Assoc Brasil Polimeros
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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