A SAXS study of PHB/DGEBA blends crystallized at different temperatures

Autores
Tognana, Sebastian Alberto; Salgueiro, Walter; Silva, Leonel Ignacio
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A small-angle X-ray scattering (SAXS) study of blends of poly-3-hydroxybutyrate (PHB)/diglycidyl ether of bisphenol A (DGEBA) with weight ratios of 90/10, 70/30 and 50/50 and PHB isothermally crystallized at temperatures between 60ºC and120ºC for one hour was performed. PHB was studied at different temperatures between 30ºC and 140ºC. The scattering curve results (intensity as a function of scattering vector (q)) indicated a main peak and secondary peaks associated with the thickness of the lamellae of PHB (with a strong tendency to crystallization). The position of the main peak decreased when the temperaturewas increased. At high temperatures (~120ºC), a deformation was observed in the main peak and a secondary peak was superimposed. This secondary peak was associated with the lamellar structures formed during the re-crystallization process. The results are discussed based on the DGEBA inclusion in the blends, crystallization temperature and partial interlamellar segregation.
Fil: Tognana, Sebastian Alberto. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: Salgueiro, Walter. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: Silva, Leonel Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Materia
POLYMERIC BLENDS
DGEBA
PHB
SAXS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/10420
Acceder
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network_name_str CONICET Digital (CONICET)
spelling A SAXS study of PHB/DGEBA blends crystallized at different temperaturesTognana, Sebastian AlbertoSalgueiro, WalterSilva, Leonel IgnacioPOLYMERIC BLENDSDGEBAPHBSAXShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1A small-angle X-ray scattering (SAXS) study of blends of poly-3-hydroxybutyrate (PHB)/diglycidyl ether of bisphenol A (DGEBA) with weight ratios of 90/10, 70/30 and 50/50 and PHB isothermally crystallized at temperatures between 60ºC and120ºC for one hour was performed. PHB was studied at different temperatures between 30ºC and 140ºC. The scattering curve results (intensity as a function of scattering vector (q)) indicated a main peak and secondary peaks associated with the thickness of the lamellae of PHB (with a strong tendency to crystallization). The position of the main peak decreased when the temperaturewas increased. At high temperatures (~120ºC), a deformation was observed in the main peak and a secondary peak was superimposed. This secondary peak was associated with the lamellar structures formed during the re-crystallization process. The results are discussed based on the DGEBA inclusion in the blends, crystallization temperature and partial interlamellar segregation.Fil: Tognana, Sebastian Alberto. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; ArgentinaFil: Salgueiro, Walter. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; ArgentinaFil: Silva, Leonel Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaElsevier2015-07-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/10420Tognana, Sebastian Alberto; Salgueiro, Walter; Silva, Leonel Ignacio; A SAXS study of PHB/DGEBA blends crystallized at different temperatures; Elsevier; Procedia Materials Science; 8; 2-7-2015; 271-2772211-8128enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S2211812815000747info:eu-repo/semantics/altIdentifier/url/http://dx.doi.org/10.1016/j.mspro.2015.04.073info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:11:30Zoai:ri.conicet.gov.ar:11336/10420instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:11:30.863CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A SAXS study of PHB/DGEBA blends crystallized at different temperatures
title A SAXS study of PHB/DGEBA blends crystallized at different temperatures
spellingShingle A SAXS study of PHB/DGEBA blends crystallized at different temperatures
Tognana, Sebastian Alberto
POLYMERIC BLENDS
DGEBA
PHB
SAXS
title_short A SAXS study of PHB/DGEBA blends crystallized at different temperatures
title_full A SAXS study of PHB/DGEBA blends crystallized at different temperatures
title_fullStr A SAXS study of PHB/DGEBA blends crystallized at different temperatures
title_full_unstemmed A SAXS study of PHB/DGEBA blends crystallized at different temperatures
title_sort A SAXS study of PHB/DGEBA blends crystallized at different temperatures
dc.creator.none.fl_str_mv Tognana, Sebastian Alberto
Salgueiro, Walter
Silva, Leonel Ignacio
author Tognana, Sebastian Alberto
author_facet Tognana, Sebastian Alberto
Salgueiro, Walter
Silva, Leonel Ignacio
author_role author
author2 Salgueiro, Walter
Silva, Leonel Ignacio
author2_role author
author
dc.subject.none.fl_str_mv POLYMERIC BLENDS
DGEBA
PHB
SAXS
topic POLYMERIC BLENDS
DGEBA
PHB
SAXS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A small-angle X-ray scattering (SAXS) study of blends of poly-3-hydroxybutyrate (PHB)/diglycidyl ether of bisphenol A (DGEBA) with weight ratios of 90/10, 70/30 and 50/50 and PHB isothermally crystallized at temperatures between 60ºC and120ºC for one hour was performed. PHB was studied at different temperatures between 30ºC and 140ºC. The scattering curve results (intensity as a function of scattering vector (q)) indicated a main peak and secondary peaks associated with the thickness of the lamellae of PHB (with a strong tendency to crystallization). The position of the main peak decreased when the temperaturewas increased. At high temperatures (~120ºC), a deformation was observed in the main peak and a secondary peak was superimposed. This secondary peak was associated with the lamellar structures formed during the re-crystallization process. The results are discussed based on the DGEBA inclusion in the blends, crystallization temperature and partial interlamellar segregation.
Fil: Tognana, Sebastian Alberto. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: Salgueiro, Walter. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ciencias Exactas. Instituto de Física de Materiales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Tandil. Centro de Investigaciones en Física e Ingeniería del Centro de la Provincia de Buenos Aires; Argentina
Fil: Silva, Leonel Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
description A small-angle X-ray scattering (SAXS) study of blends of poly-3-hydroxybutyrate (PHB)/diglycidyl ether of bisphenol A (DGEBA) with weight ratios of 90/10, 70/30 and 50/50 and PHB isothermally crystallized at temperatures between 60ºC and120ºC for one hour was performed. PHB was studied at different temperatures between 30ºC and 140ºC. The scattering curve results (intensity as a function of scattering vector (q)) indicated a main peak and secondary peaks associated with the thickness of the lamellae of PHB (with a strong tendency to crystallization). The position of the main peak decreased when the temperaturewas increased. At high temperatures (~120ºC), a deformation was observed in the main peak and a secondary peak was superimposed. This secondary peak was associated with the lamellar structures formed during the re-crystallization process. The results are discussed based on the DGEBA inclusion in the blends, crystallization temperature and partial interlamellar segregation.
publishDate 2015
dc.date.none.fl_str_mv 2015-07-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/10420
Tognana, Sebastian Alberto; Salgueiro, Walter; Silva, Leonel Ignacio; A SAXS study of PHB/DGEBA blends crystallized at different temperatures; Elsevier; Procedia Materials Science; 8; 2-7-2015; 271-277
2211-8128
url http://hdl.handle.net/11336/10420
identifier_str_mv Tognana, Sebastian Alberto; Salgueiro, Walter; Silva, Leonel Ignacio; A SAXS study of PHB/DGEBA blends crystallized at different temperatures; Elsevier; Procedia Materials Science; 8; 2-7-2015; 271-277
2211-8128
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S2211812815000747
info:eu-repo/semantics/altIdentifier/url/http://dx.doi.org/10.1016/j.mspro.2015.04.073
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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