Production of aromatic compounds in the heavy naphtha and light LCO ranges: Catalytic cracking of C10 naphthenic-aromatics and aromatics

Autores
Pujro Tarquino, Richard Alfonzo; Falco, Marisa Guadalupe; Sedran, Ulises Anselmo
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
BACKGROUND: The conversions of bicyclic compounds, both a naphthenic-aromatic compound (tetralin) and an aromatic compound (naphthalene), as model reactants representative of the heavy gasoline and light cycle oil (LCO) cuts in fluid catalytic cracking (FCC), were studied to understand the formation of C10–C20 aromatic compounds in gasoline and middle distillates cuts, in view of their impact on the properties of the cuts. A commercial FCC catalyst was used in its fresh, hydrothermally de-aluminated and equilibrium forms, at 450 °C in a fluidized bed CREC Riser Simulator reactor in the 2–8 s reaction time range. RESULTS: Products were C1–C14 hydrocarbons and coke. Based on the product distributions, reaction networks were proposed for both reactants. The reactions considered in the networks were hydrogen transfer, cracking, ring opening and contraction, alkylation and disproportionation. CONCLUSION: The load of zeolite in the catalysts and their acidities have the strongest influences on reaction selectivities. In the case of tetralin, the prevalent reaction is hydrogen transfer, which becomes more important as the catalysts are less active, the hydrocarbons with highest yields being C10 aromatics. Cracking reactions predominate in naphthalene conversion over all the catalysts, a fact which favors mono-aromatic C9− hydrocarbons. These results can help in the design of new FCC catalysts with better selectivity control.
Fil: Pujro Tarquino, Richard Alfonzo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
Catalysis
Zeolites
Polycyclic Aromatic Hydrocarbons (Pahs)
Catalytic Processes
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31049
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/31049
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Production of aromatic compounds in the heavy naphtha and light LCO ranges: Catalytic cracking of C10 naphthenic-aromatics and aromaticsPujro Tarquino, Richard AlfonzoFalco, Marisa GuadalupeSedran, Ulises AnselmoCatalysisZeolitesPolycyclic Aromatic Hydrocarbons (Pahs)Catalytic Processeshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2BACKGROUND: The conversions of bicyclic compounds, both a naphthenic-aromatic compound (tetralin) and an aromatic compound (naphthalene), as model reactants representative of the heavy gasoline and light cycle oil (LCO) cuts in fluid catalytic cracking (FCC), were studied to understand the formation of C10–C20 aromatic compounds in gasoline and middle distillates cuts, in view of their impact on the properties of the cuts. A commercial FCC catalyst was used in its fresh, hydrothermally de-aluminated and equilibrium forms, at 450 °C in a fluidized bed CREC Riser Simulator reactor in the 2–8 s reaction time range. RESULTS: Products were C1–C14 hydrocarbons and coke. Based on the product distributions, reaction networks were proposed for both reactants. The reactions considered in the networks were hydrogen transfer, cracking, ring opening and contraction, alkylation and disproportionation. CONCLUSION: The load of zeolite in the catalysts and their acidities have the strongest influences on reaction selectivities. In the case of tetralin, the prevalent reaction is hydrogen transfer, which becomes more important as the catalysts are less active, the hydrocarbons with highest yields being C10 aromatics. Cracking reactions predominate in naphthalene conversion over all the catalysts, a fact which favors mono-aromatic C9− hydrocarbons. These results can help in the design of new FCC catalysts with better selectivity control.Fil: Pujro Tarquino, Richard Alfonzo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaWiley2014-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31049Sedran, Ulises Anselmo; Falco, Marisa Guadalupe; Pujro Tarquino, Richard Alfonzo; Production of aromatic compounds in the heavy naphtha and light LCO ranges: Catalytic cracking of C10 naphthenic-aromatics and aromatics; Wiley; Journal of Chemical Technology and Biotechnology; 91; 2; 11-2014; 336-3450268-25751097-4660CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/jctb.4570info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/jctb.4570/abstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:43:21Zoai:ri.conicet.gov.ar:11336/31049instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:43:21.791CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Production of aromatic compounds in the heavy naphtha and light LCO ranges: Catalytic cracking of C10 naphthenic-aromatics and aromatics
title Production of aromatic compounds in the heavy naphtha and light LCO ranges: Catalytic cracking of C10 naphthenic-aromatics and aromatics
spellingShingle Production of aromatic compounds in the heavy naphtha and light LCO ranges: Catalytic cracking of C10 naphthenic-aromatics and aromatics
Pujro Tarquino, Richard Alfonzo
Catalysis
Zeolites
Polycyclic Aromatic Hydrocarbons (Pahs)
Catalytic Processes
title_short Production of aromatic compounds in the heavy naphtha and light LCO ranges: Catalytic cracking of C10 naphthenic-aromatics and aromatics
title_full Production of aromatic compounds in the heavy naphtha and light LCO ranges: Catalytic cracking of C10 naphthenic-aromatics and aromatics
title_fullStr Production of aromatic compounds in the heavy naphtha and light LCO ranges: Catalytic cracking of C10 naphthenic-aromatics and aromatics
title_full_unstemmed Production of aromatic compounds in the heavy naphtha and light LCO ranges: Catalytic cracking of C10 naphthenic-aromatics and aromatics
title_sort Production of aromatic compounds in the heavy naphtha and light LCO ranges: Catalytic cracking of C10 naphthenic-aromatics and aromatics
dc.creator.none.fl_str_mv Pujro Tarquino, Richard Alfonzo
Falco, Marisa Guadalupe
Sedran, Ulises Anselmo
author Pujro Tarquino, Richard Alfonzo
author_facet Pujro Tarquino, Richard Alfonzo
Falco, Marisa Guadalupe
Sedran, Ulises Anselmo
author_role author
author2 Falco, Marisa Guadalupe
Sedran, Ulises Anselmo
author2_role author
author
dc.subject.none.fl_str_mv Catalysis
Zeolites
Polycyclic Aromatic Hydrocarbons (Pahs)
Catalytic Processes
topic Catalysis
Zeolites
Polycyclic Aromatic Hydrocarbons (Pahs)
Catalytic Processes
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv BACKGROUND: The conversions of bicyclic compounds, both a naphthenic-aromatic compound (tetralin) and an aromatic compound (naphthalene), as model reactants representative of the heavy gasoline and light cycle oil (LCO) cuts in fluid catalytic cracking (FCC), were studied to understand the formation of C10–C20 aromatic compounds in gasoline and middle distillates cuts, in view of their impact on the properties of the cuts. A commercial FCC catalyst was used in its fresh, hydrothermally de-aluminated and equilibrium forms, at 450 °C in a fluidized bed CREC Riser Simulator reactor in the 2–8 s reaction time range. RESULTS: Products were C1–C14 hydrocarbons and coke. Based on the product distributions, reaction networks were proposed for both reactants. The reactions considered in the networks were hydrogen transfer, cracking, ring opening and contraction, alkylation and disproportionation. CONCLUSION: The load of zeolite in the catalysts and their acidities have the strongest influences on reaction selectivities. In the case of tetralin, the prevalent reaction is hydrogen transfer, which becomes more important as the catalysts are less active, the hydrocarbons with highest yields being C10 aromatics. Cracking reactions predominate in naphthalene conversion over all the catalysts, a fact which favors mono-aromatic C9− hydrocarbons. These results can help in the design of new FCC catalysts with better selectivity control.
Fil: Pujro Tarquino, Richard Alfonzo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description BACKGROUND: The conversions of bicyclic compounds, both a naphthenic-aromatic compound (tetralin) and an aromatic compound (naphthalene), as model reactants representative of the heavy gasoline and light cycle oil (LCO) cuts in fluid catalytic cracking (FCC), were studied to understand the formation of C10–C20 aromatic compounds in gasoline and middle distillates cuts, in view of their impact on the properties of the cuts. A commercial FCC catalyst was used in its fresh, hydrothermally de-aluminated and equilibrium forms, at 450 °C in a fluidized bed CREC Riser Simulator reactor in the 2–8 s reaction time range. RESULTS: Products were C1–C14 hydrocarbons and coke. Based on the product distributions, reaction networks were proposed for both reactants. The reactions considered in the networks were hydrogen transfer, cracking, ring opening and contraction, alkylation and disproportionation. CONCLUSION: The load of zeolite in the catalysts and their acidities have the strongest influences on reaction selectivities. In the case of tetralin, the prevalent reaction is hydrogen transfer, which becomes more important as the catalysts are less active, the hydrocarbons with highest yields being C10 aromatics. Cracking reactions predominate in naphthalene conversion over all the catalysts, a fact which favors mono-aromatic C9− hydrocarbons. These results can help in the design of new FCC catalysts with better selectivity control.
publishDate 2014
dc.date.none.fl_str_mv 2014-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31049
Sedran, Ulises Anselmo; Falco, Marisa Guadalupe; Pujro Tarquino, Richard Alfonzo; Production of aromatic compounds in the heavy naphtha and light LCO ranges: Catalytic cracking of C10 naphthenic-aromatics and aromatics; Wiley; Journal of Chemical Technology and Biotechnology; 91; 2; 11-2014; 336-345
0268-2575
1097-4660
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31049
identifier_str_mv Sedran, Ulises Anselmo; Falco, Marisa Guadalupe; Pujro Tarquino, Richard Alfonzo; Production of aromatic compounds in the heavy naphtha and light LCO ranges: Catalytic cracking of C10 naphthenic-aromatics and aromatics; Wiley; Journal of Chemical Technology and Biotechnology; 91; 2; 11-2014; 336-345
0268-2575
1097-4660
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/jctb.4570
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/jctb.4570/abstract
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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