On-line preconcentration of zinc on ethyl vinyl acetate prior to its determination by CVG-ICP-OES

Autores
Escudero, Luis Ariel; Cerutti, Estela Soledad; Martinez, Luis Dante; Salonia, José Antonio; Gasquez, José Antonio
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A separation/preconcentration procedure using solid phase extraction coupled to zinc vapor generation associated to inductively coupled plasma optical emission spectrometry determination in water samples was studied. The solid phase material was ethyl vinyl acetate (EVA) contained in a column, where the analyte ions were retained without using any complexation agent. The variables involving the preconcentration and the chemical vapor generation (CVG) were optimized using both full factorial and central composite designs, respectively. Volatile species of zinc were generated by merging the acidified eluent and sodium tetrahydroborate in a continuous flow system. The gaseous analyte was introduced via a stream of Ar carrier into the inlet tube of the ICP torch. An enhancement factor of 230-fold for a sample volume of 16 mL was obtained. The detection limit was 0.06 μg L− 1. The proposed method was successfully applied to the determination of traces of zinc in a Certified Reference Material and tap and river water samples.
Fil: Escudero, Luis Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Cerutti, Estela Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Martinez, Luis Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Salonia, José Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Gasquez, José Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Materia
Zinc Determination
On-Line Preconcentration
Chemical Vapor Generation
Eva
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5773
Acceder
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network_name_str CONICET Digital (CONICET)
spelling On-line preconcentration of zinc on ethyl vinyl acetate prior to its determination by CVG-ICP-OESEscudero, Luis ArielCerutti, Estela SoledadMartinez, Luis DanteSalonia, José AntonioGasquez, José AntonioZinc DeterminationOn-Line PreconcentrationChemical Vapor GenerationEvahttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A separation/preconcentration procedure using solid phase extraction coupled to zinc vapor generation associated to inductively coupled plasma optical emission spectrometry determination in water samples was studied. The solid phase material was ethyl vinyl acetate (EVA) contained in a column, where the analyte ions were retained without using any complexation agent. The variables involving the preconcentration and the chemical vapor generation (CVG) were optimized using both full factorial and central composite designs, respectively. Volatile species of zinc were generated by merging the acidified eluent and sodium tetrahydroborate in a continuous flow system. The gaseous analyte was introduced via a stream of Ar carrier into the inlet tube of the ICP torch. An enhancement factor of 230-fold for a sample volume of 16 mL was obtained. The detection limit was 0.06 μg L− 1. The proposed method was successfully applied to the determination of traces of zinc in a Certified Reference Material and tap and river water samples.Fil: Escudero, Luis Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Cerutti, Estela Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Martinez, Luis Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Salonia, José Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaFil: Gasquez, José Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; ArgentinaElsevier2013-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5773Escudero, Luis Ariel; Cerutti, Estela Soledad; Martinez, Luis Dante; Salonia, José Antonio; Gasquez, José Antonio; On-line preconcentration of zinc on ethyl vinyl acetate prior to its determination by CVG-ICP-OES; Elsevier; Microchemical Journal; 106; 4-2013; 34-400026-265Xenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0026265X12001063info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2012.04.013info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:56:42Zoai:ri.conicet.gov.ar:11336/5773instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:56:42.339CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv On-line preconcentration of zinc on ethyl vinyl acetate prior to its determination by CVG-ICP-OES
title On-line preconcentration of zinc on ethyl vinyl acetate prior to its determination by CVG-ICP-OES
spellingShingle On-line preconcentration of zinc on ethyl vinyl acetate prior to its determination by CVG-ICP-OES
Escudero, Luis Ariel
Zinc Determination
On-Line Preconcentration
Chemical Vapor Generation
Eva
title_short On-line preconcentration of zinc on ethyl vinyl acetate prior to its determination by CVG-ICP-OES
title_full On-line preconcentration of zinc on ethyl vinyl acetate prior to its determination by CVG-ICP-OES
title_fullStr On-line preconcentration of zinc on ethyl vinyl acetate prior to its determination by CVG-ICP-OES
title_full_unstemmed On-line preconcentration of zinc on ethyl vinyl acetate prior to its determination by CVG-ICP-OES
title_sort On-line preconcentration of zinc on ethyl vinyl acetate prior to its determination by CVG-ICP-OES
dc.creator.none.fl_str_mv Escudero, Luis Ariel
Cerutti, Estela Soledad
Martinez, Luis Dante
Salonia, José Antonio
Gasquez, José Antonio
author Escudero, Luis Ariel
author_facet Escudero, Luis Ariel
Cerutti, Estela Soledad
Martinez, Luis Dante
Salonia, José Antonio
Gasquez, José Antonio
author_role author
author2 Cerutti, Estela Soledad
Martinez, Luis Dante
Salonia, José Antonio
Gasquez, José Antonio
author2_role author
author
author
author
dc.subject.none.fl_str_mv Zinc Determination
On-Line Preconcentration
Chemical Vapor Generation
Eva
topic Zinc Determination
On-Line Preconcentration
Chemical Vapor Generation
Eva
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A separation/preconcentration procedure using solid phase extraction coupled to zinc vapor generation associated to inductively coupled plasma optical emission spectrometry determination in water samples was studied. The solid phase material was ethyl vinyl acetate (EVA) contained in a column, where the analyte ions were retained without using any complexation agent. The variables involving the preconcentration and the chemical vapor generation (CVG) were optimized using both full factorial and central composite designs, respectively. Volatile species of zinc were generated by merging the acidified eluent and sodium tetrahydroborate in a continuous flow system. The gaseous analyte was introduced via a stream of Ar carrier into the inlet tube of the ICP torch. An enhancement factor of 230-fold for a sample volume of 16 mL was obtained. The detection limit was 0.06 μg L− 1. The proposed method was successfully applied to the determination of traces of zinc in a Certified Reference Material and tap and river water samples.
Fil: Escudero, Luis Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Cerutti, Estela Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Martinez, Luis Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Salonia, José Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
Fil: Gasquez, José Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Química de San Luis; Argentina
description A separation/preconcentration procedure using solid phase extraction coupled to zinc vapor generation associated to inductively coupled plasma optical emission spectrometry determination in water samples was studied. The solid phase material was ethyl vinyl acetate (EVA) contained in a column, where the analyte ions were retained without using any complexation agent. The variables involving the preconcentration and the chemical vapor generation (CVG) were optimized using both full factorial and central composite designs, respectively. Volatile species of zinc were generated by merging the acidified eluent and sodium tetrahydroborate in a continuous flow system. The gaseous analyte was introduced via a stream of Ar carrier into the inlet tube of the ICP torch. An enhancement factor of 230-fold for a sample volume of 16 mL was obtained. The detection limit was 0.06 μg L− 1. The proposed method was successfully applied to the determination of traces of zinc in a Certified Reference Material and tap and river water samples.
publishDate 2013
dc.date.none.fl_str_mv 2013-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5773
Escudero, Luis Ariel; Cerutti, Estela Soledad; Martinez, Luis Dante; Salonia, José Antonio; Gasquez, José Antonio; On-line preconcentration of zinc on ethyl vinyl acetate prior to its determination by CVG-ICP-OES; Elsevier; Microchemical Journal; 106; 4-2013; 34-40
0026-265X
url http://hdl.handle.net/11336/5773
identifier_str_mv Escudero, Luis Ariel; Cerutti, Estela Soledad; Martinez, Luis Dante; Salonia, José Antonio; Gasquez, José Antonio; On-line preconcentration of zinc on ethyl vinyl acetate prior to its determination by CVG-ICP-OES; Elsevier; Microchemical Journal; 106; 4-2013; 34-40
0026-265X
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0026265X12001063
info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2012.04.013
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269418721116160
score 13.13397

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