Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes

Autores
De Queiroz, Angel A.A.; Soares, Demetrio A.W.; Tresniack, P.; Abraham, Gustavo Abel
Año de publicación
2001
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Poly(vinylpyrrolidone) films containing cobalt chloride or iodine were investigated to obtain information on their possible use as a humidity sensor element. FTIR and UV-VIS spectroscopies were used to characterize the PVP–I2 and PVP–Co complexes. Infrared spectroscopy revealed a structural change of both shape and intensity of the carbonyl and lactam bands, indicating the formation of an ion-coordination polymer. The J–E curves for pure PVP, PVP–I2, and PVP–Co films obey ohm's law at low voltages, deviate from the linear response at higher voltages, and finally display breakdown behavior. An increase in current density of the PVP matrix with iodine or cobalt doping is attributed to the formation of charge transfer complexes. The observed hysteresis of the I–V characteristics implies that there was some standing voltage in the film, which could be attributed to a disorientation of polar side groups of PVP. The electrical conductivities of the polymeric complexes were very sensitive to environmental humidity. An explanation of the humidity-sensing behavior of the PVP–I2 and PVP–Co complexes is presented.
Fil: De Queiroz, Angel A.A.. Universidade Federal Itajuba; Brasil
Fil: Soares, Demetrio A.W.. Universidade Federal Itajuba; Brasil
Fil: Tresniack, P.. Universidade Federal Itajuba; Brasil
Fil: Abraham, Gustavo Abel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Poly(Vinylpyrrolidone)
Charge Transfer Complexes
Electrical Properties
Humidity Sensors
Polymeric Electret Behavior
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/35736

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network_name_str CONICET Digital (CONICET)
spelling Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexesDe Queiroz, Angel A.A.Soares, Demetrio A.W.Tresniack, P.Abraham, Gustavo AbelPoly(Vinylpyrrolidone)Charge Transfer ComplexesElectrical PropertiesHumidity SensorsPolymeric Electret Behaviorhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Poly(vinylpyrrolidone) films containing cobalt chloride or iodine were investigated to obtain information on their possible use as a humidity sensor element. FTIR and UV-VIS spectroscopies were used to characterize the PVP–I2 and PVP–Co complexes. Infrared spectroscopy revealed a structural change of both shape and intensity of the carbonyl and lactam bands, indicating the formation of an ion-coordination polymer. The J–E curves for pure PVP, PVP–I2, and PVP–Co films obey ohm's law at low voltages, deviate from the linear response at higher voltages, and finally display breakdown behavior. An increase in current density of the PVP matrix with iodine or cobalt doping is attributed to the formation of charge transfer complexes. The observed hysteresis of the I–V characteristics implies that there was some standing voltage in the film, which could be attributed to a disorientation of polar side groups of PVP. The electrical conductivities of the polymeric complexes were very sensitive to environmental humidity. An explanation of the humidity-sensing behavior of the PVP–I2 and PVP–Co complexes is presented.Fil: De Queiroz, Angel A.A.. Universidade Federal Itajuba; BrasilFil: Soares, Demetrio A.W.. Universidade Federal Itajuba; BrasilFil: Tresniack, P.. Universidade Federal Itajuba; BrasilFil: Abraham, Gustavo Abel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaJohn Wiley & Sons Inc2001-01-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/35736De Queiroz, Angel A.A.; Soares, Demetrio A.W.; Tresniack, P.; Abraham, Gustavo Abel; Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes; John Wiley & Sons Inc; Journal of Polymer Science Part B: Polymer Physics; 39; 4; 11-1-2001; 459-4690887-6266CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/1099-0488(20010215)39:4<459::AID-POLB1019>3.0.CO;2-Tinfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/1099-0488(20010215)39:4%3C459::AID-POLB1019%3E3.0.CO;2-T/abstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:23:41Zoai:ri.conicet.gov.ar:11336/35736instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:23:42.078CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes
title Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes
spellingShingle Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes
De Queiroz, Angel A.A.
Poly(Vinylpyrrolidone)
Charge Transfer Complexes
Electrical Properties
Humidity Sensors
Polymeric Electret Behavior
title_short Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes
title_full Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes
title_fullStr Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes
title_full_unstemmed Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes
title_sort Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes
dc.creator.none.fl_str_mv De Queiroz, Angel A.A.
Soares, Demetrio A.W.
Tresniack, P.
Abraham, Gustavo Abel
author De Queiroz, Angel A.A.
author_facet De Queiroz, Angel A.A.
Soares, Demetrio A.W.
Tresniack, P.
Abraham, Gustavo Abel
author_role author
author2 Soares, Demetrio A.W.
Tresniack, P.
Abraham, Gustavo Abel
author2_role author
author
author
dc.subject.none.fl_str_mv Poly(Vinylpyrrolidone)
Charge Transfer Complexes
Electrical Properties
Humidity Sensors
Polymeric Electret Behavior
topic Poly(Vinylpyrrolidone)
Charge Transfer Complexes
Electrical Properties
Humidity Sensors
Polymeric Electret Behavior
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Poly(vinylpyrrolidone) films containing cobalt chloride or iodine were investigated to obtain information on their possible use as a humidity sensor element. FTIR and UV-VIS spectroscopies were used to characterize the PVP–I2 and PVP–Co complexes. Infrared spectroscopy revealed a structural change of both shape and intensity of the carbonyl and lactam bands, indicating the formation of an ion-coordination polymer. The J–E curves for pure PVP, PVP–I2, and PVP–Co films obey ohm's law at low voltages, deviate from the linear response at higher voltages, and finally display breakdown behavior. An increase in current density of the PVP matrix with iodine or cobalt doping is attributed to the formation of charge transfer complexes. The observed hysteresis of the I–V characteristics implies that there was some standing voltage in the film, which could be attributed to a disorientation of polar side groups of PVP. The electrical conductivities of the polymeric complexes were very sensitive to environmental humidity. An explanation of the humidity-sensing behavior of the PVP–I2 and PVP–Co complexes is presented.
Fil: De Queiroz, Angel A.A.. Universidade Federal Itajuba; Brasil
Fil: Soares, Demetrio A.W.. Universidade Federal Itajuba; Brasil
Fil: Tresniack, P.. Universidade Federal Itajuba; Brasil
Fil: Abraham, Gustavo Abel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Poly(vinylpyrrolidone) films containing cobalt chloride or iodine were investigated to obtain information on their possible use as a humidity sensor element. FTIR and UV-VIS spectroscopies were used to characterize the PVP–I2 and PVP–Co complexes. Infrared spectroscopy revealed a structural change of both shape and intensity of the carbonyl and lactam bands, indicating the formation of an ion-coordination polymer. The J–E curves for pure PVP, PVP–I2, and PVP–Co films obey ohm's law at low voltages, deviate from the linear response at higher voltages, and finally display breakdown behavior. An increase in current density of the PVP matrix with iodine or cobalt doping is attributed to the formation of charge transfer complexes. The observed hysteresis of the I–V characteristics implies that there was some standing voltage in the film, which could be attributed to a disorientation of polar side groups of PVP. The electrical conductivities of the polymeric complexes were very sensitive to environmental humidity. An explanation of the humidity-sensing behavior of the PVP–I2 and PVP–Co complexes is presented.
publishDate 2001
dc.date.none.fl_str_mv 2001-01-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/35736
De Queiroz, Angel A.A.; Soares, Demetrio A.W.; Tresniack, P.; Abraham, Gustavo Abel; Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes; John Wiley & Sons Inc; Journal of Polymer Science Part B: Polymer Physics; 39; 4; 11-1-2001; 459-469
0887-6266
CONICET Digital
CONICET
url http://hdl.handle.net/11336/35736
identifier_str_mv De Queiroz, Angel A.A.; Soares, Demetrio A.W.; Tresniack, P.; Abraham, Gustavo Abel; Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes; John Wiley & Sons Inc; Journal of Polymer Science Part B: Polymer Physics; 39; 4; 11-1-2001; 459-469
0887-6266
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/1099-0488(20010215)39:4<459::AID-POLB1019>3.0.CO;2-T
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/1099-0488(20010215)39:4%3C459::AID-POLB1019%3E3.0.CO;2-T/abstract
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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