Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes
- Autores
- De Queiroz, Angel A.A.; Soares, Demetrio A.W.; Tresniack, P.; Abraham, Gustavo Abel
- Año de publicación
- 2001
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Poly(vinylpyrrolidone) films containing cobalt chloride or iodine were investigated to obtain information on their possible use as a humidity sensor element. FTIR and UV-VIS spectroscopies were used to characterize the PVP–I2 and PVP–Co complexes. Infrared spectroscopy revealed a structural change of both shape and intensity of the carbonyl and lactam bands, indicating the formation of an ion-coordination polymer. The J–E curves for pure PVP, PVP–I2, and PVP–Co films obey ohm's law at low voltages, deviate from the linear response at higher voltages, and finally display breakdown behavior. An increase in current density of the PVP matrix with iodine or cobalt doping is attributed to the formation of charge transfer complexes. The observed hysteresis of the I–V characteristics implies that there was some standing voltage in the film, which could be attributed to a disorientation of polar side groups of PVP. The electrical conductivities of the polymeric complexes were very sensitive to environmental humidity. An explanation of the humidity-sensing behavior of the PVP–I2 and PVP–Co complexes is presented.
Fil: De Queiroz, Angel A.A.. Universidade Federal Itajuba; Brasil
Fil: Soares, Demetrio A.W.. Universidade Federal Itajuba; Brasil
Fil: Tresniack, P.. Universidade Federal Itajuba; Brasil
Fil: Abraham, Gustavo Abel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina - Materia
-
Poly(Vinylpyrrolidone)
Charge Transfer Complexes
Electrical Properties
Humidity Sensors
Polymeric Electret Behavior - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/35736
Ver los metadatos del registro completo
id |
CONICETDig_3a1840cf39ee50dbe98300f06447d18e |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/35736 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexesDe Queiroz, Angel A.A.Soares, Demetrio A.W.Tresniack, P.Abraham, Gustavo AbelPoly(Vinylpyrrolidone)Charge Transfer ComplexesElectrical PropertiesHumidity SensorsPolymeric Electret Behaviorhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Poly(vinylpyrrolidone) films containing cobalt chloride or iodine were investigated to obtain information on their possible use as a humidity sensor element. FTIR and UV-VIS spectroscopies were used to characterize the PVP–I2 and PVP–Co complexes. Infrared spectroscopy revealed a structural change of both shape and intensity of the carbonyl and lactam bands, indicating the formation of an ion-coordination polymer. The J–E curves for pure PVP, PVP–I2, and PVP–Co films obey ohm's law at low voltages, deviate from the linear response at higher voltages, and finally display breakdown behavior. An increase in current density of the PVP matrix with iodine or cobalt doping is attributed to the formation of charge transfer complexes. The observed hysteresis of the I–V characteristics implies that there was some standing voltage in the film, which could be attributed to a disorientation of polar side groups of PVP. The electrical conductivities of the polymeric complexes were very sensitive to environmental humidity. An explanation of the humidity-sensing behavior of the PVP–I2 and PVP–Co complexes is presented.Fil: De Queiroz, Angel A.A.. Universidade Federal Itajuba; BrasilFil: Soares, Demetrio A.W.. Universidade Federal Itajuba; BrasilFil: Tresniack, P.. Universidade Federal Itajuba; BrasilFil: Abraham, Gustavo Abel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaJohn Wiley & Sons Inc2001-01-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/35736De Queiroz, Angel A.A.; Soares, Demetrio A.W.; Tresniack, P.; Abraham, Gustavo Abel; Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes; John Wiley & Sons Inc; Journal of Polymer Science Part B: Polymer Physics; 39; 4; 11-1-2001; 459-4690887-6266CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/1099-0488(20010215)39:4<459::AID-POLB1019>3.0.CO;2-Tinfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/1099-0488(20010215)39:4%3C459::AID-POLB1019%3E3.0.CO;2-T/abstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:23:41Zoai:ri.conicet.gov.ar:11336/35736instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:23:42.078CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes |
title |
Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes |
spellingShingle |
Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes De Queiroz, Angel A.A. Poly(Vinylpyrrolidone) Charge Transfer Complexes Electrical Properties Humidity Sensors Polymeric Electret Behavior |
title_short |
Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes |
title_full |
Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes |
title_fullStr |
Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes |
title_full_unstemmed |
Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes |
title_sort |
Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes |
dc.creator.none.fl_str_mv |
De Queiroz, Angel A.A. Soares, Demetrio A.W. Tresniack, P. Abraham, Gustavo Abel |
author |
De Queiroz, Angel A.A. |
author_facet |
De Queiroz, Angel A.A. Soares, Demetrio A.W. Tresniack, P. Abraham, Gustavo Abel |
author_role |
author |
author2 |
Soares, Demetrio A.W. Tresniack, P. Abraham, Gustavo Abel |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Poly(Vinylpyrrolidone) Charge Transfer Complexes Electrical Properties Humidity Sensors Polymeric Electret Behavior |
topic |
Poly(Vinylpyrrolidone) Charge Transfer Complexes Electrical Properties Humidity Sensors Polymeric Electret Behavior |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Poly(vinylpyrrolidone) films containing cobalt chloride or iodine were investigated to obtain information on their possible use as a humidity sensor element. FTIR and UV-VIS spectroscopies were used to characterize the PVP–I2 and PVP–Co complexes. Infrared spectroscopy revealed a structural change of both shape and intensity of the carbonyl and lactam bands, indicating the formation of an ion-coordination polymer. The J–E curves for pure PVP, PVP–I2, and PVP–Co films obey ohm's law at low voltages, deviate from the linear response at higher voltages, and finally display breakdown behavior. An increase in current density of the PVP matrix with iodine or cobalt doping is attributed to the formation of charge transfer complexes. The observed hysteresis of the I–V characteristics implies that there was some standing voltage in the film, which could be attributed to a disorientation of polar side groups of PVP. The electrical conductivities of the polymeric complexes were very sensitive to environmental humidity. An explanation of the humidity-sensing behavior of the PVP–I2 and PVP–Co complexes is presented. Fil: De Queiroz, Angel A.A.. Universidade Federal Itajuba; Brasil Fil: Soares, Demetrio A.W.. Universidade Federal Itajuba; Brasil Fil: Tresniack, P.. Universidade Federal Itajuba; Brasil Fil: Abraham, Gustavo Abel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina |
description |
Poly(vinylpyrrolidone) films containing cobalt chloride or iodine were investigated to obtain information on their possible use as a humidity sensor element. FTIR and UV-VIS spectroscopies were used to characterize the PVP–I2 and PVP–Co complexes. Infrared spectroscopy revealed a structural change of both shape and intensity of the carbonyl and lactam bands, indicating the formation of an ion-coordination polymer. The J–E curves for pure PVP, PVP–I2, and PVP–Co films obey ohm's law at low voltages, deviate from the linear response at higher voltages, and finally display breakdown behavior. An increase in current density of the PVP matrix with iodine or cobalt doping is attributed to the formation of charge transfer complexes. The observed hysteresis of the I–V characteristics implies that there was some standing voltage in the film, which could be attributed to a disorientation of polar side groups of PVP. The electrical conductivities of the polymeric complexes were very sensitive to environmental humidity. An explanation of the humidity-sensing behavior of the PVP–I2 and PVP–Co complexes is presented. |
publishDate |
2001 |
dc.date.none.fl_str_mv |
2001-01-11 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/35736 De Queiroz, Angel A.A.; Soares, Demetrio A.W.; Tresniack, P.; Abraham, Gustavo Abel; Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes; John Wiley & Sons Inc; Journal of Polymer Science Part B: Polymer Physics; 39; 4; 11-1-2001; 459-469 0887-6266 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/35736 |
identifier_str_mv |
De Queiroz, Angel A.A.; Soares, Demetrio A.W.; Tresniack, P.; Abraham, Gustavo Abel; Resistive-type humidity sensors based on PVP–Co and PVP–I2 complexes; John Wiley & Sons Inc; Journal of Polymer Science Part B: Polymer Physics; 39; 4; 11-1-2001; 459-469 0887-6266 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1002/1099-0488(20010215)39:4<459::AID-POLB1019>3.0.CO;2-T info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/1099-0488(20010215)39:4%3C459::AID-POLB1019%3E3.0.CO;2-T/abstract |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
John Wiley & Sons Inc |
publisher.none.fl_str_mv |
John Wiley & Sons Inc |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844614232481464320 |
score |
13.070432 |