Lanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficient

Autores
Kilo, Martin; Taylor, Marcela Andrea; Argirusis, Christos; Borchardt, Günter; Weber, Sylvain; Scherrer, Hubert; Jackson, Robert A.
Año de publicación
2004
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The diffusion of all stable lanthanides in calcia stabilized zirconia (CSZ) and in yttria stabilized zirconia (YSZ) was measured. Lanthanide migration enthalpies were calculated using the Mott-littleton approach. The results suggest that the bulk diffusion coefficient depends on the ionic radius of the lanthanide tracer. It was also found that the experimental activation enthalpies are about 6eV for CSZ and between 4 and 5 eV for YSZ and almost constant for all lanthanides.
Fil: Kilo, Martin. Technische Universität Clausthal; Alemania
Fil: Taylor, Marcela Andrea. Technische Universität Clausthal; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Argirusis, Christos. Technische Universität Clausthal; Alemania
Fil: Borchardt, Günter. Technische Universität Clausthal; Alemania
Fil: Weber, Sylvain. École Nationale Supérieure Des Mines de Nancy; Francia
Fil: Scherrer, Hubert. École Nationale Supérieure Des Mines de Nancy; Francia
Fil: Jackson, Robert A.. Keele University; Reino Unido
Materia
Lanthanides
Cation diffusion
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/74365
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/74365
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Lanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficientKilo, MartinTaylor, Marcela AndreaArgirusis, ChristosBorchardt, GünterWeber, SylvainScherrer, HubertJackson, Robert A.LanthanidesCation diffusionhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The diffusion of all stable lanthanides in calcia stabilized zirconia (CSZ) and in yttria stabilized zirconia (YSZ) was measured. Lanthanide migration enthalpies were calculated using the Mott-littleton approach. The results suggest that the bulk diffusion coefficient depends on the ionic radius of the lanthanide tracer. It was also found that the experimental activation enthalpies are about 6eV for CSZ and between 4 and 5 eV for YSZ and almost constant for all lanthanides.Fil: Kilo, Martin. Technische Universität Clausthal; AlemaniaFil: Taylor, Marcela Andrea. Technische Universität Clausthal; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Argirusis, Christos. Technische Universität Clausthal; AlemaniaFil: Borchardt, Günter. Technische Universität Clausthal; AlemaniaFil: Weber, Sylvain. École Nationale Supérieure Des Mines de Nancy; FranciaFil: Scherrer, Hubert. École Nationale Supérieure Des Mines de Nancy; FranciaFil: Jackson, Robert A.. Keele University; Reino UnidoAmerican Institute of Physics2004-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/74365Kilo, Martin; Taylor, Marcela Andrea; Argirusis, Christos; Borchardt, Günter; Weber, Sylvain; et al.; Lanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficient; American Institute of Physics; Journal of Chemical Physics; 121; 11; 6-2004; 5482-54870021-9606CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1063/1.1784439info:eu-repo/semantics/altIdentifier/url/https://aip.scitation.org/doi/10.1063/1.1784439info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:34:07Zoai:ri.conicet.gov.ar:11336/74365instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:34:07.946CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Lanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficient
title Lanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficient
spellingShingle Lanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficient
Kilo, Martin
Lanthanides
Cation diffusion
title_short Lanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficient
title_full Lanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficient
title_fullStr Lanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficient
title_full_unstemmed Lanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficient
title_sort Lanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficient
dc.creator.none.fl_str_mv Kilo, Martin
Taylor, Marcela Andrea
Argirusis, Christos
Borchardt, Günter
Weber, Sylvain
Scherrer, Hubert
Jackson, Robert A.
author Kilo, Martin
author_facet Kilo, Martin
Taylor, Marcela Andrea
Argirusis, Christos
Borchardt, Günter
Weber, Sylvain
Scherrer, Hubert
Jackson, Robert A.
author_role author
author2 Taylor, Marcela Andrea
Argirusis, Christos
Borchardt, Günter
Weber, Sylvain
Scherrer, Hubert
Jackson, Robert A.
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Lanthanides
Cation diffusion
topic Lanthanides
Cation diffusion
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The diffusion of all stable lanthanides in calcia stabilized zirconia (CSZ) and in yttria stabilized zirconia (YSZ) was measured. Lanthanide migration enthalpies were calculated using the Mott-littleton approach. The results suggest that the bulk diffusion coefficient depends on the ionic radius of the lanthanide tracer. It was also found that the experimental activation enthalpies are about 6eV for CSZ and between 4 and 5 eV for YSZ and almost constant for all lanthanides.
Fil: Kilo, Martin. Technische Universität Clausthal; Alemania
Fil: Taylor, Marcela Andrea. Technische Universität Clausthal; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Argirusis, Christos. Technische Universität Clausthal; Alemania
Fil: Borchardt, Günter. Technische Universität Clausthal; Alemania
Fil: Weber, Sylvain. École Nationale Supérieure Des Mines de Nancy; Francia
Fil: Scherrer, Hubert. École Nationale Supérieure Des Mines de Nancy; Francia
Fil: Jackson, Robert A.. Keele University; Reino Unido
description The diffusion of all stable lanthanides in calcia stabilized zirconia (CSZ) and in yttria stabilized zirconia (YSZ) was measured. Lanthanide migration enthalpies were calculated using the Mott-littleton approach. The results suggest that the bulk diffusion coefficient depends on the ionic radius of the lanthanide tracer. It was also found that the experimental activation enthalpies are about 6eV for CSZ and between 4 and 5 eV for YSZ and almost constant for all lanthanides.
publishDate 2004
dc.date.none.fl_str_mv 2004-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/74365
Kilo, Martin; Taylor, Marcela Andrea; Argirusis, Christos; Borchardt, Günter; Weber, Sylvain; et al.; Lanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficient; American Institute of Physics; Journal of Chemical Physics; 121; 11; 6-2004; 5482-5487
0021-9606
CONICET Digital
CONICET
url http://hdl.handle.net/11336/74365
identifier_str_mv Kilo, Martin; Taylor, Marcela Andrea; Argirusis, Christos; Borchardt, Günter; Weber, Sylvain; et al.; Lanthanide transport in stabilized zirconias: Interrelation between ionic radius and diffusion coefficient; American Institute of Physics; Journal of Chemical Physics; 121; 11; 6-2004; 5482-5487
0021-9606
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1063/1.1784439
info:eu-repo/semantics/altIdentifier/url/https://aip.scitation.org/doi/10.1063/1.1784439
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Institute of Physics
publisher.none.fl_str_mv American Institute of Physics
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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