Aqueous phase hydrogenation of furfural using carbon-supported Ru and RuSn catalysts

Autores
Musci, Juan José; Merlo, Andrea Beatriz; Casella, Mónica Laura
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The aqueous phase hydrogenation (APH) of furfural was studied over carbon-supported monometallic Ru and bimetallic RuSn catalysts at 90 °C and 1.25 MPa. Tin was added via Surface Organometallic Chemistry on Metals techniques and its effect was a function of the Sn/Ru atomic ratio. Thus, the addition of Sn in a Sn/Ru ratio of 0.4 promoted the C[dbnd]O hydrogenation reaching a selectivity towards furfuryl alcohol over 85% throughout the course of the reaction. A higher concentration of tin does not improve the situation. It seems to be a compromise between the dilution of Ru sites, active for the hydrogenation reaction, and the promoting effect of Sn. TEM, TPR and XPS characterization indicate the strong interaction between Ru and Sn in all the bimetallic catalysts. Finally, the reuse of the catalyst was analyzed.
Fil: Musci, Juan José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro de Investigaciones y Transferencia del Noroeste de la Provincia de Buenos Aires. Universidad Nacional del Noroeste de la Provincia de Buenos Aires. Centro de Investigaciones y Transferencia del Noroeste de la Provincia de Buenos Aires; Argentina
Fil: Merlo, Andrea Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Fil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Materia
Aqueous Phase Hydrogenation
Biomass
Furfural
Rusn
Surface Organometallic Chemistry
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/37260
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Aqueous phase hydrogenation of furfural using carbon-supported Ru and RuSn catalystsMusci, Juan JoséMerlo, Andrea BeatrizCasella, Mónica LauraAqueous Phase HydrogenationBiomassFurfuralRusnSurface Organometallic Chemistryhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The aqueous phase hydrogenation (APH) of furfural was studied over carbon-supported monometallic Ru and bimetallic RuSn catalysts at 90 °C and 1.25 MPa. Tin was added via Surface Organometallic Chemistry on Metals techniques and its effect was a function of the Sn/Ru atomic ratio. Thus, the addition of Sn in a Sn/Ru ratio of 0.4 promoted the C[dbnd]O hydrogenation reaching a selectivity towards furfuryl alcohol over 85% throughout the course of the reaction. A higher concentration of tin does not improve the situation. It seems to be a compromise between the dilution of Ru sites, active for the hydrogenation reaction, and the promoting effect of Sn. TEM, TPR and XPS characterization indicate the strong interaction between Ru and Sn in all the bimetallic catalysts. Finally, the reuse of the catalyst was analyzed.Fil: Musci, Juan José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro de Investigaciones y Transferencia del Noroeste de la Provincia de Buenos Aires. Universidad Nacional del Noroeste de la Provincia de Buenos Aires. Centro de Investigaciones y Transferencia del Noroeste de la Provincia de Buenos Aires; ArgentinaFil: Merlo, Andrea Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; ArgentinaFil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; ArgentinaElsevier Science2017-05-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/37260Musci, Juan José; Merlo, Andrea Beatriz; Casella, Mónica Laura; Aqueous phase hydrogenation of furfural using carbon-supported Ru and RuSn catalysts; Elsevier Science; Catalysis Today; 296; 1; 5-5-2017; 45-500920-5861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2017.04.063info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0920586117302961info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:14:43Zoai:ri.conicet.gov.ar:11336/37260instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:14:44.069CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Aqueous phase hydrogenation of furfural using carbon-supported Ru and RuSn catalysts
title Aqueous phase hydrogenation of furfural using carbon-supported Ru and RuSn catalysts
spellingShingle Aqueous phase hydrogenation of furfural using carbon-supported Ru and RuSn catalysts
Musci, Juan José
Aqueous Phase Hydrogenation
Biomass
Furfural
Rusn
Surface Organometallic Chemistry
title_short Aqueous phase hydrogenation of furfural using carbon-supported Ru and RuSn catalysts
title_full Aqueous phase hydrogenation of furfural using carbon-supported Ru and RuSn catalysts
title_fullStr Aqueous phase hydrogenation of furfural using carbon-supported Ru and RuSn catalysts
title_full_unstemmed Aqueous phase hydrogenation of furfural using carbon-supported Ru and RuSn catalysts
title_sort Aqueous phase hydrogenation of furfural using carbon-supported Ru and RuSn catalysts
dc.creator.none.fl_str_mv Musci, Juan José
Merlo, Andrea Beatriz
Casella, Mónica Laura
author Musci, Juan José
author_facet Musci, Juan José
Merlo, Andrea Beatriz
Casella, Mónica Laura
author_role author
author2 Merlo, Andrea Beatriz
Casella, Mónica Laura
author2_role author
author
dc.subject.none.fl_str_mv Aqueous Phase Hydrogenation
Biomass
Furfural
Rusn
Surface Organometallic Chemistry
topic Aqueous Phase Hydrogenation
Biomass
Furfural
Rusn
Surface Organometallic Chemistry
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The aqueous phase hydrogenation (APH) of furfural was studied over carbon-supported monometallic Ru and bimetallic RuSn catalysts at 90 °C and 1.25 MPa. Tin was added via Surface Organometallic Chemistry on Metals techniques and its effect was a function of the Sn/Ru atomic ratio. Thus, the addition of Sn in a Sn/Ru ratio of 0.4 promoted the C[dbnd]O hydrogenation reaching a selectivity towards furfuryl alcohol over 85% throughout the course of the reaction. A higher concentration of tin does not improve the situation. It seems to be a compromise between the dilution of Ru sites, active for the hydrogenation reaction, and the promoting effect of Sn. TEM, TPR and XPS characterization indicate the strong interaction between Ru and Sn in all the bimetallic catalysts. Finally, the reuse of the catalyst was analyzed.
Fil: Musci, Juan José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro de Investigaciones y Transferencia del Noroeste de la Provincia de Buenos Aires. Universidad Nacional del Noroeste de la Provincia de Buenos Aires. Centro de Investigaciones y Transferencia del Noroeste de la Provincia de Buenos Aires; Argentina
Fil: Merlo, Andrea Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
Fil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
description The aqueous phase hydrogenation (APH) of furfural was studied over carbon-supported monometallic Ru and bimetallic RuSn catalysts at 90 °C and 1.25 MPa. Tin was added via Surface Organometallic Chemistry on Metals techniques and its effect was a function of the Sn/Ru atomic ratio. Thus, the addition of Sn in a Sn/Ru ratio of 0.4 promoted the C[dbnd]O hydrogenation reaching a selectivity towards furfuryl alcohol over 85% throughout the course of the reaction. A higher concentration of tin does not improve the situation. It seems to be a compromise between the dilution of Ru sites, active for the hydrogenation reaction, and the promoting effect of Sn. TEM, TPR and XPS characterization indicate the strong interaction between Ru and Sn in all the bimetallic catalysts. Finally, the reuse of the catalyst was analyzed.
publishDate 2017
dc.date.none.fl_str_mv 2017-05-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/37260
Musci, Juan José; Merlo, Andrea Beatriz; Casella, Mónica Laura; Aqueous phase hydrogenation of furfural using carbon-supported Ru and RuSn catalysts; Elsevier Science; Catalysis Today; 296; 1; 5-5-2017; 45-50
0920-5861
CONICET Digital
CONICET
url http://hdl.handle.net/11336/37260
identifier_str_mv Musci, Juan José; Merlo, Andrea Beatriz; Casella, Mónica Laura; Aqueous phase hydrogenation of furfural using carbon-supported Ru and RuSn catalysts; Elsevier Science; Catalysis Today; 296; 1; 5-5-2017; 45-50
0920-5861
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2017.04.063
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0920586117302961
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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