Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid phase
- Autores
- Merlo, Andrea Beatriz; Vetere, Virginia; Ruggera, José Fernando; Casella, Mónica Laura
- Año de publicación
- 2009
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Bimetallic PtSn catalysts, containing different amounts of tin, were obtained by means of controlled surface reactions and used in the liquid-phase hydrogenation of furfural. All the studied systems allowed to obtain fufuryl alcohol with high selectivity (96-98%). A minor product was detected when alcoholic solvent were employed, coming from the reaction between furfuryl alcohol and the solvent. Nonalcoholic and non-polar solvents caused a drastic activity decrease.When used in consecutive hydrogenation reactions, the bimetallic catalysts showed a certain deactivation (25% between the first and third cycle), but still they were very selective to furfuryl alcohol. The most efficient system was the catalyst with the lowest tin content (PtSn0.3).
Fil: Merlo, Andrea Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Vetere, Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Ruggera, José Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina - Materia
-
Furfural
Furfuryl Alcohol
Hydrogenation
Bimetallic Catalysts
Ptsn
Surface Organometallic Chemistry on Metals - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/30144
Ver los metadatos del registro completo
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Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid phaseMerlo, Andrea BeatrizVetere, VirginiaRuggera, José FernandoCasella, Mónica LauraFurfuralFurfuryl AlcoholHydrogenationBimetallic CatalystsPtsnSurface Organometallic Chemistry on Metalshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Bimetallic PtSn catalysts, containing different amounts of tin, were obtained by means of controlled surface reactions and used in the liquid-phase hydrogenation of furfural. All the studied systems allowed to obtain fufuryl alcohol with high selectivity (96-98%). A minor product was detected when alcoholic solvent were employed, coming from the reaction between furfuryl alcohol and the solvent. Nonalcoholic and non-polar solvents caused a drastic activity decrease.When used in consecutive hydrogenation reactions, the bimetallic catalysts showed a certain deactivation (25% between the first and third cycle), but still they were very selective to furfuryl alcohol. The most efficient system was the catalyst with the lowest tin content (PtSn0.3).Fil: Merlo, Andrea Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Vetere, Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Ruggera, José Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaElsevier Science2009-05-20info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/30144Merlo, Andrea Beatriz; Vetere, Virginia; Ruggera, José Fernando; Casella, Mónica Laura; Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid phase; Elsevier Science; Catalysis Communications; 10; 13; 20-5-2009; 1665-16691566-7367CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1566736709001940info:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2009.05.005info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:49:41Zoai:ri.conicet.gov.ar:11336/30144instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:49:42.03CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid phase |
title |
Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid phase |
spellingShingle |
Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid phase Merlo, Andrea Beatriz Furfural Furfuryl Alcohol Hydrogenation Bimetallic Catalysts Ptsn Surface Organometallic Chemistry on Metals |
title_short |
Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid phase |
title_full |
Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid phase |
title_fullStr |
Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid phase |
title_full_unstemmed |
Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid phase |
title_sort |
Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid phase |
dc.creator.none.fl_str_mv |
Merlo, Andrea Beatriz Vetere, Virginia Ruggera, José Fernando Casella, Mónica Laura |
author |
Merlo, Andrea Beatriz |
author_facet |
Merlo, Andrea Beatriz Vetere, Virginia Ruggera, José Fernando Casella, Mónica Laura |
author_role |
author |
author2 |
Vetere, Virginia Ruggera, José Fernando Casella, Mónica Laura |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Furfural Furfuryl Alcohol Hydrogenation Bimetallic Catalysts Ptsn Surface Organometallic Chemistry on Metals |
topic |
Furfural Furfuryl Alcohol Hydrogenation Bimetallic Catalysts Ptsn Surface Organometallic Chemistry on Metals |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Bimetallic PtSn catalysts, containing different amounts of tin, were obtained by means of controlled surface reactions and used in the liquid-phase hydrogenation of furfural. All the studied systems allowed to obtain fufuryl alcohol with high selectivity (96-98%). A minor product was detected when alcoholic solvent were employed, coming from the reaction between furfuryl alcohol and the solvent. Nonalcoholic and non-polar solvents caused a drastic activity decrease.When used in consecutive hydrogenation reactions, the bimetallic catalysts showed a certain deactivation (25% between the first and third cycle), but still they were very selective to furfuryl alcohol. The most efficient system was the catalyst with the lowest tin content (PtSn0.3). Fil: Merlo, Andrea Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina Fil: Vetere, Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina Fil: Ruggera, José Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina Fil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina |
description |
Bimetallic PtSn catalysts, containing different amounts of tin, were obtained by means of controlled surface reactions and used in the liquid-phase hydrogenation of furfural. All the studied systems allowed to obtain fufuryl alcohol with high selectivity (96-98%). A minor product was detected when alcoholic solvent were employed, coming from the reaction between furfuryl alcohol and the solvent. Nonalcoholic and non-polar solvents caused a drastic activity decrease.When used in consecutive hydrogenation reactions, the bimetallic catalysts showed a certain deactivation (25% between the first and third cycle), but still they were very selective to furfuryl alcohol. The most efficient system was the catalyst with the lowest tin content (PtSn0.3). |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-05-20 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/30144 Merlo, Andrea Beatriz; Vetere, Virginia; Ruggera, José Fernando; Casella, Mónica Laura; Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid phase; Elsevier Science; Catalysis Communications; 10; 13; 20-5-2009; 1665-1669 1566-7367 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/30144 |
identifier_str_mv |
Merlo, Andrea Beatriz; Vetere, Virginia; Ruggera, José Fernando; Casella, Mónica Laura; Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid phase; Elsevier Science; Catalysis Communications; 10; 13; 20-5-2009; 1665-1669 1566-7367 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1566736709001940 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2009.05.005 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842268988980068352 |
score |
13.13397 |