XPS and EXAFS study of supported PtSn catalysts obtained by surface organometallic chemistry on metals: Application to the isobutane dehydrogenation

Autores
Siri, Guillermo Jorge; Ramallo Lopez, Jose Martin; Casella, Mónica Laura; García Fierro, José Luis; Requejo, Felix Gregorio; Ferretti, Osmar Alberto
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, well defined alumina and silica supported Pt and PtSn catalysts were prepared by surface organometallic reactions and were characterized by TEM, XPS and EXAFS. These catalysts were tested in the catalytic dehydrogenation of isobutane. XPS results show that tin is found under the form of Sn(0) and Sn(II,IV), being the percentage of Sn(0) lower for alumina supported than for silica supported catalysts. Tin modified platinum catalysts, always show a decrease of approximately 1 eV in the BE of Pt, what would be indicative of an electron charge transfer from tin to platinum. When the concentration of Sn(0) is high enough, in our case Sn(0)/Pt ∼ 0.3, EXAFS experiments demonstrated the existence of a PtSn alloy diluting metallic Pt atoms, for both PtSn/γ-Al2O3 and PtSn/SiO2. This PtSn alloy seems to be not active in the dehydrogenation reaction; however, it is very important for selectivity and stability, inhibiting cracking and coke formation reactions. The ensemble of our catalytic, XPS and EXAFS results, show that bimetallic PtSn/γ-Al2O3 catalysts, prepared via SOMC/M techniques, can be submitted to several sequential reaction–regeneration cycles, recovering the same level of initial activity each time and that the nature of the catalytic surface remains practically without modifications.
Fil: Siri, Guillermo Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Ramallo Lopez, Jose Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: García Fierro, José Luis. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; España
Fil: Requejo, Felix Gregorio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Ferretti, Osmar Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Materia
Catalyst Regeneration
Isobutane Hydrogenation
Organometallic Chemistry
Ptsn Catalysts
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/55479
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/55479
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling XPS and EXAFS study of supported PtSn catalysts obtained by surface organometallic chemistry on metals: Application to the isobutane dehydrogenationSiri, Guillermo JorgeRamallo Lopez, Jose MartinCasella, Mónica LauraGarcía Fierro, José LuisRequejo, Felix GregorioFerretti, Osmar AlbertoCatalyst RegenerationIsobutane HydrogenationOrganometallic ChemistryPtsn Catalystshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In this work, well defined alumina and silica supported Pt and PtSn catalysts were prepared by surface organometallic reactions and were characterized by TEM, XPS and EXAFS. These catalysts were tested in the catalytic dehydrogenation of isobutane. XPS results show that tin is found under the form of Sn(0) and Sn(II,IV), being the percentage of Sn(0) lower for alumina supported than for silica supported catalysts. Tin modified platinum catalysts, always show a decrease of approximately 1 eV in the BE of Pt, what would be indicative of an electron charge transfer from tin to platinum. When the concentration of Sn(0) is high enough, in our case Sn(0)/Pt ∼ 0.3, EXAFS experiments demonstrated the existence of a PtSn alloy diluting metallic Pt atoms, for both PtSn/γ-Al2O3 and PtSn/SiO2. This PtSn alloy seems to be not active in the dehydrogenation reaction; however, it is very important for selectivity and stability, inhibiting cracking and coke formation reactions. The ensemble of our catalytic, XPS and EXAFS results, show that bimetallic PtSn/γ-Al2O3 catalysts, prepared via SOMC/M techniques, can be submitted to several sequential reaction–regeneration cycles, recovering the same level of initial activity each time and that the nature of the catalytic surface remains practically without modifications.Fil: Siri, Guillermo Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Ramallo Lopez, Jose Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: García Fierro, José Luis. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; EspañaFil: Requejo, Felix Gregorio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Ferretti, Osmar Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaElsevier Science2005-01-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/55479Siri, Guillermo Jorge; Ramallo Lopez, Jose Martin; Casella, Mónica Laura; García Fierro, José Luis; Requejo, Felix Gregorio; et al.; XPS and EXAFS study of supported PtSn catalysts obtained by surface organometallic chemistry on metals: Application to the isobutane dehydrogenation; Elsevier Science; Applied Catalysis A: General; 278; 2; 10-1-2005; 239-2490926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2004.10.004info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X04008178info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:44:00Zoai:ri.conicet.gov.ar:11336/55479instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:44:01.021CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv XPS and EXAFS study of supported PtSn catalysts obtained by surface organometallic chemistry on metals: Application to the isobutane dehydrogenation
title XPS and EXAFS study of supported PtSn catalysts obtained by surface organometallic chemistry on metals: Application to the isobutane dehydrogenation
spellingShingle XPS and EXAFS study of supported PtSn catalysts obtained by surface organometallic chemistry on metals: Application to the isobutane dehydrogenation
Siri, Guillermo Jorge
Catalyst Regeneration
Isobutane Hydrogenation
Organometallic Chemistry
Ptsn Catalysts
title_short XPS and EXAFS study of supported PtSn catalysts obtained by surface organometallic chemistry on metals: Application to the isobutane dehydrogenation
title_full XPS and EXAFS study of supported PtSn catalysts obtained by surface organometallic chemistry on metals: Application to the isobutane dehydrogenation
title_fullStr XPS and EXAFS study of supported PtSn catalysts obtained by surface organometallic chemistry on metals: Application to the isobutane dehydrogenation
title_full_unstemmed XPS and EXAFS study of supported PtSn catalysts obtained by surface organometallic chemistry on metals: Application to the isobutane dehydrogenation
title_sort XPS and EXAFS study of supported PtSn catalysts obtained by surface organometallic chemistry on metals: Application to the isobutane dehydrogenation
dc.creator.none.fl_str_mv Siri, Guillermo Jorge
Ramallo Lopez, Jose Martin
Casella, Mónica Laura
García Fierro, José Luis
Requejo, Felix Gregorio
Ferretti, Osmar Alberto
author Siri, Guillermo Jorge
author_facet Siri, Guillermo Jorge
Ramallo Lopez, Jose Martin
Casella, Mónica Laura
García Fierro, José Luis
Requejo, Felix Gregorio
Ferretti, Osmar Alberto
author_role author
author2 Ramallo Lopez, Jose Martin
Casella, Mónica Laura
García Fierro, José Luis
Requejo, Felix Gregorio
Ferretti, Osmar Alberto
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Catalyst Regeneration
Isobutane Hydrogenation
Organometallic Chemistry
Ptsn Catalysts
topic Catalyst Regeneration
Isobutane Hydrogenation
Organometallic Chemistry
Ptsn Catalysts
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this work, well defined alumina and silica supported Pt and PtSn catalysts were prepared by surface organometallic reactions and were characterized by TEM, XPS and EXAFS. These catalysts were tested in the catalytic dehydrogenation of isobutane. XPS results show that tin is found under the form of Sn(0) and Sn(II,IV), being the percentage of Sn(0) lower for alumina supported than for silica supported catalysts. Tin modified platinum catalysts, always show a decrease of approximately 1 eV in the BE of Pt, what would be indicative of an electron charge transfer from tin to platinum. When the concentration of Sn(0) is high enough, in our case Sn(0)/Pt ∼ 0.3, EXAFS experiments demonstrated the existence of a PtSn alloy diluting metallic Pt atoms, for both PtSn/γ-Al2O3 and PtSn/SiO2. This PtSn alloy seems to be not active in the dehydrogenation reaction; however, it is very important for selectivity and stability, inhibiting cracking and coke formation reactions. The ensemble of our catalytic, XPS and EXAFS results, show that bimetallic PtSn/γ-Al2O3 catalysts, prepared via SOMC/M techniques, can be submitted to several sequential reaction–regeneration cycles, recovering the same level of initial activity each time and that the nature of the catalytic surface remains practically without modifications.
Fil: Siri, Guillermo Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Ramallo Lopez, Jose Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: García Fierro, José Luis. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; España
Fil: Requejo, Felix Gregorio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Ferretti, Osmar Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
description In this work, well defined alumina and silica supported Pt and PtSn catalysts were prepared by surface organometallic reactions and were characterized by TEM, XPS and EXAFS. These catalysts were tested in the catalytic dehydrogenation of isobutane. XPS results show that tin is found under the form of Sn(0) and Sn(II,IV), being the percentage of Sn(0) lower for alumina supported than for silica supported catalysts. Tin modified platinum catalysts, always show a decrease of approximately 1 eV in the BE of Pt, what would be indicative of an electron charge transfer from tin to platinum. When the concentration of Sn(0) is high enough, in our case Sn(0)/Pt ∼ 0.3, EXAFS experiments demonstrated the existence of a PtSn alloy diluting metallic Pt atoms, for both PtSn/γ-Al2O3 and PtSn/SiO2. This PtSn alloy seems to be not active in the dehydrogenation reaction; however, it is very important for selectivity and stability, inhibiting cracking and coke formation reactions. The ensemble of our catalytic, XPS and EXAFS results, show that bimetallic PtSn/γ-Al2O3 catalysts, prepared via SOMC/M techniques, can be submitted to several sequential reaction–regeneration cycles, recovering the same level of initial activity each time and that the nature of the catalytic surface remains practically without modifications.
publishDate 2005
dc.date.none.fl_str_mv 2005-01-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/55479
Siri, Guillermo Jorge; Ramallo Lopez, Jose Martin; Casella, Mónica Laura; García Fierro, José Luis; Requejo, Felix Gregorio; et al.; XPS and EXAFS study of supported PtSn catalysts obtained by surface organometallic chemistry on metals: Application to the isobutane dehydrogenation; Elsevier Science; Applied Catalysis A: General; 278; 2; 10-1-2005; 239-249
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/55479
identifier_str_mv Siri, Guillermo Jorge; Ramallo Lopez, Jose Martin; Casella, Mónica Laura; García Fierro, José Luis; Requejo, Felix Gregorio; et al.; XPS and EXAFS study of supported PtSn catalysts obtained by surface organometallic chemistry on metals: Application to the isobutane dehydrogenation; Elsevier Science; Applied Catalysis A: General; 278; 2; 10-1-2005; 239-249
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2004.10.004
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926860X04008178
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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